Abstract: Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula wherein each R1 is a Z1OZ2Z3SiZ4 group, wherein each Z1 represents a hydrogen atom, a C1-C4 alkyl group, or a bond to a silicon atom of another monomer unit; each Z2 and Z3 independently represent a hydroxyl group, a C1-C4 alkyl group, a C1-C4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Z4 represents a C1-C8 alkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.

Abstract: Methods are provided herein for separating an aromatic compound from a lube base stock by contacting a lube base stock containing an aromatic compound with an organosilica material.

Abstract: Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula wherein each R1 is a Z1OZ2Z3SiZ4 group, wherein each Z1 represents a hydrogen atom, a C1-C4 alkyl group, or a bond to a silicon atom of another monomer unit; each Z2 and Z3 independently represent a hydroxyl group, a C1-C4 alkyl group, a C1-C4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Z4 represents a C1-C8 alkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.

Abstract: Methods for separating an aromatic compound from a lube base stock are provided herein. The method includes contacting a lube base stock containing an aromatic compound with an organosilica material as provided herein.

Abstract: The present invention is directed to a process for producing a diesel fuel of enhanced cetane value from low cetane distillate and diesel boiling range fractions from poor crudes such as naphthenic crudes.

Abstract: A process for removing relatively low levels of high molecular weight organic sulfur from hydrocarbon streams, particularly from streams that have picked-up such sulfur while being transported through a pipeline. The hydrocarbon stream containing the organic sulfur is passed through a bed of adsorbent material comprised of a high Ni content, high surface area material that also contains an effective amount of SiO2 or GeO2 and an alkaline earth metal.

Abstract: The present invention is a method for operating a rapid cycling pressure swing adsorption (RCPSA) having a cycle time, T, to separate a feed gas into a non-adsorbed gas and tail gas. The method includes the steps of passing the feed gas having a purity of F % at high pressure into a first end of a bed which selectively adsorbs the tail gas and passes the product gas out a second end of the bed for a time, F. The product gas has a purity, P %, and a rate of recovery of R %. Then the bed is cocurrently drpressurized for a time, tCO, followed by countercurrently depressurizing the bed for a time, tCN. The bed is then purged for a time, tP, wherein desorbate (tail gas) is released at the first end of the bed at a pressure greater than 30 psig, Subsequently the bed is repressurized for a duration, tRP. R>80%, P/F?1.1 or R?90%, 0<P/F<1.1.

Abstract: A method for separating aromatic hydrocarbons from a feed stream. The method includes flowing the feed stream through a first channel within a first wafer assembly that may contain an underflow distribution weir. Next, the feed stream is exposed to a first thin film polymer membrane. A stream permeates through the first thin film polymer membrane, and the permeate is produced from the first wafer assembly. The retentate is directed via a redistribution channel (such as a tube) to a second wafer assembly that may contain an underflow distribution weir. This retentate is exposed to a second thin film polymer membrane. A second permeate stream is created that permeates through the second thin film polymer membrane. The second permeate stream is conducted into the permeate zone and ultimately produced from the second wafer assembly. An apparatus for separating aromatic components from a feed stream is also disclosed. In the preferred embodiment, the apparatus includes a series of tandem wafer assemblies.