Abstract: A lunar base energy supply and application system based on photocatalytic water splitting hydrogen production technology are provided. The system includes a solar photovoltaic power generation unit, a power management unit, a water storage tank, a photocatalytic water splitting unit, an hydrogen-oxygen storage unit, an hydrogen-oxygen-water conversion unit, a condition monitoring unit, a chemical propulsion unit, an environmental control and life support unit, and a load. The photocatalytic water splitting unit and the hydrogen-oxygen-water conversion unit can generate hydrogen and oxygen, and the solar photovoltaic power generation unit and the hydrogen-oxygen-water conversion unit can generate electric power, thus ensuring stable supply of energy at the lunar base.