Patents by Inventor Baojian Shen
Baojian Shen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10335773Abstract: The present invention relates to a Fe-based hydrogenation catalyst having Fe as a primary active metal component, and zinc and potassium as a first co-active metal component. The molar ratio of the primary active metal component to the first co-active metal component is 0.5-200:1. The Fe-based hydrogenation catalyst in present invention overcomes the problem of limiting to the active metal components as used over decades for the conventional hydrogenation catalyst, and thus has long-term values for industrial application.Type: GrantFiled: July 18, 2014Date of Patent: July 2, 2019Assignee: CHINA UNIVERSITY OF PETROLEUM—BEIJINGInventors: Baojian Shen, Hao Li, Yandan Wang, Jiancong Li, Lei Li, Bojun Shen, Baohua Shen, Wennian Wang, Delin Yuan, Honglian Xu
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Patent number: 9725658Abstract: The present invention provides a method for processing low-grade heavy oil, comprising: providing a riser-bed reactor; preheating the low-grade heavy oil and injecting it into the riser reactor to react with solid catalyst particles at the temperature of 550-610° C.; oil-gas, after reacting with the solid catalyst particles in the riser reactor, being introduced into the fluidized bed reactor to continue to react at temperature of 440-520° C. and weight hourly space velocity of 0.5-5 h?1; and the oil-gas, after reacting in the fluidized bed reactor, being separated from coked solid catalyst particles carried therein, and the separated oil-gas being introduced into a fractionation system. The method can effectively remove carbon residues, heavy metals, asphaltenes and other impurities from the low-grade heavy oil, and obtain high liquid product yield in a simple process.Type: GrantFiled: June 4, 2014Date of Patent: August 8, 2017Assignees: CHINA UNIVERSITY OF PETROLEUM-BEIJING, CHINA NATIONAL PETROLEUM CORPORATIONInventors: Gang Wang, Jinsen Gao, Chunming Xu, Baojian Shen, Hongliang Wang
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Patent number: 9382124Abstract: The present invention relates to a synthesis method for ETS-10 titanosilicate molecular sieves. The method comprises the steps of mixing a titanium oxide hydrosol, a silicon source, a sodium hydroxide, a fluorine-containing mineralizer and a water to give a gel and adjusting the pH thereof to 10.4 to 10.8; and hydrothermal crystallizing the gel at 170 to 250° C. for 10 to 100 hours to obtain the ETS-10 titanosilicate molecular sieves. In the synthesis method for ETS-10 titanosilicate molecular sieves provided by the present invention, a titanium oxide hydrosol is used as the titanium source to synthesize the ETS-10 titanosilicate molecular sieves, and the problem that conventional soluble titanium salt-based titanium sources tend to hydrolyze and the problem of poor dispersibility for the titanium source system of insoluble titanium oxide are therefore prevented. The ETS-10 titanosilicate molecular sieves synthesized has high purity and high crystallinity.Type: GrantFiled: December 13, 2012Date of Patent: July 5, 2016Assignees: China University of Petroleum-Beijing (CUPB), China National Petroleum CorporationInventors: Baojian Shen, Jing Li, Xiaohua Wang, Wencheng Zhang, Qiaoxia Guo, Bojun Shen, Bing Feng, Guangming Wen, Zhihua Zhang, Ran Tian
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Publication number: 20160158733Abstract: The present invention relates to a Fe-based hydrogenation catalyst having Fe as a primary active metal component, and zinc and potassium as a first co-active metal component. The molar ratio of the primary active metal component to the first co-active metal component is 0.5-200:1. The Fe-based hydrogenation catalyst in present invention overcomes the problem of limiting to the active metal components as used over decades for the conventional hydrogenation catalyst, and thus has long-term values for industrial application.Type: ApplicationFiled: July 18, 2014Publication date: June 9, 2016Inventors: Baojian SHEN, Hao LI, Yandan WANG, Jiancong LI, Lei LI, Bojun SHEN, Baohua SHEN, Wennian WANG, Delin YUAN, Honglian XU
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Publication number: 20150090637Abstract: The present invention provides a method for processing low-grade heavy oil, comprising: providing a riser-bed reactor; preheating the low-grade heavy oil and injecting it into the riser reactor to react with solid catalyst particles at the temperature of 550-610° C.; oil-gas, after reacting with the solid catalyst particles in the riser reactor, being introduced into the fluidized bed reactor to continue to react at temperature of 440-520° C. and weight hourly space velocity of 0.5-5 h?1; and the oil-gas, after reacting in the fluidized bed reactor, being separated from coked solid catalyst particles carried therein, and the separated oil-gas being introduced into a fractionation system. The method can effectively remove carbon residues, heavy metals, asphaltenes and other impurities from the low-grade heavy oil, and obtain high liquid product yield in a simple process.Type: ApplicationFiled: June 4, 2014Publication date: April 2, 2015Inventors: GANG WANG, JINSEN GAO, CHUNMING XU, BAOJIAN SHEN, HONGLIANG WANG
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Publication number: 20130149235Abstract: The present invention relates to a synthesis method for ETS-10 titanosilicate molecular sieves. The method comprises the steps of mixing a titanium oxide hydrosol, a silicon source, a sodium hydroxide, a fluorine-containing mineralizer and a water to give a gel and adjusting the pH thereof to 10.4 to 10.8; and hydrothermal crystallizing the gel at 170 to 250° C. for 10 to 100 hours to obtain the ETS-10 titanosilicate molecular sieves. In the synthesis method for ETS-10 titanosilicate molecular sieves provided by the present invention, a titanium oxide hydrosol is used as the titanium source to synthesize the ETS-10 titanosilicate molecular sieves, and the problem that conventional soluble titanium salt-based titanium sources tend to hydrolyze and the problem of poor dispersibility for the titanium source system of insoluble titanium oxide are therefore prevented. The ETS-10 titanosilicate molecular sieves synthesized has high purity and high crystallinity.Type: ApplicationFiled: December 13, 2012Publication date: June 13, 2013Inventors: Baojian Shen, Jing Li, Xiaohua Wang, Wencheng Zhang, Qiaoxia Guo, Bojun Shen, Bing Feng, Guangming Wen, Zhihua Zhang, Ran Tian
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Patent number: 7594995Abstract: The present invention provides a catalyst and a process for its preparation and its use in cracking heavy feedstocks. The catalyst comprises one or more zeolites having a controlled silica to alumina ratio and preferably treated with alkali in the presence of a matrix component selected from the group consisting of clays, synthetic matrix other than pillared clay, and mixtures thereof. The catalyst are particularly useful in treating heavy feedstock such as residues from oil sands processing.Type: GrantFiled: November 17, 2008Date of Patent: September 29, 2009Assignee: State Key Laboratory of Heavy Oil ProcessingInventors: Baojian Shen, Jinsen Gao, Chunming Xu, Liang Zhao, Xianfeng Li, Pei Wu
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Publication number: 20090101543Abstract: The present invention provides a catalyst and a process for its preparation and its use in cracking heavy feedstocks. The catalyst comprises one or more zeolites having a controlled silica to alumina ratio and preferably treated with alkali in the presence of a matrix component selected from the group consisting of clays, synthetic matrix other than pillared clay, and mixtures thereof. The catalyst are particularly useful in treating heavy feedstock such as residues from oil sands processing.Type: ApplicationFiled: November 17, 2008Publication date: April 23, 2009Inventors: Baojian Shen, Jinsen Gao, Chunming Xu, Liang Zhao, Xianfeng Li, Pei Wu
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Patent number: 7459413Abstract: The present invention provides a catalyst and a process for its preparation and its use in cracking heavy feedstocks. The catalyst comprises one or more zeolites having a controlled silica to alumina ratio and preferably treated with alkali in the presence of a matrix component selected from the group consisting of clays, synthetic matrix other than pillared clay, and mixtures thereof. The catalyst are particularly useful in treating heavy feedstock such as residues from oil sands processing.Type: GrantFiled: February 21, 2007Date of Patent: December 2, 2008Assignee: State Key Laboratory of Heavy Oil ProcessingInventors: Baojian Shen, Jinsen Gao, Chunming Xu, Liang Zhao, Xianfeng Li, Pei Wu
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Publication number: 20070209969Abstract: The present invention provides a catalyst and a process for its preparation and its use in cracking heavy feedstocks. The catalyst comprises one or more zeolites having a controlled silica to alumina ratio and preferably treated with alkali in the presence of a matrix component selected from the group consisting of clays, synthetic matrix other than pillared clay, and mixtures thereof. The catalyst are particularly useful in treating heavy feedstock such as residues from oil sands processing.Type: ApplicationFiled: February 21, 2007Publication date: September 13, 2007Inventors: Baojian Shen, Jinsen Gao, Chunming Xu, Liang Zhao, Xianfeng Li, Pei Wu
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Patent number: 6723228Abstract: An additive used in catalytic cracking of hydrocarbons, which is in the form of homogeneous liquid and comprises a composite metal compound, wherein said composite metal compound consists of the oxides, hydroxides, organic acid salts, inorganic acid salts or metal organic complex compounds of at least one of the 1st group metals and at least one of the 2nd group metals, wherein the 1st group metals are selected from the group consisting of the metals of the IIIA, IVA, VA, VIA groups of the Element Period Table, boron, silicon, phosphorous and tellurium; wherein the 2nd group metals are selected from the group consisting of alkali-earth metals, transition metals, and rare earth metals, is disclosed. A process of catalytic cracking of hydrocarbons, utilizing the additive is also disclosed. The additive can passivate metals and promote the oxidation of CO, and is operated easily with production cost decreased.Type: GrantFiled: June 11, 2003Date of Patent: April 20, 2004Assignees: China Petrochemical Corporation, Luoyang Petrochemical Engineering CorporationInventors: Shuqin Su, Guoliang Wang, Haiqing Guo, Xianliang Deng, Longyan Wang, Wenyi Qi, Shufang Liu, Baojian Shen, Jinlong Liu, Dongming Zhao
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Publication number: 20030209468Abstract: An additive used in catalytic cracking of hydrocarbons, which is in the form of homogeneous liquid and comprises a composite metal compound, wherein said composite metal compound consists of the oxides, hydroxides, organic acid salts, inorganic acid salts or metal organic complex compounds of at least one of the 1st group metals and at least one of the 2nd group metals, wherein the 1st group metals are selected from the group consisting of the metals of the IIIA, IVA, VA, VIA groups of the Element Period Table, boron, silicon, phosphorous and tellurium; wherein the 2nd group metals are selected from the group consisting of alkali-earth metals, transition metals, and rare earth metals, is disclosed. A process of catalytic cracking of hydrocarbons, utilizing the additive is also disclosed. The additive can passivate metals and promote the oxidation of CO, and is operated easily with production cost decreased.Type: ApplicationFiled: June 11, 2003Publication date: November 13, 2003Inventors: Shuqin Su, Guoliang Wang, Haiqing Guo, Xianliang Deng, Longyan Wang, Wenyi Qi, Shufang Liu, Baojian Shen, Jinlong Liu, Dongming Zhao