Abstract: The invention relates to a method for start-up and operation of a Fischer-Tropsch reactor comprising the steps of: (a) providing a reactor with a fixed bed of reduced Fischer-Tropsch catalyst that comprises cobalt as catalytically active metal; (b) supplying a gaseous feed stream comprising carbon monoxide and hydrogen to the reactor, wherein the gaseous feed stream comprises a nitrogen-containing compound other than molecular nitrogen in an initial concentration, wherein the initial concentration in the range of from 10 to 350 ppbv based on the volume of the gaseous feed stream; (c) converting carbon monoxide and hydrogen supplied with the gaseous feed stream to the reactor into hydrocarbons at a reaction temperature and at a set reactor productivity, whilst maintaining the initial concentration of the nitrogen-containing compound and maintaining the set reactor productivity during a first time period by adjusting the reaction temperature; (d) decreasing the concentration of the nitrogen-containing compound

Abstract: The invention relates to a method for start-up and operation of a Fischer-Tropsch reactor comprising the steps of: (a) providing a reactor with a fixed bed of reduced Fischer-Tropsch catalyst that comprises cobalt as catalytically active metal; (b) supplying a gaseous feed stream comprising carbon monoxide and hydrogen to the reactor, wherein the gaseous feed stream comprises a nitrogen-containing compound other than molecular nitrogen in an initial concentration, wherein the initial concentration in the range of from 10 to 350 ppbv based on the volume of the gaseous feed stream; (c) converting carbon monoxide and hydrogen supplied with the gaseous feed stream to the reactor into hydrocarbons at a reaction temperature and at a set reactor productivity, whilst maintaining the initial concentration of the nitrogen-containing compound and maintaining the set reactor productivity during a first time period by adjusting the reaction temperature; (d) decreasing the concentration of the nitrogen- containing compound

Abstract: The invention comprises a cooling module for use in a reactor for carrying out an exothermic process, such as a Fischer-Tropsch process, comprising a coolant inlet, a coolant distribution chamber, a plurality of cooling tubes, a coolant collection chamber, and a coolant discharge. A plurality of tubes extend through the distribution chamber to enable fluid communication between the space on one side of the distribution chamber and the space between the cooling tubes, and wherein at least 80% of the cooling tubes are arranged separately with a distance to the nearest cooling tube of at least 1 cm.

Abstract: The invention relates to a reactor for carrying out an exothermic process comprising a reactor shell, inlets for introducing reactants and coolant into the reactor shell, outlets for removing product and coolant from the reactor shell, and a plurality of cooling modules, the reactor comprising for at least some of the modules a skirt for guiding gas underneath the modules.