Abstract: An ink composition including a metal salt amine complex; wherein the metal salt amine complex is formed from a metal salt and an amine; a compound selected from the group consisting of a stable free radical, a photoacid generator, and a thermal acid generator; and an optional solvent. A process including forming a metal salt amine complex; adding a compound selected from the group consisting of a stable free radical, a photoacid generator, and a thermal acid generator to the metal salt amine complex to form an ink. A process forming conductive features on a substrate with the ink composition.

Abstract: A method of producing a transparent polymer aerogel can include dissolving gel precursors consisting of radical polymerizable monomers and crosslinkers, radical initiators, and a chain transfer agent (CTA) in a reaction solvent, placing the gel precursors into a substrate, polymerizing the gel on the substrate, optionally removing the wet gel from the mold, optionally performing at least one solvent exchange on the gel, and drying the solvent-exchanged gel.

Abstract: Provided herein is a composition for eutectic metal alloy nanoparticles having an average particle size ranging from about 0.5 nanometers to less than about 5000 nanometers and at least one organoamine stabilizer. Also provided herein is a process for preparing eutectic metal alloy nanoparticles comprising mixing at least one organic polar solvent, at least one organoamine stabilizer, and a eutectic metal alloy to create a mixture; sonicating the mixture at a temperature above the melting point of the eutectic metal alloy; and collecting a composition comprising a plurality of eutectic metal alloy nanoparticles having an average particle size ranging from about 0.5 nanometers to less than about 5000 nanometers. Further disclosed herein are hybrid conductive ink compositions comprising a component comprising a plurality of metal nanoparticles and a component comprising a plurality of eutectic metal alloy nanoparticles.

Abstract: A nanoparticle composition comprising a plurality of stabilized metal-containing nanoparticles comprising silver and/or a silver alloy composite. The stabilized metal-containing nanoparticles are prepared by a method comprising reacting a silver compound with a reducing agent comprising a hydrazine compound by incrementally adding the silver compound to a first mixture comprising the reducing agent, a stabilizer and a solvent. The stabilizer comprises a mixture of a first organoamine and a second organoamine, an alkyl moiety of the first organoamine having a longer carbon chain length than the alkyl moiety of the second organoamine. The first organoamine is selected from the group consisting of decylamine, undecylamine, dodecylamine, tridecylamine, tetradecylamine and mixtures thereof. The second organoamine is selected from group consisting of butylamine, pentylamine, hexylamine, heptylamine, octylamine, nonylamine, decylamine and mixtures thereof.

Abstract: A method to produce a polymer gel includes dissolving precursors in a solvent to form a precursor solution, the precursors including polymer precursors, a stable free radical, one or more initiating radicals, and one or more stable free radical control agents, and heating the precursor solution to a temperature of polymerization to produce a cross-linked gel. A dried polymer aerogel has a Brunauer-Emmett Teller (BET) surface area over 100 m2/g, porosity of greater than 10%, visible transparency greater than 20%, color rendering index of over 20%, and average pore size of less than 100 nm.

Abstract: The present disclosure is directed to a hybrid conductive ink including: silver nanoparticles and eutectic low melting point alloy particles, wherein a weight ratio of the eutectic low melting point alloy particles and the silver nanoparticles ranges from 1:20 to 1:5.

Abstract: Methods for printing a conductive object are provided which may comprise dispensing one of a first ink composition and a second ink composition towards a substrate surface to form a deposition region on the substrate surface or on a previously printed object on the substrate surface, wherein the first ink composition comprises an aqueous solution of a metal compound and the second ink composition comprises an aqueous solution of a stable free radical; dispensing the other of the first and second ink compositions in the deposition region to mix the first and second ink compositions and induce chemical reduction of the metal compound by the stable free radical and precipitation of the metal of the metal compound; and removing solvent from the deposition region, thereby forming a conductive object comprising the precipitated metal.

Abstract: The present disclosure is directed to a hybrid conductive ink including: silver nanoparticles and eutectic low melting point alloy particles, wherein a weight ratio of the eutectic low melting point alloy particles and the silver nanoparticles ranges from 1:20 to 1:5.

Abstract: A process including providing a substantially flat printed image on a substrate; disposing a curable gellant composition onto the printed image in registration with the printed image, successively depositing additional amounts of the gellant composition to create a raised image in registration with the printed image; and curing the deposited raised image. A process including providing a printed image on a substrate; disposing a curable non-gellant composition onto the printed image in registration with the printed image; and disposing a curable gellant composition onto the printed image in registration with the printed image; to create a raised image in registration with the printed image; and curing the deposited raised image. An ultraviolet curable phase change gellant composition including a radiation curable monomer or prepolymer, a photoinitiator, a silicone polymer or pre-polymer, and a gellant.

Abstract: A conductive polymer composite is disclosed. The composite comprises a thermoplastic polymer and a plurality of metal-plated carbon nanotubes. A method of three dimensional printing using the conductive polymer composite and a filament comprising the conductive polymer composite are also disclosed.

Abstract: A composite filament includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite filaments.

Abstract: A method of selective laser sintering is disclosed. The method comprises providing composite particles made by emulsion aggregation, the composite particles comprising at least one thermoplastic polymer and at least one carbon particle material. The composite particles are exposed to a laser to fuse the composite particles.

Abstract: A curable ink including at least one monomer, oligomer, or prepolymer; an optional photoinitiator; an optional colorant; and amide gellant having a molecular weight of from about 800 to about 2,500 g/mole; wherein the ink has an onset of gelation defined by the glass transition of the low molecular weight amide gellant according to the relationship Onset of Gelation (K)=(Constant) Tg of gellant (K); wherein the Constant is less than 1.5. A process for printing a three-dimensional article including providing a curable ink; depositing the curable ink in one or more layers; and curing the deposited ink to form the three-dimensional object.

Abstract: Provided is a method of forming a conductive polymer composite. The method includes forming a mixture. The mixture includes a first thermoplastic polymer, a second thermoplastic polymer and a plurality of metal particles. The first thermoplastic polymer and the second thermoplastic polymer are immiscible with each other. The plurality of metal particles include at least one metal that is immiscible with both the first thermoplastic polymer and the second thermoplastic polymer. The method includes heating the mixture to a temperature greater than or equal to a melting point of the metal.

Abstract: A method of producing a polymer aerogel can include dissolving gel precursors consisting of radical polymerizable monomers and crosslinkers, radical initiators, and a chain transfer agent (CTA) in a reaction solvent, wherein the monomers and cross-linkers produce stiff homopolymers; placing the gel precursors into a substrate; polymerizing the gel on the substrate; optionally removing the wet gel from the mold; optionally performing at least one solvent exchange on the gel; and removing the reaction solvent.

Abstract: A method of producing a transparent polymer aerogel can include dissolving gel precursors consisting of radical polymerizable monomers and crosslinkers, radical initiators, and a chain transfer agent (CTA) in a reaction solvent, placing the gel precursors into a substrate, polymerizing the gel on the substrate, optionally removing the wet gel from the mold, optionally performing at least one solvent exchange on the gel, and drying the solvent-exchanged gel.

Abstract: An ink composition including a metal salt; an optional solvent; and a stable component that is stable in the ink composition until treated, wherein, upon treatment, the component forms a compound that reduces the metal salt to form metal. An ink composition including a metal salt; an initiator; and an optional solvent; wherein, upon treatment, the initiator forms a compound which reduces the metal salt to metal. A process including combining a metal salt, an initiator, and an optional solvent, to form an ink; wherein, upon treatment, the initiator forms a compound which reduces the metal salt to metal. A process including providing an ink composition comprising a metal salt, an initiator, and an optional solvent; depositing the ink composition onto a substrate to form deposited features; and treating the deposited features on the substrate wherein the initiator forms a compound which reduces the metal salt to metal to form conductive features on the substrate.

Abstract: An article includes a body and at least one 3D-printable conductive composite segment in mechanical communication with the body. The body includes a first material and the at least one conductive composite segment includes a matrix material, a plurality of carbon nanotubes, and conductive additives. The conductive additives include a plurality of metallic particulates, a plurality of graphitic particles or a combination thereof.

Abstract: Provided is a method of forming a conductive polymer composite. The method includes forming a mixture. The mixture includes a first thermoplastic polymer, a second thermoplastic polymer and a plurality of metal particles. The first thermoplastic polymer and the second thermoplastic polymer are immiscible with each other. The plurality of metal particles include at least one metal that is immiscible with both the first thermoplastic polymer and the second thermoplastic polymer. The method includes heating the mixture to a temperature greater than or equal to a melting point of the metal.

Abstract: An ink composition including a metal salt amine complex; wherein the metal salt amine complex is formed from a metal salt and an amine; a compound selected from the group consisting of a stable free radical, a photoacid generator, and a thermal acid generator; and an optional solvent. A process including forming a metal salt amine complex; adding a compound selected from the group consisting of a stable free radical, a photoacid generator, and a thermal acid generator to the metal salt amine complex to form an ink. A process including providing an ink composition comprising a metal salt amine complex, wherein the metal salt amine complex is formed from a metal salt and an amine; a compound selected from the group consisting of a stable free radical, a photoacid generator, and a thermal acid generator; and an optional solvent; depositing the ink composition onto a substrate to form deposited features; and treating the deposited features on the substrate to form conductive features on the substrate.