Abstract: A free radical curable inkjet ink containing a colour pigment and a polymerizable composition, wherein the colour pigment is a mixture of colour pigments including at least one colour pigment selected from a quinacridone pigment, a diketopyrrolo pyrrole pigment, and a mixed crystal thereof; wherein the average particle diameter of the colour pigment is between 80 nm and 240 nm as determined by a dynamic light scattering technique using a laser diode having an emission wavelength of 635 nm; wherein the polymerizable composition contains 95.0 to 99.5 wt % of monofunctional polymerizable compounds; wherein the polymerizable composition has a double bond density DBD of at least 5.40. An inkjet printing method with the free radical curable inkjet ink is also disclosed.

Abstract: A free radical curable inkjet ink containing a colour pigment, a photoinitiator and polymerizable composition, wherein the polymerizable composition includes more than 88.0% of monofunctional polymerizable compounds based on the total weight of the polymerizable composition; wherein more than 13.0 wt % of a monofunctional polymerizable compound having a double bond density DBD of more than 7.00; wherein more than 35.0 wt % of a polyfunctional alkoxylated acrylate having a molecular weight MW of more than 310 based on the total weight of the polyfunctional polymerizable compounds; wherein non-aromatic cyclic monofunctional acrylates in an amount such that the ratio of the wt % of polyfunctional alkoxylated acrylate having a molecular weight MW of more than 310 to the wt % of non-aromatic cyclic monofunctional acrylates is larger than 0.35; and wherein the polymerizable composition has a double bond density DBD of no more than 5.55 mmol double bonds/g.

Abstract: A radiation curable inkjet ink set comprising a cyan inkjet ink containing a beta-copper phthalocyanine pigment and a polymerizable composition; a magenta inkjet ink containing a magenta or red pigment and a polymerizable composition; a yellow inkjet ink containing a yellow pigment and a polymerizable composition; and a black inkjet ink containing a carbon black pigment and a polymerizable composition; wherein the polymerizable compositions of the cyan, magenta, yellow and black inkjet inks include on average: a) 20.0 to 40.0 wt % of phenoxyethyl acrylate; b) 23.0 to 32.0 wt % of isobornyl acrylate; c) 1.0 to 14.4 wt % of monomer selected from the group consisting of 4-acryloylmorpholine and a monomer according to Formula (I), wherein X represents C or O, n represents 1, 2 or 3 and m represents 0 or 1; and d) up to 14.

Abstract: A UV LED free radical curable inkjet ink containing an organic colour pigment; an acylphosphine oxide photoinitiator; monofunctional polymerizable compounds including vinyl methyl oxazolidinone; and one or more polyfunctional polymerizable compounds; wherein: the double bond density DD is between 5.28 and 5.78 mmol double bonds/g; the content of monofunctional polymerizable compounds is between 84 and 98 wt % based on the total weight of the polymerizable composition; and the content of vinyl methyl oxazolidinone is at least 13.3 wt % based on the total weight of the polymerizable composition.

Abstract: A radiation curable inkjet ink set comprising a cyan inkjet ink containing a beta-copper phthalocyanine pigment and a polymerizable composition; a magenta inkjet ink containing a magenta or red pigment and a polymerizable composition; a yellow inkjet ink containing a yellow pigment and a polymerizable composition; and a black inkjet ink containing a carbon black pigment and a polymerizable composition; wherein the polymerizable compositions of the cyan, magenta, yellow and black inkjet inks include on average: a) 20.0 to 40.0 wt % of phenoxyethyl acrylate; b) 23.0 to 32.0 wt % of isobornyl acrylate; c) 1.0 to 14.4 wt % of monomer selected from the group consisting of 4-acryloylmorpholine and a monomer according to Formula (I), wherein X represents C or O, n represents 1, 2 or 3 and m represents 0 or 1; and d) up to 14.

Abstract: A UV curable colourless inkjet liquid includes at least one radical photoinitiator and a polymerizable composition, wherein the polymerizable composition contains a mixture of: a) 25 to 50 wt % of a monofunctional methacrylate; b) 40 to 70 wt % of a polyfunctional acrylate; and c) 0 to 15 wt % of a monofunctional acrylate; with the weight percentage wt % based on the total weight of the polymerizable composition.

Abstract: A method of producing a security document includes the steps of producing a first part of a color image by color laser marking a security document precursor; and producing a second part of the color image by a second imaging technique different from laser marking. The resulting security document is more difficult to falsify.

Abstract: A UV curable colourless inkjet liquid includes at least one radical photoinitiator and a polymerizable composition, wherein the polymerizable composition contains a mixture of: a) 25 to 50 wt % of a monofunctional methacrylate; b) 40 to 70 wt % of a polyfunctional acrylate; and c) 0 to 15 wt % of a monofunctional acrylate; with the weight percentage wt % based on the total weight of the polymerizable composition.

Abstract: A set of laminates includes an outer laminate and an inner laminate, wherein the outer laminate includes a transparent polymeric support including on a first side of the support a color laser markable layer containing an infrared dye having an absorption maximum ?max(IR-1) in the infrared region; wherein the inner laminate includes a transparent polymeric support including on, a first side of the transparent polymeric support, a color laser markable layer containing an infrared dye having an absorption maximum ?max(IR-2) in the infrared region and, on a second side of the transparent polymeric support, a color laser markable layer containing an infrared dye having an absorption maximum ?max(IR-3) in the infrared region; and the conditions a) and b) are satisfied: ?max(IR-1)>?max(IR-2)>?max(IR-3); and??a) ?max(IR-1)>1100 nm and ?max(IR-3)<1000 nm.

Abstract: A method for preparing a color laser marked article using three infrared lasers L-1, L-2 and L-3 having respectively a laser emission wavelength of ?(L-1), ?(L-2) and ?(L-3) includes the steps of laser marking with the infrared laser L-1 a first color laser markable layer including an infrared dye IR-1 having an absorption maximum in the infrared region ?max(IR-1); laser marking with the infrared laser L-2 a second color laser markable layer including an infrared dye IR-2 having an absorption maximum in the infrared region ?max(IR-2); laser marking with the infrared laser L-3 a third color laser markable layer including an infrared dye IR-3 having an absorption maximum in the infrared region ?max(IR-3); and at least partially exposing the color laser markable article to light having a wavelength between 520 nm and 700 nm, wherein, the laser emission wavelengths satisfy the condition of: ?(L-1)>?(L-2)>?(L-3); the infrared red dye absorption maxima satisfy the condition of: ?max(IR-1)>?max(IR-2)>?ma

Abstract: A security laminate (1) including in order a transparent oriented polyester support (2), a subbing layer (3) and an adhesive layer (4) which is coated on top of the subbing layer, wherein the binder of the adhesive layer is based on a mixture of a first and a second polymer in a weight ratio from 50/50 to 90/10, wherein the first polymer is a copolymer comprising vinyl acetate and at least 85 wt % of vinyl chloride based on the total weight of the first polymer; wherein the second polymer is a copolymer of styrene, butadiene and methylmethacrylate or a copolymer of vinyl butyral, vinyl acetate and vinyl alcohol; and wherein the binder of the subbing layer is based on a polyester-urethane copolymer.

Abstract: A color laser markable laminate includes at least a transparent polymeric support and a color forming layer including a leuco dye; an infrared dye; and a polymeric binder including vinyl acetate and at least 85 wt % of vinyl chloride based on the total weight of the binder; wherein the color laser markable laminate includes a specific phenol stabilizer sterically hindered by a ring containing three nitrogen atoms. A method for preparing a color laser marked document is also disclosed.

Abstract: A method of producing a security document includes the steps of producing a first part of a colour image by colour laser marking a security document precursor; and producing a second part of the colour image by a second imaging technique different from laser marking. The resulting security document is more difficult to falsify.

Abstract: A colour laser markable laminate includes at least a transparent polymeric support and a colour forming layer including a leuco dye; an infrared dye; and a polymeric binder including vinyl acetate and at least 85 wt % of vinyl chloride based on the total weight of the binder; wherein the colour laser markable laminate includes a specific phenol stabilizer sterically hindered by a ring containing three nitrogen atoms. A method for preparing a colour laser marked document is also disclosed.

Abstract: A set of laminates includes an outer laminate and an inner laminate, wherein the outer laminate includes a transparent polymeric support includinq on a first side of the support a colour laser markable layer containing an infrared dye having an absorption maximum ?max(IR-1) in the infrared region; wherein the inner laminate includes a transparent polymeric support including on, a first side of the transparent polymeric support, a colour laser markable layer containing an infrared dye having an absorption maximum ?max(IR-2) in the infrared region and, on a second side of the transparent polymeric support, a colour laser markable layer containing an infrared dye having an absorption maximum ?max(IR-3) in the infrared region; and the conditions a) and b) are satisfied: ?max(IR-1)>?max(IR-2)>?max(IR-3); and??a) ?max(IR-1)>1100 nm and ?max(IR-3)<1000 nm.

Abstract: Infrared dyes soluble in methylene chloride have an infrared absorption maximum above 1100 nm and minor discolouration in the visual spectrum. The infrared dyes are especially useful for producing multicolour laser marked security documents having reduced background discoloration and enhanced colour gamut.

Abstract: A method for preparing a color laser marked article using three infrared lasers L-1, L-2 and L-3 having respectively a laser emission wavelength of ?(L-1), ?(L-2) and ?(L-3) includes the steps of laser marking with the infrared laser L-1 a first color laser markable layer including an infrared dye IR-1 having an absorption maximum in the infrared region ?max(IR-1); laser marking with the infrared laser L-2 a second color laser markable layer including an infrared dye IR-2 having an absorption maximum in the infrared region ?max(IR-2); laser marking with the infrared laser L-3 a third color laser markable layer including an infrared dye IR-3 having an absorption maximum in the infrared region ?max(IR-3); and at least partially exposing the color laser markable article to light having a wavelength between 520 nm and 700 nm, wherein, the laser emission wavelengths satisfy the condition of: ?(L-1)>?(L-2)>?(L-3); the infrared red dye absorption maxima satisfy the condition of: ?max(IR-1)>?max(IR-2)>?ma

Abstract: A security film including, in order, a transparent biaxially oriented polyethylene terephthalate support (1), a subbing layer (2, 2?) and a laser markable layer (3, 3?) comprising a laser additive and one or more polymers selected from the group consisting of polystyrene, polycarbonate and styrene acrylonitrile.

Abstract: A method of color laser marking a security document precursor including at least: a transparent biaxially stretched polyethylene terephthalate foil; at least one colorless color forming layer for generating a color different from black containing at least an infrared absorber a color forming compound and a polymeric binder; and a laser markable polymeric support or a laser markable layer for generating a black color; comprising the steps of: laser marking the colorless color forming layer through the transparent polymeric foil with a infrared laser used in continuous wave mode to generate a color different from black; and laser marking the laser markable polymeric support or the laser markable layer through the transparent polymeric foil with the same infrared laser but used in a pulsed mode to generate a black color.

Abstract: A security film including a support (1) and a laser markable layer (3), wherein the laser markable layer includes i) a laser additive; ii) a polymer selected from the group consisting of polystyrene, polycarbonate and styrene acrylonitrile; iii) an initiator; and iv) at least 15 wt % of radiation curable compound based on the total dry weight of the laser markable layer, wherein the radiation curable compound has a viscosity of less than 100 mPa·s at 25° C. and at a shear rate of 100 s?1. A security document and a method for preparing the security film are also disclosed.