Abstract: communications grade glass optical fibers are protected from static fatigue failure by an initial coating that reacts with surface silanol groups, thereby to occupy or tie up water vapor reaction sites. The OH surface radicals may be bonded to by condensation reactions including: esterification, carboxylation, etherification, chlorination and ammination. For speed and simplicity of reaction, silanation with silanes is attractive as, for example, hexamethyldisilizane (HMDS). The reaction is sufficiently fast to use in a continuous fiber drawing and in-line coating process. The barrier coating may be selected to bond relatively strongly to an outer abrasion protection polymeric coating. Bonding is also enhanced by creating an initial minimum, evenly distributed concentration, of surface silanol groups, for example, about 5 groups/100 Angstrom units in any direction. The reaction molecule is also large enough to act as a water vapor barrier.