Abstract: Apparatus for use in an ion exchange unit or column comprising a riser pipe, a port coupled to one end of said pipe, a first rigid cylinder having apertures therein mounted concentrically on the pipe, a port coupled to the space between the pipe and said cylinder, a mesh sleeve concentrically mounted about the cylinder, a sieve mounted about the mesh sleeve, a second rigid cylinder concentric with the pipe and near its outer end, a second mesh sleeve mounted about said second rigid cylinder and a sieve bag containing the second mesh sleeve. The aperture size in said sieve material is only sufficiently fine to prevent the passage of ion exchange resin beads.

Abstract: An apparatus and method is provided for automated periodic removal of metal ions and contaminants from a chemical bath comprising a latex solution containing charged latex particles and having an acidic pH, used for forming a coating by autodeposition. The system includes a tank containing a chemical bath, an ion exchange column for removing the metal ion contaminants, circulating pump, metal composition sensors, and equipment for regeneration of the ion exchange column. The system particularly includes a filter located at the inlet to the ion exchange column for removing solid particulates, including coagulated latex and debris from the coating solution, while permitting the uncoagulated latex particles to pass through to the ion exchange column.

Abstract: The quality of coating in autodeposition from solutions in which the coating is predominantly derived from epoxy resins can be improved in two ways, which can be used jointly or separately: A blocked isocyanate is used as cross linking agent for the epoxy resin, and a surfactant that prevents the occurrence of phase separation during drying of the coating is used. Preferably the surfactant is a fluoroaliphatic polymer ester.

Abstract: The use of chelating type cation exchange resins, particularly those with iminodiacetic acid functionality, to remove dissolved multivalent cations such as iron, zinc, and chromium from used autodeposition compositions permits reuse of the autodeposition compositions without the need for added surfactant and without developing any undesirable graininess or other texture in the coatings formed. The cation exchange resins can be efficiently regenerated with 0.5 to 4% by weight aqueous hydrofluoric acid.

Abstract: Process for forming an autodeposition coating on a metallic substrate by applying an autodepositing composition from a motile source thereof such as by spraying or by treating the surface with a continuous stream of the autodepositing composition.

Abstract: Pinhole and blister formation during autodeposition coating of galvanized steel and similar zinciferous surfaces can be greatly reduced by exposing the zinciferous surfaces to a pinhole inhibiting aqueous HF solution containing a suitable additive before using an autodeposition process itself. The most effective additives are boric acid, polyphosphonic acids, and polyethyleneimine.

Abstract: A process forming an organic coating, such as an autodeposited coating, on a plurality of small metallic articles by contacting the articles with a liquid coating composition containing an organic film-forming material comprising:(A) providing a plurality of said articles, with at least some of the articles being in contact with at least one other of said articles;(B) immersing the articles into a bath of said composition under conditions such that said articles are not in conttact with another article in said composition;(C) maintaining said articles in separated form in said composition for a period of time sufficiently long for the entirety of the surfaces of said articles to be coated with said composition; and(D) collecting the coated articles in the bath in a form in which at least some of the coated articles are in contact with another of said coated articles;wherein the coating composition is capable of forming on a steel panel immersed therein a coating having a wet strength such that its rinse resis

Abstract: Autodepositing compositions of the type that form coatings which tend to crack in the wet stage are modified by including in the composition a fugitive plasticizer, such as 2,2,4-trimethylpentanediol-1,3 monoisobutyrate, tributoxyethyl phosphate, ethylene glycol monohexyl ether, diethylene glycol monohexyl ether, or a mixture of phenyl glycol ethers.

Abstract: Curing of autodeposited coatings by treatment with water or steam including a solute.

Abstract: A method for stabilizing the electrolyte content of latex composition baths in which, preferably, the bath is flowingly contacted with the outside of a tubular filtration membrane having pores smaller than the latex micelles, and partly deioized water flows through the center of the tubular membrane at a rate sufficient to cause a pressure differential and thus effect ultrafiltration removal of electrolytes.

Abstract: Staining of the finish coat on irregular workpieces caused by bleed-out of cleansing chemicals used in autodeposition coating processes is substantially eliminated by maintaining temperatures sufficiently constant to reduce or eliminate significant contraction or expansion of the metal fabric of the workpiece throughout the cleaning stage of the process.

Abstract: Curing of autodeposited coatings by treatment with water or steam.