Abstract: The present invention provides an alloy film of Mn or its Fe—Mn is depositable on a metalized alumina ceramic (Al2O3-SiO3) substrate for hermetically sealed glass-metal fusion used for aircraft switch assemblies. The coefficient of thermal expansion of Fe—Mn alloys appear to be fairly low, nearer to that of glass. Fe—Mn alloy film is an alternative to Fe64—Ni36 alloy films (Invar) normally used for glass to glass fusion purposes. Fe—Mn alloy films is also depositable directly on bare Alumina (Al2O3) substrate with or without zincating pretreatment. Similarly bright, smooth coherent film of Mn—Au or Fe—Mn—Ni Au alloys is depositable from an aqueous solution of simple salt bath or on Cu substrate without the use of cyanide without bridging with zincate processes.

Abstract: A method of codepositing iron and manganese having a high proportion of manganese incorporates use of a new electrochemical cell. The deposit comprises up to 38% manganese from a solution of wide ranging pH from an aqueous bath of sulfate, phosphate salt or any other type of bath, The deposits may subsequently be nitrided, phosphatized or carburized to produced an amorphous surface comparable to Hadfield steel. The manganese alloy deposit exhibits a bright, shiny surface.