Abstract: The present invention relates to a process for producing an aqueous polymer dispersion of polymerized ethylenically unsaturated monomers, where the process has a first polymerization step as an aqueous radical emulsion polymerization of a first monomer composition M.a and a subsequent further polymerization step as an aqueous radical emulsion polymerization of a second monomer composition M.b, where the monomers M comprise at least one monomer M0 which is selected from compounds of formula 1, wherein X is Cl, Br or OS(O)2R3, Y is H, Cl, Br, OS(O)2R4, C1-C10-alkyl, or C(?O)OR5, R1 is H or C1-C10-alkyl, R2 is H or C1-C10-alkyl, R3 is C1-C10-alkyl, R4 is C1-C10-alkyl, R5 is C1-C20-alkyl. The invention also relates to an aqueous polymer dispersion obtainable by such a process as well as the use of such dispersions.

Abstract: The present invention relates to aqueous polymer latexes of film-forming copolymers which are suitable as binders in waterborne coating compositions, and are obtainable by aqueous emulsion polymerisation of ethylenically unsaturated monomers M, which comprise •20 to 95% by weight, based on the total amount of monomers M, of at least one monomer M1, which is selected from isobutyl acrylate and isoamyl acrylate and mixtures thereof; •0 to 55% by weight, based on the total amount of monomers M, of at least one monomer M2, which is selected from ethyl acrylate, n-propyl acrylate, n-butyl acrylate, n-pentyl acrylate, C6-C20-alkyl esters of acrylic acid and C5-C20-alkyl esters of methacrylic acid and mixtures thereof; •5 to 50% by weight, based on the total amount of monomers M, of at least one monomer M3, which is selected from tert-butyl acrylate, C1-C4-alkyl esters of methacrylic acid, C5-C20-cycloalkyl esters of acrylic acid, C5-C20-cycloalkyl esters of methacrylic acid, C5-C20-cycloalkylmethyl esters of acryli

Abstract: The presently claimed invention relates to use of an aqueous polymer latex as a binder or co-binder in a waterborne coating composition, wherein the aqueous polymer latex is obtained by polymerizing a monomer composition M, comprising at least one tert-butyl acrylate and/or tertbutyl methacrylate monomer, by radical emulsion polymerization.

Abstract: The present invention relates to a process for producing an aqueous polymer dispersion of polymerized ethylenically unsaturated monomers M having a polymer content of at least 55 wt. % and a polymodal particle size distribution of the polymer particles of the polymer dispersion. The invention also relates to aqueous polymer dispersions obtained from this process as well as aqueous liquid compositions comprising at least one aqueous polymer dispersion and the use of such aqueous liquid compositions as binder.

Abstract: The present invention relates to aqueous polymer latexes of film-forming copolymers obtainable by aqueous emulsion polymerisation of monomers M, which comprise at least 80% by weight, based on the monomers M, of—at least one non-ionic monomer M1, which is selected from C1-C20-alkyl esters of acrylic acid, C5-C20-cycloalkyl esters of acrylic acid, C1-C20-alkyl esters of methacrylic acid, C5-C20-cycloalkyl esters of methacrylic acid and monovinyl aromatic monomers; —one or more monoethylenically unsaturated monomers M2, which are selected from monoethylenically unsaturated monocarboxylic acids having 3 to 6 carbon atoms and monoethylenically unsaturated dicarboxylic acids having 4 to 6 carbon atoms; and where the polymer latex contains an emulsifier combination comprising i.

Abstract: The present invention relates to a process for producing an aqueous polymer dispersion of polymerized ethylenically unsaturated monomers, where the process has a first polymerization step as an aqueous radical emulsion polymerization of a first monomer composition M.a and a subsequent further polymerization step as an aqueous radical emulsion polymerization of a second monomer composition M.b, where the monomers M comprise at least one monomer M0 which is selected from compounds of formula 1, wherein X is Cl, Br or OS(O)2R3, Y is H, Cl, Br, OS(O)2R4, C1-C10-alkyl, or C(?O)OR5, R1 is H or C1-C10-alkyl, R2 is H or C1-C10-alkyl, R3 is C1-C10-alkyl, R4 is C1-C10-alkyl, R5 is C1-C20-alkyl. The invention also relates to an aqueous polymer dispersion obtainable by such a process as well as the use of such dispersions.

Abstract: The present invention provides very finely divided polymer dispersions obtainable by at least one two-stage emulsion polymerization, wherein 1) an acid-rich first polymer P1 is prepared by a radical polymerization from a 1st composition comprising A) at least one monomer selected from the group of (cyclo)alkyl (meth)acrylates, vinylaromatics having up to 20 carbon atoms, a radically polymerizable compound selected from the group of ethylenically unsaturated nitriles having up to 20 carbon atoms, vinyl esters of carboxylic acids containing up to 20 carbon atoms, vinyl halides having up to 10 carbon atoms, and vinyl ethers of alcohols containing 1 to 10 carbon atoms B) at least one ?,?-ethylenically unsaturated carboxylic acid C) at least one crosslinking monomer with a keto or aldehyde group D) optionally at least one adhesion promoter E) optionally tert-butyl acrylate F) optionally further monomers M in the presence of a chain link transfer agent, 2) the polymer P1 prepared under 1) is admixed with a base

Abstract: The present invention relates to a polymer dispersion obtainable by at least one two-stage emulsion polymerization, by 1) preparing a polymer A by a radical polymerization from a 1st composition comprising A) at least one monomer, B) at least one anionic copolymerizable emulsifier, 2) admixing the polymer A prepared at 1) with a base, 3) in the presence of the polymer A treated at 2), preparing a polymer B by radical polymerization from a 2nd composition comprising A) at least one monomer, B) at least one anionic copolymerizable emulsifier. The present invention also relates to a process for preparing the polymer dispersion of the invention, to coating materials in the form of an aqueous composition comprising the polymer dispersion of the invention, and to the use of the polymer dispersion of the invention for coating compositions or paints and varnishes.

Abstract: The present invention provides very finely divided polymer dispersions obtainable by at least one two-stage emulsion polymerization, wherein 1) an acid-rich first polymer P1 is prepared by a radical polymerization from a 1st composition comprising A) at least one monomer selected from the group of (cyclo)alkyl (meth)acrylates, vinylaromatics having up to 20 carbon atoms, a radically polymerizable compound selected from the group of ethylenically unsaturated nitriles having up to 20 carbon atoms, vinyl esters of carboxylic acids containing up to 20 carbon atoms, vinyl halides having up to 10 carbon atoms, and vinyl ethers of alcohols containing 1 to 10 carbon atoms B) at least one ?,?-ethylenically unsaturated carboxylic acid C) at least one crosslinking monomer with a keto or aldehyde group D) optionally at least one adhesion promoter E) optionally tert-butyl acrylate F) optionally further monomers M in the presence of a chain link transfer agent, 2) the polymer P1 prepared under 1) is admixed with a base

Abstract: The present invention relates to a method for producing an aqueous polymer dispersion by radical-initiated aqueous emulsion polymerization of ethylenically unsaturated monomers, and to polymer dispersions obtainable according to said method. The invention also relates to the use of the said polymer dispersions, in particular for the production of coating products for wood.

Abstract: The present invention relates to a method for producing an aqueous polymer dispersion by radical-initiated aqueous emulsion polymerization of ethylenically unsaturated monomers, and to polymer dispersions obtainable according to said method. The invention also relates to the use of the said polymer dispersions, in particular for the production of coating products for wood.

Abstract: The present invention relates to a polymer dispersion obtainable by at least one two-stage emulsion polymerization, by 1) preparing a polymer A by a radical polymerization from a 1st composition comprising A) at least one monomer, B) at least one anionic copolymerizable emulsifier, 2) admixing the polymer A prepared at 1) with a base, 3) in the presence of the polymer A treated at 2), preparing a polymer B by radical polymerization from a 2nd composition comprising A) at least one monomer, B) at least one anionic copolymerizable emulsifier. The present invention also relates to a process for preparing the polymer dispersion of the invention, to coating materials in the form of an aqueous composition comprising the polymer dispersion of the invention, and to the use of the polymer dispersion of the invention for coating compositions or paints and varnishes.