Patents by Inventor Beate Froehling
Beate Froehling has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11344489Abstract: A composition for dyeing keratin fibres comprising a. at least one azomethine compound selected from compounds (3) and (4) and b. water. The composition may be used in a process for dyeing keratin fibres or, with simultaneous or sequential application of a composition comprising one or more oxidising agents, in a process for lightening keratin fibres.Type: GrantFiled: November 21, 2019Date of Patent: May 31, 2022Assignee: BASF SEInventors: Frank Bachmann, Beate Froehling, Christian Cremer, Marie-Pascale Perritaz, Volker Wendel
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Publication number: 20220016007Abstract: A composition for dyeing keratin fibres comprising a. at least one azomethine compound selected from compounds (3) and (4) and b. water. The composition may be used in a process for dyeing keratin fibres or, with simultaneous or sequential application of a composition comprising one or more oxidising agents, in a process for lightening keratin fibres.Type: ApplicationFiled: November 21, 2019Publication date: January 20, 2022Inventors: Frank Bachmann, Beate Froehling, Christian Cremer, Marie-Pascale Perritaz, Volker Wendel
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Patent number: 10494527Abstract: The invention relates to cationic direct dyes of the formula I (1), wherein m and n are independently from each other 0 or 1, D is an aromatic or a cationic heteroaromatic group, which are further specified, K is an aromatic or heteroaromatic group, E1 and E2 are independently from each other ?CH— or ?N—, An is an anion and a is a number from 1 to 6 and R1 and R2 are independently from each other and further specified. The compounds show washfastness at hair-dying.Type: GrantFiled: March 18, 2016Date of Patent: December 3, 2019Assignee: BASF SEInventors: Frank Bachmann, Christian Cremer, Beate Froehling, Bryan Patrick Murphy, Guiru Zhang, Peter Marte Torgerson
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Publication number: 20180244924Abstract: The invention relates to cationic direct dyes of the formula I (1), wherein m and n are independently from each other 0 or 1, D is an aromatic or a cationic heteroaromatic group, which are further specified, K is an aromatic or heteroaromatic group, E1 and E2 are independently from each other ?CH— or ?N—, An is an anion and a is a number from 1 to 6 and R1 and R2 are independently from each other and further specified. The compounds show washfastness at hair-dying.Type: ApplicationFiled: March 18, 2016Publication date: August 30, 2018Inventors: Frank Bachmann, Christian Cremer, Beate Froehling, Bryan Patrick Murphy, Guiru Zhang, Peter Marte Torgerson
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Patent number: 10047225Abstract: Disclosed are styryl dyes of formula wherein R1, R2, R3, R?1, R?2 and R?3 independently of each other are hydrogen; —NH(CO)—C1-C5alkyl; —N(C1-C5alkyl)(C1-C5alkyl-CN); C1-C6alkoxy; a heterocyclic radical; or R1 and R2 or R?1 and R?2 together form a 5- to 10-membered, monocyclic, carbocyclic or heterocyclic ring; wherein at least one of R1, R2, R3, R?1, R?2 and R?3 is different from hydrogen; Q and Q? independently from each other are the direct bond; *—C(O)—*; *—C(O)O—*; *—OCO—*; *—N(R4)—*; ?*—C(O)N(R6)—*; or *—(R6)NC(O)—*; and R4, R5 and R6 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C12aryl; C6-C12aryl-C1-C10alkyl; or C1-C10alkyl(C5-C12aryl); X and X? are *—(CH2)m—*; Y1 and Y2 independently from each other are C1-C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene); An? is an anion; m is a number from 1 to 8; n is 0, or 1; and p is 0, or 1.Type: GrantFiled: August 28, 2014Date of Patent: August 14, 2018Assignee: BASF SEInventors: Frank Bachmann, Christian Cremer, Markus Knobloch, Beate Fröhling, Werner Specker
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Publication number: 20160208103Abstract: Disclosed are styryl dyes of formula wherein R1, R2, R3, R?1, R?2 and R?3 independently of each other are hydrogen; —NH(CO)—C1-C5alkyl; —N(C1-C5alkyl)(C1-C5alkyl-CN); C1-C6alkoxy; a heterocyclic radical; or R1 and R2 or R?1 and R?2 together form a 5- to 10-membered, monocyclic, carbocyclic or heterocyclic ring; wherein at least one of R1, R2, R3, R?1, R?2 and R?3 is different from hydrogen; Q and Q? independently from each other are the direct bond; *—C(O)—*; *—C(O)O—*; *—OCO—*; *—N(R4)—*; *—C(O)N(R6)—*; or *—(R6)NC(O)—*; and R4, R5 and R6 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C12aryl; C6-C12aryl-C1-C10alkyl; or C1-C10alkyl(C5-C12aryl); X and X? are *—(CH2)m—*; Y1 and Y2 independently from each other are C1-C10alkylene; C6-C10cycloalkylene; C5-C12arylene; or C6-C12arylene-(C1-C10alkylene); An? is an anion; m is a number from 1 to 8; n is 0, or 1; and p is 0, or 1.Type: ApplicationFiled: August 28, 2014Publication date: July 21, 2016Inventors: Frank BACHMANN, Christian CREMER, Markus KNOBLOCH, Beate FRÖHLING, Werner SPECKER
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Patent number: 8337569Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein the substituents and variables are defined in the claims and specification. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.Type: GrantFiled: July 15, 2010Date of Patent: December 25, 2012Assignee: BASF SEInventors: Christian Cremer, Oliver Becherer, Beate Fröhling
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Patent number: 8268014Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) ant least one dye selected from the compounds of formulae (2); (3) and (4); wherein D is the radical of a diazo component of the formula (2a); (2b); (2c); (2d); (2f); (2g) or (2h). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.Type: GrantFiled: February 19, 2010Date of Patent: September 18, 2012Assignee: BASF SE LudwigshafenInventor: Beate Fröhling
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Patent number: 8257448Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) a least one dye selected from the compounds of formulae (2) and (3), wherein D is the radical of a diazo component of the formula (2a) and (c) a quaternary ammonium salt selected from (c1) quaternary ammonium salts of the formula (4); (c2) imidazolium salts of the formula (5) and (c3) quaternary diammonium salts of the formula (6). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.Type: GrantFiled: February 19, 2010Date of Patent: September 4, 2012Assignee: BASF SEInventor: Beate Fröhling
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Patent number: 8206464Abstract: Disclosed are cationic polymeric dye with a hue value of h=210° to 330° comprising: a) a polymer backbone, b) a residue of an organic dye, and c) optionally colorless organic groups, wherein (b) and (c) are covalently bound to the polymer backbone (a), and wherein the cationic charges can independently be part of the dye or the colorless organic groups. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.Type: GrantFiled: January 7, 2009Date of Patent: June 26, 2012Assignee: BASF SEInventors: Christian Cremer, Sophie Marquais-Bienewald, Olof Wallquist, Beate Fröhling
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Publication number: 20120110750Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —S—, —S—S—, —N—, —N?—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (formula II) —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; which may be interrupted and/or terminated at one or both ends by one or more than one —C1C30alkylene- or —C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstType: ApplicationFiled: July 15, 2010Publication date: May 10, 2012Applicant: BASF SEInventors: Christian Cremer, Oliver Becherer, Beate Fröhling
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Publication number: 20120017931Abstract: Hair dyeing composition comprising (a) a dye of formula (1) (b) at least one dye selected from the compounds of formulae (2) (3) (4) wherein D is the radical of a diazo component of the formula (2a) (2b) (2c) (2d) K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; naphthalene derivative; X is —CH? —O—; —S—; or —N(R7)—; R1, R2, R3 end R4 independently from each other are hydrogen; or C1-C4alkyl; R5 and R6 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; R7 and R9 independently from each other are unsubstituted or OH—, C1-C4alkoxy-, halogen-, amino-, C1-C4-mono or -dialkylamino-substituted C1-C4alkyl; or phenyl; R8 is hydrogen; C1-C4alkyl; Cl; or nitro; R10 is hydrogen; C1-C4alkyl; Cl; nitro; amino; or C1-C4mono- or C1-C4dialkylamino; R11 is hydrogen; C1-C4alkyl; or CN; R12 is unsubstituted or OH— or CN-substituted C1-C4alkyl; R13 is hydrogen; or C1-C4alkyl; R14 and R15 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; orType: ApplicationFiled: February 19, 2010Publication date: January 26, 2012Applicant: BASF SEInventor: Beate Fröhling
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Publication number: 20120012128Abstract: Disclosed is a hair dyeing composition comprising (a) a dye of formula (1); (b) at least one dye selected from the compounds of formulae (2); wherein D is the radical of a diazo component of the formula (2a); K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; and a radical of a heterocyclic coupling component; X is O—; —S—; or N(R8)—; Y is CH?; —CR15?; or N?; R1, R2, R3 and R4 independently from each other are hydrogen; or C1-C4alkyl; R5 and R6 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; R7 and R9 independently from each other are unsubstituted or OH—, C1-C4alkoxy-, halogen-, amino-, C1-C4-mono or -dialkylamino-substituted C1-C4alkyl; R8 is hydrogen; or C1-C4alkyl; R10 is hydrogen; C1-C4alkyl; or CN; R11 is unsubstituted or OH- or CN-substituted C1-C4alkyl; R12 is hydrogen; or C1-C4alkyl; R13 and R14 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; or R13 and R14 together with the nitrogen and carbon atoms joiningType: ApplicationFiled: February 19, 2010Publication date: January 19, 2012Applicant: BASF SEInventor: Beate Fröhling
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Patent number: 8097045Abstract: Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N?—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straighType: GrantFiled: January 7, 2009Date of Patent: January 17, 2012Assignee: BASF SEInventors: Sophie Marquais-Bienewald, Christian Cremer, Olof Wallquist, Beate Fröhling
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Patent number: 7976585Abstract: A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C1-C18alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, —C5-C10arylene-(C1-C10alkylene)- each of which may be end-capped towards the linkage to Dye by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, SO2, C5-C10cycloalkylene, C5-C10arylene; or T is C3-C18alkylene interrupted, and optionally end-capped towards the linkage to Dye, by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, —SO2—, C5-C10cycloalkylene, C5-C10arylene; or is CO; (CH2CH2—O)1-5; COO; N(R1); CON(R1); O; S; SO; SO2; R1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; CType: GrantFiled: April 25, 2008Date of Patent: July 12, 2011Assignee: BASF SE LudwigshafenInventors: Christian Cremer, Richard Lewis Riggs, Beate Fröhling, Martin Müller
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Patent number: 7931696Abstract: Disclosed are dyes of formula wherein D is the radical of anthraquinone, acridine, azo, azomethine, hydrazomethine, benzodifuranone, coumarine, diketopyrrolopyrrol, dioxaxine, diphenylmethane, formazane, indigoid, indophenol, naphtalimide, naphthaquinone, nitroaryl, merocyanine, methine, oxazine, perinone, perylene, pyrenequinone, phtalocyanine, phenazine, quinoneimine, quinacridone, quinophtalone, stilbene, styryl, triphenylmethane, xanthene, thiazine dye and thioxanthene dye; and Q is defined herein.Type: GrantFiled: January 22, 2008Date of Patent: April 26, 2011Assignee: BASF SE LudwigshafenInventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7828858Abstract: Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.Type: GrantFiled: September 13, 2006Date of Patent: November 9, 2010Assignee: Ciba CorporationInventors: Christian Cremer, Victor Paul Eliu, Beate Fröhling, Olof Wallquist
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Patent number: 7811335Abstract: Disclosed are composition and method for dyeing keratin-containing fibers comprising or utilizing styryl sulfide dyes of formula (1), their salts, isomers, hydrates and other solvates, wherein R1, R?1, R2, R?2, R3, R?3, W1, W?1, W2, W?2, W3, W?3, W4, W?4, Q, Q?, Y1 and Y2 are defined in claims and disclosure.Type: GrantFiled: June 7, 2006Date of Patent: October 12, 2010Assignee: Ciba Specialty Chemicals Corp.Inventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7806940Abstract: Disclosed are oligomeric cationic azo dyes of formula (1), their salts, isomers, hydrates and other solvates, wherein n, R1, R2, X, Y? and Z+ are defined in claims and disclosure. Furthermore, the present invention relates to novel cationic oligomeric azo dyes of formula (1), compositions, thereof, especially comprising other dyes, and to application for hair dyeing.Type: GrantFiled: June 7, 2006Date of Patent: October 5, 2010Assignee: Ciba Specialty Chemicals Corp.Inventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7803197Abstract: Disclosed are thiol dyes of formula (1) wherein L1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, or C5-C10arylene-C1-C10alkylene, which may by interrupted by —O—, —NH—, —S—, —CO—, o-SO2—; Y is the residue of an organic dye Z is a group of formula (1b) or —C?N; wherein A is O; S; or N-L2; B is L3; —OL3; —NL3L4; or —SL3; and L2, L3 and L4, independently from other are hydrogen; C1-C12alkyl; C5-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.Type: GrantFiled: August 8, 2007Date of Patent: September 28, 2010Assignee: Ciba CorporationInventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann