Patents by Inventor Beate Frohling

Beate Frohling has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8992633
    Abstract: Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2).
    Type: Grant
    Filed: May 2, 2012
    Date of Patent: March 31, 2015
    Assignee: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Publication number: 20140157529
    Abstract: Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2).
    Type: Application
    Filed: May 2, 2012
    Publication date: June 12, 2014
    Applicant: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Patent number: 8641783
    Abstract: The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.
    Type: Grant
    Filed: August 15, 2011
    Date of Patent: February 4, 2014
    Assignee: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Publication number: 20130139328
    Abstract: The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.
    Type: Application
    Filed: August 15, 2011
    Publication date: June 6, 2013
    Applicant: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Publication number: 20110107525
    Abstract: Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N?—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straigh
    Type: Application
    Filed: January 7, 2009
    Publication date: May 12, 2011
    Applicant: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Olof Wallquist, Beate Frohling
  • Publication number: 20110061179
    Abstract: Disclosed are cationic polymeric dye with a hue value of h=210° to 330° comprising: a) a polymer backbone, b) a residue of an organic dye, and c) optionally colorless organic groups, wherein (b) and (c) are covalently bound to the polymer backbone (a), and wherein the cationic charges can independently be part of the dye or the colorless organic groups. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    Type: Application
    Filed: January 7, 2009
    Publication date: March 17, 2011
    Applicant: BASF SE
    Inventors: Christian Cremer, Sophie Marquais-Bienewald, Olof Wallquist, Beate Frohling
  • Publication number: 20100192312
    Abstract: A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C1-C18alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, —C5-C10arylene-(C1-C10alkylene)- each of which may be end-capped towards the linkage to Dye by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, SO2, C5-C10cycloalkylene, C5-C10arylene; or T is C3-C18alkylene interrupted, and optionally end-capped towards the linkage to Dye, by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, —SO2—, C5-C10cycloalkylene, C5-C10arylene; or is CO; (CH2CH2—O)1-5; COO; N(R1); CON(R1); O; S; SO; SO2; R1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C
    Type: Application
    Filed: April 25, 2008
    Publication date: August 5, 2010
    Applicant: CIBA CORPORATION
    Inventors: Christian Cremer, Richard Lewis Riggs, Beate Frohling, Martin Muller
  • Publication number: 20100058545
    Abstract: Disclosed are dyes of Formula (I) wherein D is the radical of anthraquinone, acridine, azo, azomethine, hydrazomethine, benzodifuranone, coumarine, diketopyrrolopyrrol, dioxaxine, diphenylmethane, formazane, indigoid, indophenol, naphtalimide, naphthaquinone, nitroaryl, merocyanine, methine, oxazine, perinone, perylene, pyrenequinone, phtalocyanine, phenazine, quinoneimine, quinacridone, quinophtalone, stilbene, styryl, triphenylmethane, xanthene, thiazine dye and thioxanthene dye; Q is C1-C30alkylene, —C2-C12alkenylene, C5-C10arylene-, C5-C10cycloalkylene- or —C1-C10alkylene(C5-C10arylene)- which may be interrupted and/or terminated at one or both ends by one or more than one —O—, —S—, —N?, —N(R1)—, SO2, —(CH2CH2-O) 1-5-, —(CH2CH2CH2—O) 1-5-, —C(O)—, —C(O)—C1-C12alkenylene, —C(O)O—, —OCO—, A N+R1R2, —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —CSR1— or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (hetero)cyclic) bivalent radical optionally comprising at least one h
    Type: Application
    Filed: January 22, 2008
    Publication date: March 11, 2010
    Applicant: CIBA CORPORATION
    Inventors: Victor Paul Eliu, Beate Frohling, Dominique Kauffmann
  • Publication number: 20090265866
    Abstract: Disclosed are compounds of formula (1a), wherein R1 is N+R8R9; R8 and/or R9 independently from each other are hydrogen; C1-C12alkyl; or phenyl-C1-C4-alkyl; or R8 and/or R9 are a bivalent C3-C6alkylene radical which is linked to the carbon atoms C1 or C2 respectively and, together with the linking nitrogen atom form a 6 to 16-membered carbocyclic ring; R2 is NR10R11; or OR10; R10 and R11, independently from each other are hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; or R10 and/or R11 are a bivalent C3-C6alkylene radical which is linked to the carbon atoms C3 or C4 respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16-membered carbocyclic ring; or R10 and R11 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; R3, R4, R5, R6 and R7 independently form each other are hydrogen; C1-C12alkyl; halogen; NR12R13; or a radical of formula (1a); R12 and R13 independently from each other are hydrogen; C1-C12alkyl; phenyl-C1-C4alkyl; or a radical of formula (1a2); V
    Type: Application
    Filed: September 25, 2006
    Publication date: October 29, 2009
    Inventors: Victor Paul Eliu, Beate Frohling, Dominique Kauffmann
  • Publication number: 20090113639
    Abstract: Disclosed are thiol dyes of formula (1), wherein R1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene; C2-C12alkenylene; C5-C10cycloalkylene; C5-C10arylene; or C5-C10arylene-C1-C10alkylene; Y is the residue of an organic dye which corresponds to the formula (1a), wherein R2 is hydrogen; or C1-C5alkyl; R3 is a radical of formula (1a1): (1a2); or (1a3); or R2 and R3 together with the linking carbon atom 1C form a 6 to 10 membered carbocyclic ring which may optionally be a condensated aromatic system and may contain one or more than one hetero atom; and R4, R5 and R6 independently form each other are hydrogen, or C1-C5alkyl; Z is H; or a thio ester group of formula (1b), wherein A is O; S; or N—R9; B is —OR7; —NR7R8, or —SR7; and A is O; S; or N—R9; B is —OR7; —NR7R8, or —SR7; and R7, R8 and R9, independently from each other are hydrogen; C1-C12alkyl C6-C12aryl; or C6-C12aryl-C1-C12alkyl.
    Type: Application
    Filed: September 27, 2006
    Publication date: May 7, 2009
    Inventors: Victor Paul Eliu, Beate Frohling, Achim Buhrer
  • Publication number: 20090106915
    Abstract: The present invention concerns coloring keratin fibers, especially human hair, with colored metal complexes.
    Type: Application
    Filed: May 3, 2006
    Publication date: April 30, 2009
    Inventors: Nicole End, Kai-Uwe Schoning, Beate Frohling
  • Publication number: 20090100610
    Abstract: Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
    Type: Application
    Filed: September 13, 2006
    Publication date: April 23, 2009
    Inventors: Christian Cremer, Victor Paul Eliu, Beate Frohling, Olof Wallquist
  • Publication number: 20080295260
    Abstract: Formula (I) wherein R1 and R2 each independently from each other are a residue of an organic dye: Y1 and Y2 each independently from each other are unsubstituted or substituted, straightchain or branched, interrupted or uninterrupted —C1-C10alkylene-; —C5-C10cycloalkylene-; C5-C10arylene; or —C5-C10arylene-(C1C10alkylene)-; Z1 and Z2 independently from each other are Formula (II) are each independently from each other hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); r, q and n independently from each other are 0 or 1, if n is 0, Z3 is hydrogen; and if n is 1, Z3 is —S—; with the proviso that the method does not comprise treating the fiber with an enzyme of the type of a protein disulfidisomerase (EC 5.3.4.1).
    Type: Application
    Filed: March 29, 2005
    Publication date: December 4, 2008
    Inventors: Victor Paul Eliu, Beate Frohling, Dominique Kauffmann
  • Publication number: 20070214580
    Abstract: Disclosed are azo dyes of formula (1) , wherein R1 is hydrogen; C1-C14alkyl; hydroxy-C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a) —(CH2)n1—O—(CH2)n2—CH3; a radical of formula (1b) C10aryl; or C6-C10aryl-C1-C6alkyl; R3 is hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C6alkyl; or CO—R6; R4 is CO—R6; R5 is C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; or C6-C10aryl-C1-C6alkyl; R6 is hydrogen; C1-C14alkyl; C2-C14alkenyl; or C6-C10aryl; R7, R8, R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; m is 1; or 2; An? is an anion; If m=1, R2 is hydrogen; C1-C14alkyl; C2-C14alkenyl; a radical of formula (1a); a radical of formula (1b) ; C6-C10aryl; or C6-C10aryl-C1-C6alkyl; If m=2, R2 is the direct bond; or C1-C14alkylene, which is optionally substituted by one or more C1-C4alkyl, or which is optionally interrupted by C5-C10arylene, —O— or —NR9R10—; R9 and R10, independently from each other are hydrogen; or C1-C5alkyl; and n1, n2, n3 and n4, independently from each other are a num
    Type: Application
    Filed: March 23, 2005
    Publication date: September 20, 2007
    Inventors: Victor Eliu, Thomas Sauder, Dominique Kauffmann, Beate Frohling
  • Publication number: 20070124872
    Abstract: The present invention relates to a method of coloring porous material, which comprises contacting the material being colored, with a) a capped diazonium compound of formula (1) wherein A+ is a cationic radical of an organic compound, B is a radical of an unsubstituted or substituted, aliphatic or aromatic amine, An is an anion, and b) optionally a coupling component. Further, the present invention relates to novel compounds and compositions thereof.
    Type: Application
    Filed: December 8, 2004
    Publication date: June 7, 2007
    Inventors: Victor Eliu, Beate Frohling, Dominique Kauffmann
  • Publication number: 20060179586
    Abstract: The present invention relates to novel the cationic dyes of formula (1) wherein R, is an unsubstituted or substituted C1-C14 alkyl or an aryl radical; X? is an anion; R3 is an unsubstituted or substituted C1-C14 alkyl, aryl radical, C1-C6 alkoxy, cyanid, nitro or halide; n is 1 or 2; and if n is 1, then R2 is hydrogen, unsubstituted or substituted C1-C14 alkyl; or if n is 2, then R2 is an unsubstituted or substituted C1-C14 alkylen. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, paper, cellulose or polyamides, and preferably human hair.
    Type: Application
    Filed: July 14, 2004
    Publication date: August 17, 2006
    Inventors: Victor Eliu, Beate Frohling
  • Publication number: 20060162095
    Abstract: A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound and b) at least one cationic water-soluble aromatic coupling component, under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
    Type: Application
    Filed: August 26, 2003
    Publication date: July 27, 2006
    Inventors: Beate Frohling, Victor Eliu
  • Publication number: 20050166337
    Abstract: The present invention relates to a method of colouring keratin-containing fibres comprising applying at least one diazonium compound of formula Ia or Ib, wherein R1 to R5 are each independently of the others C1-C12alkyl, C5-C14aryl, C5-C8cycloalkyl, C6-C20aralkyl, C1-C12alkoxy or C1-C12alkylthio unsubstituted or substituted by one or more halogen atoms, nitro, cyano or alkoxy groups; or hydrogen, halogen, hydroxy, nitro, COOH, SO3H, CN, SCN, C1-C4alkylsulfonyl, phenylsulfonyl, benzylsulfonyl, di-C1-C4alkylaminosulfonyl, C1-C4alkylcarbonylamino, C1-C4alkoxysulfonyl or dihydroxy-C1-C4alkylaminosulfonyl and X? is o?, COO? or SO3?, and at least one coupling component, preferably a a water-soluble to the material to be coloured and causing them to react at a pH in the range of 8 to 12.
    Type: Application
    Filed: February 18, 2003
    Publication date: August 4, 2005
    Inventors: Jean-Marie Adam, Taher Yousaf, Beate Frohling
  • Publication number: 20040231072
    Abstract: Process of coloring porous material, which comprises
    Type: Application
    Filed: May 13, 2004
    Publication date: November 25, 2004
    Inventors: Victor Paul Eliu, Beate Frohling, Dominique Kauffmann
  • Publication number: 20040187231
    Abstract: The present invention relates to novel cationic dye of formula (1) and (1a) 1
    Type: Application
    Filed: March 16, 2004
    Publication date: September 30, 2004
    Inventors: Victor Paul Eliu, Beate Frohling