Patents by Inventor Beate Frohling

Beate Frohling has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10047225
    Abstract: Disclosed are styryl dyes of formula wherein R1, R2, R3, R?1, R?2 and R?3 independently of each other are hydrogen; —NH(CO)—C1-C5alkyl; —N(C1-C5alkyl)(C1-C5alkyl-CN); C1-C6alkoxy; a heterocyclic radical; or R1 and R2 or R?1 and R?2 together form a 5- to 10-membered, monocyclic, carbocyclic or heterocyclic ring; wherein at least one of R1, R2, R3, R?1, R?2 and R?3 is different from hydrogen; Q and Q? independently from each other are the direct bond; *—C(O)—*; *—C(O)O—*; *—OCO—*; *—N(R4)—*; ?*—C(O)N(R6)—*; or *—(R6)NC(O)—*; and R4, R5 and R6 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C12aryl; C6-C12aryl-C1-C10alkyl; or C1-C10alkyl(C5-C12aryl); X and X? are *—(CH2)m—*; Y1 and Y2 independently from each other are C1-C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene); An? is an anion; m is a number from 1 to 8; n is 0, or 1; and p is 0, or 1.
    Type: Grant
    Filed: August 28, 2014
    Date of Patent: August 14, 2018
    Assignee: BASF SE
    Inventors: Frank Bachmann, Christian Cremer, Markus Knobloch, Beate Fröhling, Werner Specker
  • Publication number: 20160208103
    Abstract: Disclosed are styryl dyes of formula wherein R1, R2, R3, R?1, R?2 and R?3 independently of each other are hydrogen; —NH(CO)—C1-C5alkyl; —N(C1-C5alkyl)(C1-C5alkyl-CN); C1-C6alkoxy; a heterocyclic radical; or R1 and R2 or R?1 and R?2 together form a 5- to 10-membered, monocyclic, carbocyclic or heterocyclic ring; wherein at least one of R1, R2, R3, R?1, R?2 and R?3 is different from hydrogen; Q and Q? independently from each other are the direct bond; *—C(O)—*; *—C(O)O—*; *—OCO—*; *—N(R4)—*; *—C(O)N(R6)—*; or *—(R6)NC(O)—*; and R4, R5 and R6 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6-C12aryl; C6-C12aryl-C1-C10alkyl; or C1-C10alkyl(C5-C12aryl); X and X? are *—(CH2)m—*; Y1 and Y2 independently from each other are C1-C10alkylene; C6-C10cycloalkylene; C5-C12arylene; or C6-C12arylene-(C1-C10alkylene); An? is an anion; m is a number from 1 to 8; n is 0, or 1; and p is 0, or 1.
    Type: Application
    Filed: August 28, 2014
    Publication date: July 21, 2016
    Inventors: Frank BACHMANN, Christian CREMER, Markus KNOBLOCH, Beate FRÖHLING, Werner SPECKER
  • Patent number: 8992633
    Abstract: Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2).
    Type: Grant
    Filed: May 2, 2012
    Date of Patent: March 31, 2015
    Assignee: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Publication number: 20140157529
    Abstract: Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin-containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2).
    Type: Application
    Filed: May 2, 2012
    Publication date: June 12, 2014
    Applicant: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Patent number: 8641783
    Abstract: The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.
    Type: Grant
    Filed: August 15, 2011
    Date of Patent: February 4, 2014
    Assignee: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Publication number: 20130139328
    Abstract: The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.
    Type: Application
    Filed: August 15, 2011
    Publication date: June 6, 2013
    Applicant: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
  • Patent number: 8337569
    Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein the substituents and variables are defined in the claims and specification. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    Type: Grant
    Filed: July 15, 2010
    Date of Patent: December 25, 2012
    Assignee: BASF SE
    Inventors: Christian Cremer, Oliver Becherer, Beate Fröhling
  • Patent number: 8268014
    Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) ant least one dye selected from the compounds of formulae (2); (3) and (4); wherein D is the radical of a diazo component of the formula (2a); (2b); (2c); (2d); (2f); (2g) or (2h). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: September 18, 2012
    Assignee: BASF SE Ludwigshafen
    Inventor: Beate Fröhling
  • Patent number: 8257448
    Abstract: The invention relates to hair dyeing composition comprising (a) a dye of formula (1); (b) a least one dye selected from the compounds of formulae (2) and (3), wherein D is the radical of a diazo component of the formula (2a) and (c) a quaternary ammonium salt selected from (c1) quaternary ammonium salts of the formula (4); (c2) imidazolium salts of the formula (5) and (c3) quaternary diammonium salts of the formula (6). The invention also relates to the dyeing methods for dyeing keratinous fibers comprising such dyeing composition.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: September 4, 2012
    Assignee: BASF SE
    Inventor: Beate Fröhling
  • Patent number: 8206464
    Abstract: Disclosed are cationic polymeric dye with a hue value of h=210° to 330° comprising: a) a polymer backbone, b) a residue of an organic dye, and c) optionally colorless organic groups, wherein (b) and (c) are covalently bound to the polymer backbone (a), and wherein the cationic charges can independently be part of the dye or the colorless organic groups. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: June 26, 2012
    Assignee: BASF SE
    Inventors: Christian Cremer, Sophie Marquais-Bienewald, Olof Wallquist, Beate Fröhling
  • Publication number: 20120110750
    Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —S—, —S—S—, —N—, —N?—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (formula II) —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; which may be interrupted and/or terminated at one or both ends by one or more than one —C1C30alkylene- or —C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubst
    Type: Application
    Filed: July 15, 2010
    Publication date: May 10, 2012
    Applicant: BASF SE
    Inventors: Christian Cremer, Oliver Becherer, Beate Fröhling
  • Publication number: 20120017931
    Abstract: Hair dyeing composition comprising (a) a dye of formula (1) (b) at least one dye selected from the compounds of formulae (2) (3) (4) wherein D is the radical of a diazo component of the formula (2a) (2b) (2c) (2d) K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; naphthalene derivative; X is —CH? —O—; —S—; or —N(R7)—; R1, R2, R3 end R4 independently from each other are hydrogen; or C1-C4alkyl; R5 and R6 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; R7 and R9 independently from each other are unsubstituted or OH—, C1-C4alkoxy-, halogen-, amino-, C1-C4-mono or -dialkylamino-substituted C1-C4alkyl; or phenyl; R8 is hydrogen; C1-C4alkyl; Cl; or nitro; R10 is hydrogen; C1-C4alkyl; Cl; nitro; amino; or C1-C4mono- or C1-C4dialkylamino; R11 is hydrogen; C1-C4alkyl; or CN; R12 is unsubstituted or OH— or CN-substituted C1-C4alkyl; R13 is hydrogen; or C1-C4alkyl; R14 and R15 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; or
    Type: Application
    Filed: February 19, 2010
    Publication date: January 26, 2012
    Applicant: BASF SE
    Inventor: Beate Fröhling
  • Publication number: 20120012128
    Abstract: Disclosed is a hair dyeing composition comprising (a) a dye of formula (1); (b) at least one dye selected from the compounds of formulae (2); wherein D is the radical of a diazo component of the formula (2a); K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; and a radical of a heterocyclic coupling component; X is O—; —S—; or N(R8)—; Y is CH?; —CR15?; or N?; R1, R2, R3 and R4 independently from each other are hydrogen; or C1-C4alkyl; R5 and R6 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; R7 and R9 independently from each other are unsubstituted or OH—, C1-C4alkoxy-, halogen-, amino-, C1-C4-mono or -dialkylamino-substituted C1-C4alkyl; R8 is hydrogen; or C1-C4alkyl; R10 is hydrogen; C1-C4alkyl; or CN; R11 is unsubstituted or OH- or CN-substituted C1-C4alkyl; R12 is hydrogen; or C1-C4alkyl; R13 and R14 independently from each other are hydrogen; C1-C4alkyl; or C1-C4alkoxy; or R13 and R14 together with the nitrogen and carbon atoms joining
    Type: Application
    Filed: February 19, 2010
    Publication date: January 19, 2012
    Applicant: BASF SE
    Inventor: Beate Fröhling
  • Patent number: 8097045
    Abstract: Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N?—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straigh
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: January 17, 2012
    Assignee: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Olof Wallquist, Beate Fröhling
  • Patent number: 7976585
    Abstract: A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C1-C18alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, —C5-C10arylene-(C1-C10alkylene)- each of which may be end-capped towards the linkage to Dye by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, SO2, C5-C10cycloalkylene, C5-C10arylene; or T is C3-C18alkylene interrupted, and optionally end-capped towards the linkage to Dye, by CO, COO, NR1, CONR1, NR1CONR1, CS, CSS, CSNR1, NR1CSNR1, O, S, SO, —SO2—, C5-C10cycloalkylene, C5-C10arylene; or is CO; (CH2CH2—O)1-5; COO; N(R1); CON(R1); O; S; SO; SO2; R1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C
    Type: Grant
    Filed: April 25, 2008
    Date of Patent: July 12, 2011
    Assignee: BASF SE Ludwigshafen
    Inventors: Christian Cremer, Richard Lewis Riggs, Beate Fröhling, Martin Müller
  • Publication number: 20110107525
    Abstract: Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C30alkylene- or —C2-C12alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one —S—, —N—, —N?—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (II), —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubstituted or substituted, straigh
    Type: Application
    Filed: January 7, 2009
    Publication date: May 12, 2011
    Applicant: BASF SE
    Inventors: Sophie Marquais-Bienewald, Christian Cremer, Olof Wallquist, Beate Frohling
  • Patent number: 7931696
    Abstract: Disclosed are dyes of formula wherein D is the radical of anthraquinone, acridine, azo, azomethine, hydrazomethine, benzodifuranone, coumarine, diketopyrrolopyrrol, dioxaxine, diphenylmethane, formazane, indigoid, indophenol, naphtalimide, naphthaquinone, nitroaryl, merocyanine, methine, oxazine, perinone, perylene, pyrenequinone, phtalocyanine, phenazine, quinoneimine, quinacridone, quinophtalone, stilbene, styryl, triphenylmethane, xanthene, thiazine dye and thioxanthene dye; and Q is defined herein.
    Type: Grant
    Filed: January 22, 2008
    Date of Patent: April 26, 2011
    Assignee: BASF SE Ludwigshafen
    Inventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
  • Publication number: 20110061179
    Abstract: Disclosed are cationic polymeric dye with a hue value of h=210° to 330° comprising: a) a polymer backbone, b) a residue of an organic dye, and c) optionally colorless organic groups, wherein (b) and (c) are covalently bound to the polymer backbone (a), and wherein the cationic charges can independently be part of the dye or the colorless organic groups. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
    Type: Application
    Filed: January 7, 2009
    Publication date: March 17, 2011
    Applicant: BASF SE
    Inventors: Christian Cremer, Sophie Marquais-Bienewald, Olof Wallquist, Beate Frohling
  • Patent number: 7828858
    Abstract: Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: November 9, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Victor Paul Eliu, Beate Fröhling, Olof Wallquist
  • Patent number: 7811335
    Abstract: Disclosed are composition and method for dyeing keratin-containing fibers comprising or utilizing styryl sulfide dyes of formula (1), their salts, isomers, hydrates and other solvates, wherein R1, R?1, R2, R?2, R3, R?3, W1, W?1, W2, W?2, W3, W?3, W4, W?4, Q, Q?, Y1 and Y2 are defined in claims and disclosure.
    Type: Grant
    Filed: June 7, 2006
    Date of Patent: October 12, 2010
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann