Abstract: A process for producing and purifying a synthesis gas stream that contains CO- and H2-produced from a hydrocarbon-containing feed in a gas production unit. CO2 is separated from the synthesis gas stream and CO is cryogenically separated from the synthesis gas stream. CO2 that makes up 5% to 30% by volume in the synthesis is reduced to less than 10 ppm by volume by temperature swing adsorption. The temperature swing adsorption takes place upstream of the cryogenic separation of CO. The CO2 is adsorbed using a disordered adsorbent bed wherein the adsorbent is cooled by means of indirect heat transfer from the adsorbent to the heat transfer medium during adsorption and the adsorbent loaded with CO2 is heated by indirect heat transfer from the heat transfer medium to the adsorbent to effect desorption of CO2.

Abstract: The invention relates to a device for adsorbing at least one component from a gas mixture by temperature swing adsorption, comprising a through-flow chamber (7) and a cooling chamber (8) for accommodating a heat transfer fluid, wherein the through-flow chamber (7) is separated from the cooling chamber (8), wherein the through-flow chamber (7) has an adsorbent (1) which contains a plurality of (two or more) adsorbent bodies containing a porous and adsorptively additive first material (3) and a second material (4) having better thermal conductivity as compared to the first material (3) and wherein the first material (3) is at least partly surrounded by the second material (4).

Abstract: A method for producing urea. A methane-containing feed gas stream is reacted with oxygen by partial oxidation to form a synthesis gas stream containing hydrogen and carbon monoxide. The carbon monoxide is reacted with water in a water gas-shift reaction to form carbon dioxide and hydrogen. The synthesis gas stream is separated into a first synthesis gas substream a second synthesis gas substream. The first synthesis gas substream is subjected to pressure-swing adsorption to separate hydrogen and the second synthesis gas substream is subjected to temperature-swing adsorption to separate carbon dioxide. The separated is reacted with nitrogen to form ammonia and the ammonia is reacted with the carbon dioxide to form urea.

Abstract: A process for producing and purifying a synthesis gas stream that contains CO- and H2-produced from a hydrocarbon-containing feed in a gas production unit, CO2 is separated from the synthesis gas stream and CO is cryogenically separated from the synthesis gas stream. CO2 that makes up 5% to 30% by volume in the synthesis is reduced to less than 10 ppm by volume by temperature swing adsorption. The temperature swing adsorption takes place upstream of the cryogenic separation of CO. The CO2 is adsorbed using a disordered adsorbent bed wherein the adsorbent is cooled by means of indirect heat transfer from the adsorbent to the heat transfer medium during adsorption and the adsorbent loaded with CO2 is heated by indirect heat transfer from the heat transfer medium to the adsorbent to effect desorption of CO2.