Abstract: The present invention relates to photopolymerizable resin compositions suitable for producing durable dental prosthetic and restorative articles. In particular, the invention relates to photopolymerizable resin compositions comprised of a specific combination of multiple polymerizable components, one or more resin-modifying particle components, and one or more photopolymerization initiator components. Compositions of the invention are especially well-suited to producing durable, stain-and wear-resistant dental prosthetic and restorative articles, such as artificial teeth, crowns, bridges, inlays, onlays, and veneers, in an efficient and reliable manner using additive manufacturing systems and methods (e.g., three-dimensional (3D) printing).

Abstract: The present invention relates to photopolymerizable resin compositions suitable for producing durable dental prosthetic and restorative articles. In particular, the invention relates to photopolymerizable resin compositions comprised of a specific combination of multiple polymerizable components, one or more resin-modifying particle components, and one or more photopolymerization initiator components. Compositions of the invention are especially well-suited to producing durable, stain-and wear-resistant dental prosthetic and restorative articles, such as artificial teeth, crowns, bridges, inlays, onlays, and veneers, in an efficient and reliable manner using additive manufacturing systems and methods (e.g., three-dimensional (3D) printing).

Abstract: A three-dimensional printed dental device formed from rapid prototyping with printable polymerizable materials, the dental device comprising a polymeric composition, wherein the polymeric composition, after curing, has at least one property of flexural strength, flexural modulus, fracture toughness, and work of fracture that is at least 20% greater in measured value at 37° C. in comparison to measured value at 23° C.

Abstract: This invention designs and builds multiple layers (two layers or more) of various dental devices, specifically denture base or denture, where printed multiple layered denture base with teeth cavities to receive artificial denture tooth materials to form final dental devices, such as partial and full dentures. It can also print denture teeth. This invention also designs and prints multiple layers (two layers or more) of denture base with artificial denture teeth to form final dental devices, such as partial and full dentures. A method for manufacturing a layered denture is provided. The invention provides a multiple layered denture base materials for printing a denture base. The invention also provides a multiple layered denture tooth materials for printing artificial denture teeth. Highly shape adjustable or shape memory polymer layer(s) may be used in these multiple layered denture base forms.

Abstract: A method for light-curing polymerizable materials to form a dental device is provided. A light-curing apparatus having at least one integrated lighting and heating source, a curing volume, and a temperature controller, preferably a fan, is used in the method. The light source and temperature controller are used to heat a first polymerizable material to temperatures within a first temperature range. A second polymerizable material is applied on or adjacent to the first polymerizable material. The light source and temperature controller are used to heat the second polymerizable material to temperatures within a second temperature range. The first temperature range has a first midpoint and the second temperature range has a second midpoint. The first midpoint temperature is at least 10° C. apart from the second midpoint temperature.

Abstract: The invention provides a high strength dental composition including polymerizable dental resins. The dental composition is useful as restorative material and for making various dental devices, such as artificial teeth, crowns and bridges of high strength dental polymeric material.

Abstract: This invention relates to methods for making a three-dimensional dental prosthesis using ink-jet printing systems. An ink-jet printer is used to discharge light-curable, wax-like polymerizable material in a layer-by-layer manner to build-up the prosthesis. The methods are particularly useful for making integrated dentures containing a set of artificial teeth. The denture base and set of teeth are made of light-curable, wax-like polymerizable materials comprising a mixture of monomer, oligomer, and light sensitizer. The wax-like materials are dimensionally stable in their uncured states. The denture base and artificial teeth are later light-cured to form a polymerized denture product having high flexural modulus and flexural strength.

Abstract: A dental appliance comprising a hard, shaped body having at least one portion comprising a polymerized blend of: From 0% to about 50% of an uncrosslinked polymer capable of dissolving in component; From about 0% to 50% of a monofunctional polymerizable monomer; From about 0% to 40% of a highly crosslinked polymer in the form of ground particles having average diameters up to about 500 microns; From about 0% to 50% of a crosslinked polymer in the form of discrete particles having average diameters up to about 500 microns and being easily swellable by said monomer; and From about 5% to about 35% of a di- or polyfunctional crosslinking agent.

Abstract: A dental appliance comprising a hard, shaped body having at least one portion comprising a polymerized blend of: From 0% to about 50% of an uncrosslinked polymer capable of dissolving in component;From about 0% to 50% of a monofunctional polymerizable monomer;From about 0% to 40% of a highly crosslinked polymer in the form of ground particles having average diameters up to about 500 microns;From about 0% to 50% of a crosslinked polymer in the form of discrete particles having average diameters up to about 500 microns and being easily swellable by said monomer; and From about 5% to about 35% of a di- or polyfunctional crosslinking agent.

Abstract: The invention provides a high strength dental composition including polymerizable dental resins. The dental composition is useful as restorative material and for making various dental devices, such as artificial teeth, crowns and bridges of high strength dental polymeric material.

Abstract: This invention relates to methods for making a three-dimensional dental prosthesis using ink-jet printing systems. An ink-jet printer is used to discharge light-curable, wax-like polymerizable material in a layer-by-layer manner to build-up the prosthesis. The methods are particularly useful for making integrated dentures containing a set of artificial teeth. The denture base and set of teeth are made of light-curable, wax-like polymerizable materials comprising a mixture of monomer, oligomer, and light sensitizer. The wax-like materials are dimensionally stable in their uncured states. The denture base and artificial teeth are later light-cured to form a polymerized denture product having high flexural modulus and flexural strength.

Abstract: The invention provides a method of shaping a dental product, comprising: shaping a curable polymerizable composition to form a shape of a dental product. The polymerizable composition is adapted to cure to form polymeric material, which at 37° C. has a flexural modulus of less than 250,000 psi and a flexural strength of less than 7,000 psi.

Abstract: A method for light-curing polymerizable materials to form a dental device is provided. A light-curing apparatus having at least one integrated lighting and heating source, a curing volume, and a temperature controller, preferably a fan, is used in the method. The light source and temperature controller are used to heat a first polymerizable material to temperatures within a first temperature range. A second polymerizable material is applied on or adjacent to the first polymerizable material. The light source and temperature controller are used to heat the second polymerizable material to temperatures within a second temperature range. The first temperature range has a first midpoint and the second temperature range has a second midpoint. The first midpoint temperature is at least 10° C. apart from the second midpoint temperature.

Abstract: A dental device and method of making it, by shaping a first and a second wax-like polymerizable dental material to form a polymerizable dental device.

Abstract: This invention relates to ink-jet printing systems for making dental products such as artificial teeth, dentures, splints, veneers, inlays, onlays, copings, frame patterns, crowns and bridges and the like. An ink-jet printer is used to discharge wax-like polymerizable material in a layer-by-layer manner to build-up the object. In other methods, a heated capillary or dropper can be used to apply the polymerizable material. The resulting three-dimensional object has good dimensional stability. Light irradiation can be used to cure and harden the material, thereby producing the final dental product.

Abstract: A dental device including an integrally connected artificial tooth and denture base. The artificial tooth is made by continuously conveying polymerizable material into tooth forming molds.

Abstract: The invention provides a method of making a dental appliance by shaping a low ball tack polymerizable material. By including fluorescing agent the surfaces of dental appliances are visually identifiable.

Abstract: The invention provides high strength dental polymeric dental products made from wax-like polymerizable dental material. These dental products have superior strength compared to products formed from prior wax-like polymerizable materials. Prior wax-like polymerizable materials do not form strong enough polymeric material for making dentures. High strength dentures are made by positioning artificial teeth in wax-like polymerizable dental material of the invention. This material is then shaped and polymerized to the form a denture base of high strength dental polymeric material. These dentures are completed without forming wax and without applying inorganic plaster to the artificial teeth.

Abstract: A dental product formed by a process and a method of using a denture including providing a denture having an outer face, applying a readily flowable material to the face. The flowable material comprises volatile material and polymeric material. Volatilizing at least a portion of the volatile material from the flowable material to form a readily peelable water swellable solid film. The film is substantially insoluble in water. The film comprising at least 10% by weight of the polymeric material. The denture having an outer face. The film adheres to the face and film effectively not being covalently bonded to the face. The product and method are preferably carried out using an adhesive dispenser including a container, a pump and flowable adhesive. The flowable adhesive is enclosed by the container. The pump is supported by the container and the pump is connected through a conduit to the flowable adhesive.

Abstract: The invention provides a method of shaping a dental product, comprising: shaping a curable polymerizable composition to form a shape of a dental product. The polymerizable composition is adapted to cure to form polymeric material, which at 37° C. has a flexural modulus of less than 250,000 psi and a flexural strength of less than 7,000 psi.