Patents by Inventor Benjamin Katryniok

Benjamin Katryniok has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230112595
    Abstract: The present invention relates to the use of a catalyst made of rhenium oxide supported by cerium oxide, with formula ReOx/CeO2 (I), for catalyzing the deoxydehydration of glycerol to allyl alcohol, the reaction being carried out under heterogeneous conditions in the presence of at least one aliphatic alcohol; and to a method for producing allyl alcohol from glycerol in the presence of the catalyst.
    Type: Application
    Filed: March 24, 2021
    Publication date: April 13, 2023
    Inventors: Benjamin KATRYNIOK, Karen SILVA, Marcia ARAQUE
  • Patent number: 10500567
    Abstract: The present invention relates to the use of rhenium-containing supported heterogeneous catalysts for the deoxydehydration of glycerol to allyl alcohol, as well as to a process for the production of allyl alcohol from glycerol, in the presence of such heterogeneous catalysts.
    Type: Grant
    Filed: July 27, 2016
    Date of Patent: December 10, 2019
    Assignees: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, ECOLE CENTRALE DE LILLE, NATIONAL INSTITUTE
    Inventors: Yoshihiro Kon, Benjamin Katryniok, Franck Dumeignil, Marcia Araque Marin, Sébastien Paul
  • Patent number: 10369551
    Abstract: The present invention relates to the use of haloapatites as catalysts of the dehydration reaction of ?-hydroxylated carboxylic acids or acid esters, in particular of lactic acid or of methyl lactate, and also to a process for producing unsaturated carboxylic acids or acid esters, in particular acrylic acid or methyl acrylate, in the gas phase in a stainless steel reactor, in the presence of such a catalyst.
    Type: Grant
    Filed: December 8, 2015
    Date of Patent: August 6, 2019
    Assignees: ECOLE CENTRALE DE LILLE, UNIVERSITE DE LILLE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Sébastien Paul, Benjamin Katryniok, Franck Dumeignil, Thomas Bonnotte
  • Patent number: 10301245
    Abstract: The present invention relates to the use of molybdenum and vanadium mixed oxides, optionally iron doped, as catalysts for the oxidation of unsaturated alcohols, in particular allyl alcohol, and also to a process for the production of unsaturated carboxylic acids, in particular acrylic acid, in the gas phase, in the presence of such a catalyst.
    Type: Grant
    Filed: June 18, 2015
    Date of Patent: May 28, 2019
    Assignees: Centre National de la Recherche Scientifique, Universite des Sciences et Technologies de Lille 1, Hokkaido University, Ecole Centrale de Lille
    Inventors: Sébastien Paul, Benjamin Katryniok, Franck Dumeignil, Marcia Araque Marin, Toru Murayama, Wataru Ueda
  • Patent number: 10266474
    Abstract: The present invention relates to the use of molybdenum and vanadium mixed oxides, optionally iron doped, as catalysts for the oxidation of unsaturated alcohols, in particular allyl alcohol, and also to a process for the production of unsaturated carboxylic acids, in particular acrylic acid, in the gas phase, in the presence of such a catalyst.
    Type: Grant
    Filed: June 18, 2015
    Date of Patent: April 23, 2019
    Assignees: Centre National De La Recherche Scientifique, Universite Des Sciences et Technologies De Lille 1, Hokkaido University, Ecole Centrale De Lille
    Inventors: Sébastien Paul, Benjamin Katryniok, Franck Dumeignil, Marcia Araque Marin, Toru Murayama, Wataru Ueda
  • Publication number: 20180215696
    Abstract: The present invention relates to the use of molybdenum and vanadium mixed oxides, optionally iron doped, as catalysts for the oxidation of unsaturated alcohols, in particular allyl alcohol, and also to a process for the production of unsaturated carboxylic acids, in particular acrylic acid, in the gas phase, in the presence of such a catalyst.
    Type: Application
    Filed: June 18, 2015
    Publication date: August 2, 2018
    Inventors: Sébastien PAUL, Benjamin KATRYNIOK, Franck DUMEIGNIL, Marcia ARAQUE MARIN, Toru MURAYAMA, Wataru UEDA
  • Publication number: 20180207618
    Abstract: The present invention relates to the use of rhenium-containing supported heterogeneous catalysts for the deoxydehydration of glycerol to allyl alcohol, as well as to a process for the production of allyl alcohol from glycerol, in the presence of such heterogeneous catalysts.
    Type: Application
    Filed: July 27, 2016
    Publication date: July 26, 2018
    Inventors: Yoshihiro KON, Benjamin KATRYNIOK, Franck DUMEIGNIL, Marcia ARAQUE MARIN, Sébastien PAUL
  • Publication number: 20170341061
    Abstract: The present invention relates to the use of haloapatites as catalysts of the dehydration reaction of ?-hydroxylated carboxylic acids or acid esters, in particular of lactic acid or of methyl lactate, and also to a process for producing unsaturated carboxylic acids or acid esters, in particular acrylic acid or methyl acrylate, in the gas phase in a stainless steel reactor, in the presence of such a catalyst.
    Type: Application
    Filed: December 8, 2015
    Publication date: November 30, 2017
    Inventors: Sébastien PAUL, Benjamin KATRYNIOK, Franck DUMEIGNIL, Thomas BONNOTTE
  • Patent number: 9676705
    Abstract: A compound of the formula SbxFe1Oy (I) in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive, may be used as a catalyst for catalyzing the ammoxidation reaction of an alcohol of following formula (II) CH2?C(R1)—CH2—OH (II) in which R1 represents a hydrogen atom or a methyl radical, to give nitrile of following formula (III) CH2?C(R1)—C?N (III) in which R1 has the same meaning as in above formula (II), the said reaction being carried out in the gas phase, the said gas phase comprising at least oxygen and ammonia. The present invention also relates to the process for the ammoxidation of an alcohol of formula (II) employing a compound of formula (I) as catalyst.
    Type: Grant
    Filed: April 16, 2014
    Date of Patent: June 13, 2017
    Assignees: ECOLE CENTRALE DE LILLE, UNIVERSITE DES SCIENCES ET TECHNOLOGIES D
    Inventors: Sebastien Paul, Benjamin Katryniok, Franck Dumeignil, Carsten Liebig, Wolfgang Holderich, Cyrille Guillon
  • Patent number: 9522898
    Abstract: The present invention concerns a process for the production of an aldehyde compound by an oxidation reaction of an alcohol compound in the presence of a mesostructured vanadium phosphorus mixed oxide catalyst, at a temperature comprised between 50° C. and 200° C., in presence of an oxidant. The reaction medium may also comprise a solvent.
    Type: Grant
    Filed: February 5, 2014
    Date of Patent: December 20, 2016
    Assignees: RHODIA OPERATIONS, CENTRE NATIONAL DE LA RECHERECHE SCIENTIFIQUE
    Inventors: Jean-Marc Clacens, Floryan Decampo, Fabien Grasset, Benjamin Katryniok, Franck Dumeignil, Sebastien Paul, Veronique Rataj
  • Publication number: 20160023995
    Abstract: A compound of the formula SbxFe1Oy (1) in which x varies from 0.4 to 1 inclusive and y varies from 1.6 to 4 inclusive, may be used as a catalyst for catalysing the ammoxidation reaction of an alcohol of following formula (II) CH2?C(R1)—CH2—OH (II) in which R1 represents a hydrogen atom or a methyl radical, to give nitrile of following formula (III) CH2?C(R1)—C?N (III) in which R1 has the same meaning as in above formula (ii), the said reaction being carried out in the gas phase, the said gas phase comprising at least oxygen and ammonia. The present invention also relates to the process for the ammoxidation of an alcohol of formula (II) employing a compound of formula (I) as catalyst.
    Type: Application
    Filed: April 16, 2014
    Publication date: January 28, 2016
    Inventors: Sebastien Paul, Benjamin Katryniok, Franck Dumeignil, Carsten Liebig, Wolfgang Holderich, Cyrille Guillon
  • Publication number: 20150368218
    Abstract: The present invention concerns a process for the production of an aldehyde compound by an oxidation reaction of an alcohol compound in the presence of a mesostructured vanadium phosphorus mixed oxide catalyst, at a temperature comprised between 50° C. and 200° C., in presence of an oxidant. The reaction medium may also comprise a solvent.
    Type: Application
    Filed: February 5, 2014
    Publication date: December 24, 2015
    Inventors: Jean-Marc CLACENS, Floryan DECAMPO, Fabien GRASSET, Benjamin KATRYNIOK, Franck DUMEIGNIL, Sebastien PAUL, Veronique RATAJ
  • Patent number: 8604234
    Abstract: The invention relates to a method for preparing acrolein from glycerol or glycerin, according to which dehydration of glycerol or glycerin is carried out in the presence of a catalyst which consists in at least one silica modified with zirconium dioxide, titanium dioxide or tungsten trioxide or any combination of these oxides, and a heteropolyacid. This method may be used for making 3-(methylthio)propionic aldehyde (MMP), 2-hydroxy-4-methylthiobutyronitrile (HMBTN), methionine or its analogs, from acrolein.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: December 10, 2013
    Assignees: Adisseo France S.A.S., Centre National de la Recherche Scientifique, Universite Lille 1-Sciences et Technologies
    Inventors: Sebastien Paul, Benjamin Katryniok, Franck Dumeignil, Mickael Capron
  • Publication number: 20120330049
    Abstract: The invention relates to a method for preparing acrolein from glycerol or glycerin, according to which dehydration of glycerol or glycerin is carried out in the presence of a catalyst which consists in at least one silica modified with zirconium dioxide, titanium dioxide or tungsten trioxide or any combination of these oxides, and a heteropolyacid. This method may be used for making 3-(methylthio)propionic aldehyde (MMP), 2-hydroxy-4-methylthiobutyronitrile (HMBTN), methionine or its analogs, from acrolein.
    Type: Application
    Filed: December 21, 2010
    Publication date: December 27, 2012
    Applicants: ADISSEO FRANCE S.A.S., UNIVERSITE LILLE 1 - SCIENCES ET TECHNOLOGIES, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
    Inventors: Sebastien Paul, Benjamin Katryniok, Franck Dumeignil, Mickael Capron