Abstract: A hybrid metal composite (HMC) structure comprises a first tier comprising a first fiber composite material structure, a second tier longitudinally adjacent the first tier and comprising a first metallic structure and a second fiber composite material structure laterally adjacent the first metallic structure, a third tier longitudinally adjacent the second tier and comprising a third fiber composite material structure, and a fourth tier longitudinally adjacent the third tier and comprising a second metallic structure and a fourth fiber composite material structure laterally adjacent the second metallic structure. At least one lateral end of the second metallic structure is laterally offset from at least one lateral end of the first metallic structure most proximate thereto. Methods of forming an HMC structure, and related rocket motors and multi-stage rocket motor assemblies are also disclosed.

Abstract: A multi-component structure includes a first hybrid metal composite structure, a second hybrid metal composite structure, and a joint structure. The first and second hybrid metal composite structures include layers, each layer comprising a fiber composite material structure including a fiber material dispersed within a matrix material and at least one metal ply located between layers of the layers. The joint structure extends between and connects the first hybrid metal composite structure and the second hybrid metal composite structure. Additionally, the joint structure exerts a clamping force on the first and second hybrid metal composite structures and to reduce gaps between the layers, between the layers and the at least one metal ply, and between the joint structure and the first and second hybrid metal composite structures to less than half a thickness of the at least one metal ply.

Abstract: A preceramic resin formulation comprising a polycarbosilane preceramic polymer, an organically modified silicon dioxide preceramic polymer, and, optionally, at least one filler. The preceramic resin formulation is formulated to exhibit a viscosity of from about 1,000 cP at about 25° C. to about 5,000 cP at a temperature of about 25° C. The at least one filler comprises first particles having an average mean diameter of less than about 1.0 ?m and second particles having an average mean diameter of from about 1.5 ?m to about 5 ?m. Impregnated fibers comprising the preceramic resin formulation are also disclosed, as is a composite material comprising a reaction product of the polycarbosilane preceramic polymer, organically modified silicon dioxide preceramic polymer, and the at least one filler. Methods of forming a ceramic matrix composite are also disclosed.

Abstract: An insulation material includes a matrix comprising a reaction product formed from a silicon carbide precursor resin and a silicon dioxide precursor resin. At least one filler, such as hollow glass microspheres and/or carbon fiber is dispersed within the matrix. A rocket motor includes a case, the insulation material within and bonded to the case, and a solid propellant within the case. An insulation precursor includes a silicon carbide precursor resin, a silicon dioxide precursor resin, and the at least one filler. Related methods are also disclosed.

Abstract: A precursor composition comprising, before cure, an acrylic ethylene monomer (AEM), a foaming agent, and one or more of a strengthening additive, a thermal ablation additive, or a reflectivity additive. The precursor composition is cured to form a protective article comprising a foamed protective material. A method of forming a protective article is also disclosed, as is an aerospace structure comprising the foamed protective material.

Abstract: A preceramic resin formulation comprising a polycarbosilane preceramic polymer and an organically modified silicon dioxide preceramic polymer. A ceramic material comprising a reaction product of the polycarbosilane preceramic polymer and organically modified silicon dioxide preceramic polymer is also described. Articles comprising the ceramic material are also described, as are methods of forming the preceramic resin formulation and the ceramic material.

Abstract: A barrier coating resin formulation comprising at least one polycarbosilane preceramic polymer, at least one organically modified silicon dioxide preceramic polymer, at least one filler, and at least one solvent. A barrier coating comprising a reaction product of the at least one polycarbosilane preceramic polymer and the at least one organically modified silicon dioxide preceramic polymer and the at least one filler is also disclosed, as are articles comprising the barrier coating, rocket motors comprising the barrier coating, and methods of forming the articles.

Abstract: An insulation material includes a matrix comprising a reaction product formed from a silicon carbide precursor resin and a silicon dioxide precursor resin. At least one filler, such as hollow glass microspheres and/or carbon fiber is dispersed within the matrix. A rocket motor includes a case, the insulation material within and bonded to the case, and a solid propellant within the case. An insulation precursor includes a silicon carbide precursor resin, a silicon dioxide precursor resin, and the at least one filler. Related methods are also disclosed.

Abstract: A preceramic resin formulation comprising a polycarbosilane preceramic polymer, an organically modified silicon dioxide preceramic polymer, and, optionally, at least one filler. The preceramic resin formulation is formulated to exhibit a viscosity of from about 1,000 cP at about 25° C. to about 5,000 cP at a temperature of about 25° C. The at least one filler comprises first particles having an average mean diameter of less than about 1.0 ?m and second particles having an average mean diameter of from about 1.5 ?m to about 5 ?m. Impregnated fibers comprising the preceramic resin formulation are also disclosed, as is a composite material comprising a reaction product of the polycarbosilane preceramic polymer, organically modified silicon dioxide preceramic polymer, and the at least one filler. Methods of forming a ceramic matrix composite are also disclosed.

Abstract: A preceramic resin formulation comprising a polycarbosilane preceramic polymer and an organically modified silicon dioxide preceramic polymer. A ceramic material comprising a reaction product of the polycarbosilane preceramic polymer and organically modified silicon dioxide preceramic polymer is also described. Articles comprising the ceramic material are also described, as are methods of forming the preceramic resin formulation and the ceramic material.

Abstract: A hybrid metal composite (HMC) structure comprises a first tier comprising a first fiber composite material structure, a second tier longitudinally adjacent the first tier and comprising a first metallic structure and a second fiber composite material structure laterally adjacent the first metallic structure, a third tier longitudinally adjacent the second tier and comprising a third fiber composite material structure, and a fourth tier longitudinally adjacent the third tier and comprising a second metallic structure and a fourth fiber composite material structure laterally adjacent the second metallic structure. At least one lateral end of the second metallic structure is laterally offset from at least one lateral end of the first metallic structure most proximate thereto. Methods of forming an HMC structure, and related rocket motors and multi-stage rocket motor assemblies are also disclosed.

Abstract: A method of forming a hybrid metal composite structure including at least one metal ply. The method includes forming at least one metal ply, forming the at least one metal ply comprising forming at least one perforation in the at least one metal ply, abrasively blasting at least one surface of the at least one metal ply to coarsen the at least one surface of the metal ply, and exposing the at least one metal ply to at least one of an acid or a base. The method further includes disposing at least one fiber composite material structure adjacent the at least one metal ply. Related methods of forming a portion of a rocket case and related hybrid metal composite structures are also disclosed.

Abstract: A hybrid metal composite (HMC) structure comprises tiers comprising fiber composite material structures, and additional tiers longitudinally adjacent one or more of the tiers and comprising perforated metallic structures and additional fiber composite material structures laterally adjacent the perforated metallic structures. Methods of forming an HMC structure, and related rocket motors and multi-stage rocket motor assemblies are also disclosed.

Abstract: A roller (33) includes an exterior layer (39) including one or more polymers, carbon black and an ionic salt soluble in a low molecular weight hydrocarbon oil.