Patents by Inventor Benoît De Gaudemaris
Benoît De Gaudemaris has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10676542Abstract: A modified diene elastomer having a good flow resistance, and imparting to a rubber composition containing the same a good compromise of hysteresis and abrasion properties and a satisfactory processing with a view to a tire application is provided. This modified elastomer comprises: a) at least 70% by weight of a linear diene elastomer predominantly functionalized in the middle of the chain by an alkoxysilane group, optionally partly or completely hydrolyzed to silanol, the alkoxysilane group optionally bearing another function capable of interacting with a reinforcing filler, the silicon atom of the alkoxysilane group lying in the main chain of the diene elastomer; b) more than 0 and up to 30% by weight of a star-branched diene elastomer, the Mooney viscosity of said modified diene elastomer varying from 50 to 80 and the glass transition temperature (Tg) thereof varying from ?100° C. to ?80° C.Type: GrantFiled: October 7, 2016Date of Patent: June 9, 2020Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Charlotte Dire, Florent Vaultier, Gaël Courbes, Benoit De-Gaudemaris
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Publication number: 20200157322Abstract: A rubber composition is based on at least: from 60 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, exhibiting a Tg within a range extending from ?110° C. to ?70° C., chosen from butadiene homopolymers, copolymers of butadiene and of vinylaromatic monomer, exhibiting a content of vinylaromatic unit of between 0% and 5% by weight, and the mixtures of these; a reinforcing filler; crosslinking system; and from 50 to 150 phr of at least one hydrocarbon resin predominantly composed of units resulting from ?-pinene monomers, the resin exhibiting an aliphatic proton content of greater than 95%.Type: ApplicationFiled: April 13, 2018Publication date: May 21, 2020Inventors: BENOIT DE GAUDEMARIS, JUSTIN BELZ
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Publication number: 20200123351Abstract: A rubber composition based on at least a reinforcing filler, a crosslinking system, a plasticizing system and an elastomer matrix is provided. The elastomer matrix includes at least one modified diene elastomer comprising within its structure at least one alkoxysilane group, which is optionally partially or totally hydrolysed to silanol, bonded to the elastomer by the silicon atom. The alkoxysilane group optionally bears another function bonded to the silicon atom directly or by means of a spacer group. The modified diene elastomer is such that, before modification, the diene elastomer has a polydispersity index of at least 1.1 and at most 1.6, and has a Mooney viscosity ranging from 50 to 80 and a glass transition temperature (Tg) of strictly less than ?50° C., preferably less than or equal to ?60° C., and greater than or equal to ?110° C.Type: ApplicationFiled: December 19, 2017Publication date: April 23, 2020Applicant: Compagnie Generale des Etablissements MichelinInventors: Marie-Laure FRANCOIS, Bênoit DE-GAUDEMARIS
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Publication number: 20190367707Abstract: A rubber composition based on at least: from 50 to 100 phr of one or more diene elastomers, referred to as very low glass transition temperature (Tg) diene elastomers, having a Tg within a range of from ?110° C. to ?70° C., selected from butadiene homopolymers, copolymers of butadiene and of a vinylaromatic monomer, having a content of vinylaromatic units of between 0 and 5% by weight, and mixtures thereof a reinforcing filler a crosslinking system; and from 50 to 150 phr of at least one hydrocarbon resin predominantly composed of units derived from terpene and phenol monomers, the resin having a content of aromatic protons of greater than 15%.Type: ApplicationFiled: December 5, 2017Publication date: December 5, 2019Inventors: BENOIT DE GAUDEMARIS, ALAIN HUT
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Publication number: 20190077887Abstract: A modified diene elastomer having a good flow resistance, and imparting to a rubber composition containing the same a good compromise of hysteresis and abrasion properties and a satisfactory processing with a view to a tire application is provided. This modified elastomer comprises: a) at least 70% by weight of a linear diene elastomer predominantly functionalized in the middle of the chain by an alkoxysilane group, optionally partly or completely hydrolyzed to silanol, the alkoxysilane group optionally bearing another function capable of interacting with a reinforcing filler, the silicon atom of the alkoxysilane group lying in the main chain of the diene elastomer; b) more than 0 and up to 30% by weight of a star-branched diene elastomer, the Mooney viscosity of said modified diene elastomer varying from 50 to 80 and the glass transition temperature (Tg) thereof varying from ?100° C. to ?80° C.Type: ApplicationFiled: October 7, 2016Publication date: March 14, 2019Applicant: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Charlotte DIRE, Florent VAULTIER, Gaël COURBES, Benoit DE-GAUDEMARIS
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Publication number: 20180340055Abstract: A rubber composition is based on at least one elastomer, a reinforcing filler, a crosslinking system and an optionally hydrogenated hydrocarbon-based resin, predominantly composed of units selected from the group consisting of cyclopentadiene, dicyclopentadiene, methylcyclopentadiene and mixtures thereof, said hydrocarbon-based resin having an average molecular weight Mz of less than 2000 g/mol and a glass transition temperature Tg, expressed in ° C., such that: Tg?80?2*(% HA), wherein % HA represents the content of aromatic protons of said resin, the content of said hydrocarbon-based resin being within a range extending from 15 to 150 phr.Type: ApplicationFiled: October 14, 2016Publication date: November 29, 2018Inventors: Benoit DE GAUDEMARIS, Alain HUT
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Publication number: 20180001702Abstract: A rubber composition is based on at least one diene elastomer, a reinforcing filler, a crosslinking system and a hydrocarbon-based resin. The hydrocarbon-based resin has a number-average molecular weight (Mn) of between 700 and 1000 g/mol, an average molecular weight Mz of greater than 6000 g/mol and a polydispersity index (PI) of greater than 2.4.Type: ApplicationFiled: December 18, 2015Publication date: January 4, 2018Inventors: JULIEN CHATARD, BENOIT DE GAUDEMARIS, ALAIN HUT, FABIEN HELLOT, FRANCOIS DIMIER
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Publication number: 20170204257Abstract: A tire tread comprises a rubber composition based on at least: an elastomer matrix comprising more than 50% by weight of a solution SBR bearing a silanol function at the chain end, a reinforcing filler present at a content of between 40 and 80 phr, which reinforcing filler comprises between 40 and 80 phr of a silica, a coupling agent for coupling the silica to the solution SBR, 10 to 50 phr of a hydrocarbon-based resin having a Tg of greater than 20° C., and 0 to less than 5 phr of a liquid plasticizer. Such a tire has a good performance compromise between rolling resistance and grip.Type: ApplicationFiled: May 27, 2015Publication date: July 20, 2017Inventors: PHILIPPE LABRUNIE, BENOIT DE GAUDEMARIS
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Publication number: 20170204256Abstract: A tire tread comprises a rubber composition based on at least: an elastomer matrix comprising more than 50% by weight of a solution SBR bearing a silanol function and an amine function, a reinforcing filler present at a content of between 40 and 80 phr, which reinforcing filler comprises between 40 and 80 phr of a silica, a coupling agent for coupling the silica to the solution SBR, 10 to 50 phr of a hydrocarbon-based resin having a Tg of greater than 20° C., and 0 to less than 5 phr of a liquid plasticizer. Such a tire has a good performance compromise between rolling resistance and wet grip.Type: ApplicationFiled: May 27, 2015Publication date: July 20, 2017Inventors: PHILIPPE LABRUNIE, BENOIT DE GAUDEMARIS
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Patent number: 9637601Abstract: The invention relates to a process for the preparation of a masterbatch of diene elastomer and reinforcing inorganic filler in accordance with the invention comprises the following successive stages: bringing into contact and mixing one or more aqueous dispersions (B) of one or more hydrophobized reinforcing inorganic fillers, which coagulate(s) spontaneously with the said latex, and one or more diene elastomer latexes (A) in order to obtain a coagulum, without requiring a coagulating agent, recovery of the coagulum, then drying the recovered coagulum in order to obtain the masterbatch.Type: GrantFiled: December 21, 2011Date of Patent: May 2, 2017Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventors: Jérôme Bibette, Fernando Martinez Pedrero, Benoît De Gaudemaris, Julien Berriot
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Patent number: 9512281Abstract: The invention relates to a process for the preparation of a masterbatch in the liquid phase based on one or more diene elastomer latexes and on one or more fillers, comprising the following successive stages: preparation of a stable and homogeneous aqueous dispersion by mixing one or more diene elastomer latexes with one or more stable aqueous dispersions of one or more fillers, the said fillers; homogenization of the aqueous dispersion, coagulation within the aqueous dispersion of the said diene elastomer latex or latexes with the filler or fillers by supplying mechanical energy, recovery of the coagulum, drying the recovered coagulum in order to obtain the masterbatch.Type: GrantFiled: December 21, 2011Date of Patent: December 6, 2016Assignees: COMPAGNIE GENERALE DES ESTABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventors: Jérôme Bibette, Fernando Martinez Pedrero, Benoît De Gaudemaris, Julien Berriot
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Patent number: 9505890Abstract: Method for preparing a silica/natural rubber masterbatch, including: doping the silica with magnesium; preparing at least one dispersion of the resulting doped silica in water; bringing a natural rubber field latex into contact with the aqueous doped-silica dispersion and mixing them together so as to obtain a coagulum; recovering the coagulum; and drying the recovered coagulum so as to obtain the masterbatch.Type: GrantFiled: October 10, 2012Date of Patent: November 29, 2016Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.Inventors: Benoit De Gaudemaris, Geraldine Laffargue, Julien Berriot
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Patent number: 9499730Abstract: A rubber composition based on at least one diene elastomer, a filler that contains carbon black and an inorganic filler, and a crosslinking system, wherein the inorganic filler content is greater than or equal to 5 parts by weight per hundred parts by weight of elastomer, phr, and represents at most 50% as a weight fraction of the whole of the total filler of the composition, and wherein the carbon black includes at least one acetylene-derived carbon black, with a content of greater than 3 phr, the amount of acetylene-derived carbon black representing more than 50% of the carbon black present in the composition as a weight fraction, and wherein the composition contains a plasticizing oil or a plasticizing resin with a total content of plasticizing oil and plasticizing resin of less than 30 phr.Type: GrantFiled: June 10, 2013Date of Patent: November 22, 2016Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.Inventors: Aurelie Joseph, Jr., Benoit De Gaudemaris, Marc Sevignon
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Publication number: 20160319116Abstract: The present invention relates to a tire tread that comprises a rubber composition based on at least: an elastomer matrix comprising more than 50 wt % of a first diene elastomer bearing a silanol function and a pendent amine function; a silica at a level between 120 and 140 phr; a coupling agent; and a plasticizer system comprising a hydrocarbon-containing resin having a Tg above 20° C. according to a content A ranging from 5 to 60 phr, a hydrocarbon-containing resin having a Tg above 20° C. and a liquid plasticizer according to a content B ranging from 0 to 60 phr, a liquid plasticizer, it being understood that the total level A+B is at least equal to 60 phr, preferably ranging from 60 to 90 phr. The tread according to the invention makes it possible to improve the compromise between wet grip and dry grip of a tire with low rolling resistance.Type: ApplicationFiled: December 9, 2014Publication date: November 3, 2016Inventors: PHILIPPE LABRUNIE, BENOÏT DE GAUDEMARIS
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Patent number: 9290626Abstract: Preparation of a masterbatch of diene elastomer and silica including preparing at least one silica dispersion in water; bringing into contact and mixing an elastomer latex and the aqueous silica dispersion in the presence of a calcium salt in order to obtain a coagulum; and recovering the coagulum and drying the recovered coagulum in order to obtain the masterbatch. The molar content of calcium cations, defined as the number of moles of calcium cations of the calcium salt per BET unit area of the silica, is between 1.19*10?6 and 2.81*10?6 mol/m2.Type: GrantFiled: October 10, 2012Date of Patent: March 22, 2016Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventors: Benoit De Gaudemaris, Geraldine Laffargue, Julien Berriot
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Patent number: 9290627Abstract: Preparation of a masterbatch of diene elastomer and silica including preparing at least one silica dispersion in water; bringing into contact and mixing an elastomer latex and the aqueous silica dispersion in the presence of a metal salt having an at least divalent metal element, in order to obtain a coagulum; and recovering the coagulum and drying same in order to obtain the masterbatch. The metal cation molar ration, defined as the number of moles of metal cations of the metal salt per BET unit area of the silica, is between 9.375*10?7 and 1.875*10?5 mol/m2.Type: GrantFiled: October 10, 2012Date of Patent: March 22, 2016Assignees: Compagnie Generale des Establissements Michelin, Michelin Recherche et Technique S.A.Inventors: Benoit De Gaudemaris, Geraldine Laffargue, Julien Berriot
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Patent number: 9284420Abstract: Preparation of a masterbatch of diene elastomer and silica including preparing at least one silica dispersion in water; bringing into contact and mixing an elastomer latex and the aqueous silica dispersion in the presence of a metal salt in order to obtain a coagulum; and recovering the coagulum and drying the recovered coagulum in order to obtain the masterbatch. The molar content of zinc cations, defined as the number of moles of zinc cations of the zinc salt per BET unit area of the silica, is between 1.19*10?6 and 5.62*10?6 mol/m2.Type: GrantFiled: October 10, 2012Date of Patent: March 15, 2016Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.Inventors: Benoit De Gaudemaris, Geraldine Laffargue, Julien Berriot
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Patent number: 9175144Abstract: The invention relates to a method for preparing a silica/natural rubber masterbatch, comprising the following successive steps: doping the silica with an at least divalent metallic element; preparing at least one dispersion of the resulting doped silica in water; bringing a natural rubber field latex into contact with the aqueous doped-silica dispersion and mixing them together so as to obtain a coagulum; recovering the coagulum; and drying the recovered coagulum so as to obtain the masterbatch.Type: GrantFiled: October 25, 2010Date of Patent: November 3, 2015Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventors: Julien Berriot, Benoit De Gaudemaris, Géraldine Laffargue
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Patent number: 9145489Abstract: The invention relates to a process for the preparation of a masterbatch in the liquid phase based on one or more diene elastomers and on one or more fillers which do not coagulate spontaneously with the said latex, comprising the following successive stages: preparation of a stable and homogeneous aqueous dispersion (C) by mixing one or more diene elastomer latexes (A) with one or more stable aqueous dispersions (B) of one or more fillers which do not coagulate spontaneously with the said latex and which are partially hydrophobized, homogenization of the aqueous dispersion (C), coagulation within the aqueous dispersion (C) of the diene elastomer latex with the fillers which do not coagulate spontaneously with the said latex by supplying mechanical energy, recovery of the coagulum, then drying the recovered coagulum in order to obtain the masterbatch.Type: GrantFiled: December 21, 2011Date of Patent: September 29, 2015Assignees: COMPAGNIE GENERAL DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUEInventors: Jérôme Bibette, Fernando Martinez Pedrero, Benoît De Gaudemaris, Julien Berriot
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Publication number: 20150267008Abstract: The invention relates to a process for the preparation of a masterbatch of diene elastomer and reinforcing inorganic filler in accordance with the invention comprises the following successive stages: bringing into contact and mixing one or more aqueous dispersions (B) of one or more hydrophobized reinforcing inorganic fillers, which coagulate(s) spontaneously with the said latex, and one or more diene elastomer latexes (A) in order to obtain a coagulum, without requiring a coagulating agent, recovery of the coagulum, then drying the recovered coagulum in order to obtain the masterbatch.Type: ApplicationFiled: December 21, 2011Publication date: September 24, 2015Applicant: Michelin Recherche et Technique S.A.Inventors: Jérôme Bibette, Fernando Martinez Pedrero, Benoît De Gaudemaris, Julien Berriot