Abstract: Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyl diphenylalkanes Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn of less than 1.60.

Abstract: The present invention concerns a method of manufacturing a graded index plastic optical fiber having an index that varies continuously between the center and the periphery of the fiber, from at least one polymer P and at least one reactive diluent D1 to allow the refractive index of said fiber to be varied.

Abstract: Functionalized fluoromonomers corresponding to the following chemical formula: CF2?CF—(CH2)3—Si(OR)3 with R=methyl or ethyl group (I); process for the synthesis of these monomers; copolymers based on these monomers and on VF2 and crosslinking of these polymers in the presence of water.

Abstract: Radical polymerization process for the preparation of halogenated polymers and block copolymers. Halogenated polymers and block copolymers.

Abstract: Multilayer polymer structures comprising a layer (A) based on at least one halohydrocarbon polymer linked to a layer (C) based on at least one olefin polymer via a layer (B) containing from 100% to 10% by weight of at least one grafted olefin polymer and from 0 to 90% by weight of at least one halohydrocarbon polymer, the grafted olefin polymer being obtained by grafting a polymerizable monomer, a functional oligomer or a functional telomer onto a preactivated olefin polymer; process for obtaining them and use thereof.

Abstract: The present invention describes synthesis of new fluorinated elastomers presenting very low glass transition temperatures, a good resistance to bases, petroleum and fuels and good properties for forming. These elastomers contain, by way of example, from 90 to 50 mole % of vinylidene fluoride (VDF) and from 10 to 50 molar % of perfluoromethyl vinyl ether (PMVE). In this precise case, they are prepared by radical copolymerisation of VDF and with PMVE in presence of various organic initiators such as for example the peroxides, the peresters or the diazo compounds.

Abstract: Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyldiphenylalkanes. Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw, ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn, of less than 1.60.

Abstract: A hydrophilic polymer with improved biodegradability and particular usefulness in detergent compositions contains units derived by polymerization from at least one monomers A bearing a carboxylic acid function or an equivalent function, units derived by polymerization from at least one monomers B bearing an electron-rich group or a function capable of introducing an electron-rich group into the main chain, and, optionally, units derived by polymerization from at least one monomers C which is copolymerizable with A and B, but is different from A and B. Examples of suitable monomers as monomers A include maleic anhydride, acrylic acid, methacrylic acid, itaconic acid, fumaric acid and maleic acid, and the salts thereof. Examples of suitable monomers as monomers B include butadiene, isoprene, chloroprene, dimethylbutadiene, cyclohexadiene, butadienecarboxylic acid, butadienedicarboxylic acid, acetylene, acetylenecarboxylic acid and acetylenedicarboxylic acid.

Abstract: A subject-matter of the invention is a copolymer comprising at least 3 units, P1, P2 and P3, with the following general formulae: with X1, X2 and X3, which are identical or different, taken from the group of atoms consisting of H, F, Cl and Br; with R1 taken from the group of atoms consisting of H, F, Cl and Br; with R2 a carbonaceous group comprising from 1 to 10 partially or completely fluorinated carbon atoms; with Y1 and Y2, which are identical or different, taken either from the group of atoms consisting of H, F, Cl and Br or from the family of the carbonaceous groups comprising from 1 to 10 carbon atoms; with Y3 a carbonyl group or a divalent carbonaceous group; the content of P2 unit in the copolymer being between 30 and 70 mol % for respectively a content of P1 and P3 units in the copolymer of between 70 and 30 mol % and the weight-average molar mass (Mw) of the said copolymer being between 103 and 106 g/mol. Preferably, the copolymer is of CTFE/VCA/HFP or TFE/VCA/HFP type.

Abstract: The present invention concerns a method of manufacturing a graded index plastic optical fiber having an index that varies continuously between the center and the periphery of the fiber, from at least one polymer P and at least one reactive diluent D1 to allow the refractive index of said fiber to be varied.

Abstract: The present invention concerns a method of manufacturing a plastic optical fiber from at least one polymer P, said method being characterized in that said polymer P is a copolymer comprising at least two repeating units P1 and P2 with the following general formulae, i and j corresponding to a repeat number of units: said copolymer P being transparent, amorphous in nature and having a motif P2 content in the range from substantially 30 mole % to 70 mole % when X?F or Cl in P1.

Abstract: Novel biodegradable polymers consisting of a biodegradable core bound to at least two carboxylic polyacid-based branches via a bond capable of being broken by hydrolysis or by oxidation are described. Biodegradable detergent compositions containing such polymers are also described.

Abstract: Functional trifluorovinyl monomers and their copolymerization with fluoroolefins Functional trifluorovinyl monomers, process for the copolymerization of trifluorovinyl monomers with fluoroolefins and use of these trifluorovinyl monomers in forming fluoroelastomers.

Abstract: A hydrophilic polymer with improved biodegradability and particular usefulness in detergent compositions contains units derived by polymerization from at least one monomers A bearing a carboxylic acid function or an equivalent function, units derived by polymerization from at least one monomers B bearing an electron-rich group or a function capable of introducing an electron-rich group into the main chain, and, optionally, units derived by polymerization from at least one monomers C which is copolymerizable with A and B, but is different from A and B. Examples of suitable monomers as monomers A include maleic anhydride, acrylic acid, methacrylic acid, itaconic acid, fumaric acid and maleic acid, and the salts thereof. Examples of suitable monomers as monomers B include butadiene, isoprene, chloroprene, dimethylbutadiene, cyclohexadiene, butadienecarboxylic acid, butadienedicarboxylic acid, acetylene, acetylenecarboxylic acid and acetylenedicarboxylic acid.

Abstract: Functional trifluorovinyl monomers, process for the copolymerization of trifluorovinyl monomers with fluoroolefins and use of these trifluorovinyl monomers in forming fluoroelastomers. Copolymers resulting from this copolymerization process and process for crosslinking these copolymers.

Abstract: Olefin-based copolymers made affine by grafting, characterised in that they are composed of:

Abstract: The invention comprises a vinylene carbonate (VCA) copolymer having as comonomer chlorotrifluoroethylene (CTFE) or tetrafluoroethylene (TFE). This copolymer is transparent, making possible the preparation of objects acting as guide or conductor for light with wavelengths of visible or near infrared type. Furthermore, it exhibits a glass transition temperature of greater than 60° C. which is appropriate for the preparation of optical fibers.

Abstract: The present invention comprises a transparent and partially fluorinated polymer which comprises three repeat units resulting from industrial monomers which are simple to access and which has a glass transition temperature of greater than 25° C., which polymer makes possible the preparation of articles, in particular of articles acting as guide or conductor for light in the region of the wavelengths of visible or near infrared type. This polymer is of use in the manufacture of optical fiber.

Abstract: The invention concerns a method for obtaining an electrooptic material characterised in that it consists in depositing on a substrate a solution of oligoimides whereon are grafted colouring agents capable of being oriented and in performing a treatment designed to cross-link the oligoimides and to provide orientation to the colouring agents.

Abstract: Multilayer polymer structures comprising a layer (A) based on at least one halohydrocarbon polymer linked to a layer (C) based on at least one olefin polymer via a layer (B) containing from 100% to 10% by weight of at least one grafted olefin polymer and from 0 to 90% by weight of at least one halohydrocarbon polymer, the grafted olefin polymer being obtained by grafting a polymerizable monomer, a functional oligomer or a functional telomer onto a preactivated olefin polymer; process for obtaining them and use thereof.