Abstract: A microwave oven, in particular for rapid heating to high temperature, is disclosed. A cylindrical metal housing is open at one end and has a cylindrical side wall, into which a waveguide opens, the waveguide being coupled to a microwave generator. A first outer layer of a thermally insulative, microwave-transparent material and a second inner layer thereof are provided in a coaxial configuration. A metal sleeve provided with plural coupling slots is interposed between the outer and inner layers. A muff of a microwave-absorbing material is received within a central opening of the inner layer and constitutes a heating enclosure. A metal plate fitted with an access door is provided for closing the open end of the housing. An infrared pyrometer or a thermocouple may be provided for measuring temperatures in the heating enclosure. The heating enclosure may have a vent for evacuating fumes and an orifice for injecting gases.