Patents by Inventor Bernard Gilg

Bernard Gilg has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6228911
    Abstract: The invention relates to a composition comprising a) a styrene, &agr;-methylstyrene or p-methylstyrene homo- or copolymer; b) a bromine-containing flame retardant; c) a UV absorber; d) a sterically hindered amine and e) an epoxidized fatty acid. This invention also relates to the use of the light stabilizer mixture consisting of the components c), d) and e) for light-stabilizing a styrene, &agr;-methylstyrene or p-methylstyrene homo- or copolymer finished with a bromine-containing flame retardant as well as to a process for the light-stabilization thereof. Adding an epoxidized fatty acid to a UV absorber and a sterically hindered amine in styrene, &agr;-methylstyrene or p-methylstyrene homo- or copolymer finished with bromine-containing flame retardants results in an unexpected synergistic effect in the light stability. In particular, it is possible to markedly reduce the discoloration of the finished polymer which takes place in the course of irradiation.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: May 8, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Bernard Gilg
  • Patent number: 6060545
    Abstract: Organic materials having excellent stability against oxidative, thermal or light-induced degradation comprise as stabilisers (i) at least one compound of formula I ##STR1## wherein the general symbols are as defined in claim 1, and (ii) calcium lactate and/or calcium stearoyl-2-lactylate.
    Type: Grant
    Filed: September 23, 1998
    Date of Patent: May 9, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Bernard Gilg
  • Patent number: 5772921
    Abstract: The present invention relates to synergistic mixtures of at least one 2,4-dimethyl-6-s-alkyl phenol and at least one selected sterically hindered phenol according to formula II ##STR1## The variable "n" is 1, 2 or 4. X.sub.1 is tert-butyl. X.sub.2 is C.sub.1 -C.sub.4 alkyl. X.sub.3, when n is 1, is C.sub.1 -C.sub.20 alkyl, a triazinylamino group, or a --A.sub.1 --COO--A.sub.2 or --A.sub.1 --CONH--A.sub.2 group. X.sub.3, when n is 2, is a --E.sub.1 --COO--E.sub.2 --OOC--E.sub.3 -- or --E.sub.1 --CONH--E.sub.2 --NHCO--E.sub.3 -- group. X.sub.3, when n is 4, is ?--G.sub.1 --COO!.sub.4 --G.sub.2. The instant synergistic mixtures can be used to stabilize selected organic polymers against thermal, oxidative and/or actinic degradation.
    Type: Grant
    Filed: January 29, 1997
    Date of Patent: June 30, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Bernard Gilg, Kurt Stinsky
  • Patent number: 5616780
    Abstract: The novel compounds of the formula I ##STR1## in which A is a group of the formula IIa or IIb, ##STR2## Y is oxygen, methylene, ethylidene or a >C.dbd.C(CH.sub.3).sub.2 group, Z is nitrogen, ##STR3## R.sub.1 and R.sub.2 are, for example C.sub.1 -C.sub.5 alkyl, R.sub.3 and R.sub.4 are, for example, hydrogen or methyl, and R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14 are, for example, hydrogen, are suitable for stabilizing organic material against oxidative, thermal or light-induced degradation.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: April 1, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Rita Pitteloud, Bernard Gilg
  • Patent number: 5602196
    Abstract: Stabilisers of formula I ##STR1## wherein R.sub.1 and R.sub.2 may be C.sub.1 -C.sub.5 alkyl, the substituents R.sub.3 to R.sub.8 may be hydrogen, the variable n may be 1 or 2, and, when n is 1, A may be an alkoxy radical, and, when n is 2, A may be a diamine radical.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: February 11, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernard Gilg, Rita Pitteloud
  • Patent number: 5473003
    Abstract: Compositions comprising an organic material which is sensitive to thermal, oxidative and/or actinic degradation and at least one compound of the formula I ##STR1## in which Z.sub.1 and Z.sub.2 independently of one another are C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.8 cycloalkyl, phenyl, phenyl-C.sub.1 -C.sub.4 alkyl or (C.sub.1 -C.sub.4 alkyl)phenyl andp is a number from 4 to 18,with the proviso that Z.sub.1 and Z.sub.2 are not simultaneously tertiary alkyl radicals. Some of the compounds of the formula I are novel.The compounds of the formula I can also be employed as stabilizers as a mixture with compounds of the formula VI and/or of the formula VII ##STR2## in which n and the radicals R.sup.1, R .sup.1 ' and A are as defined in claims 14 and 15.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: December 5, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Rita Pitteloud, Paul Dubs, Bernard Gilg
  • Patent number: 5290867
    Abstract: A process for producing an emulsion graft copolymer, which comprises grafting a vinyl aromatic monomer and a comonomer onto a rubber latex in the presence of an iron (II) redox system as polymerization catalyst and coagulating the graft copolymer latex with an alkaline earth metal compound, characterized in that the pH of the coagulated slurry is adjusted to a value ranging from 8 to 12a) by addition of an alkali metal hydroxide to the obtained slurry after coagulation,b) by addition of an alkali metal hydroxide to the graft copolymer latex before coagulation, orc) by coagulating the graft copolymer latex with an alkaline earth metal hydroxide,with the proviso that the solidified product of the slurry obtained according to a), b) or c) is not washed with acidified water in a subsequent processing step.Graft copolymers are used e.g. for reinforcement of natural rubber, modification of rubber-based adhesives, in fibres, or in films.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: March 1, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernard Gilg, Kurt Stinsky
  • Patent number: 5288777
    Abstract: ABS copolymers and similar styrene or .alpha.-methylstyrene copolymers which contain an elastomer phase are stabilized against light-induced degradation by a) incorporation of a copolymerizable sterically hindered amine in, and b) addition of a non-copolymerizable sterically hindered amine to, the copolymer. Preferred sterically hindered amines are polyalkylpiperidines.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: February 22, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernard Gilg, Gerhard Rytz, Werner Stauffer, Margot Clauss
  • Patent number: 5194465
    Abstract: ABS copolymers and similar styrene or .alpha.-methylstyrene copolymers with contain an elastomer phase are stabilized against light-induced degradation by a) incorporation of a copolymerizable sterically hindered amine in, and b) addition of a non-copolymerizable sterically hindered amine to, the copolymer. Preferred sterically hindered amines are polyalkylpiperidines.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: March 16, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernard Gilg, Gerhard Rytz, Werner Stauffer, Margot Clauss
  • Patent number: 5135986
    Abstract: Copolymers of styrene or a-methylstyrene and at least one comonomer, containing crosslinked elastomer particles, can be light-stabilized by modifying the elastomer particles by copolymerization with a suitable derivative of a sterically hindered amine. The modification is preferably carried out by graft polymerization, the elastomer used preferably being polybutadiene.
    Type: Grant
    Filed: August 1, 1991
    Date of Patent: August 4, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Rolf Mulhaupt, Bernard Gilg, Gerhard Rytz, Mario Slongo
  • Patent number: 4439615
    Abstract: Compounds of the formula V ##STR1## wherein R.sup.2 is straight-chain or branched alkyl of 1 to 8 carbon atoms, cycloalkyl, aryl, alkaryl or aralkyl, L is a bivalent radical, for example --SCH.sub.2 CO.O(CH.sub.2 CH.sub.2 S).sub.y --CH.sub.2 CH.sub.2 -- or --O.COC.sub.p H.sub.2p -- wherein y is a number from 1 to 3 and p is a number from 1 to 18.
    Type: Grant
    Filed: July 19, 1982
    Date of Patent: March 27, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Siegfried Rosenberger, Samuel Evans, Bernard Gilg
  • Patent number: 4123418
    Abstract: Stabilizer system consisting of(a) at least one sterically hindered cyclic amine of the formula I ##STR1## in which q is 1 or 2, X represents an organic grouping which complements the nitrogen-containing ring to give a 5-membered, 6-membered or 7-membered ring, R.sub.1 and R.sub.2 represent methyl or together represent --(CH.sub.2).sub.5 --, R.sub.3 represents methyl, R.sub.4 represents alkyl with 1-5 carbon atoms or together with R.sub.3 represents the radicals --(CH.sub.2).sub.4 --, --(CH.sub.2).sub.5 -- ##STR2## and, if q is 1, Y denotes hydrogen, --0.sup.., hydroxyl, alkyl, substituted akyl, alkenyl, alkinyl, aralkyl, substituted aralkyl or acyl or, if q is 2, Y denotes alkylene, alkenylene, alkinylene, cycloalkylene or aralkylene, and(b) at least one co-stabilizer for stabilizing plastics.
    Type: Grant
    Filed: December 5, 1975
    Date of Patent: October 31, 1978
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernard Gilg, Helmut Muller, Jean Rody
  • Patent number: 4110304
    Abstract: Stabilizer system consisting of(a) at least one sterically hindered cyclic amine of the formula I ##STR1## in which q is 1 or 2, X represents an organic grouping which complements the nitrogen-containing ring to give a 5-membered, 6-membered or 7-membered ring, R.sub.1 and R.sub.2 represent methyl or together represent --(CH.sub.2).sub.5 --, R.sub.3 represents methyl, R.sub.4 represents alkyl with 1-5 carbon atoms or together with R.sub.3 represents the radicals --(CH.sub.2).sub.4 --, --(CH.sub.2).sub.5 -- ##STR2## and, if q is 1, Y denotes hydrogen, --O.multidot., hydroxyl alkyl, substituted alkyl, alkenyl, alkinyl, aralkyl, substituted aralkyl or acyl or, if q is 2, Y denotes alkylene, alkenylene, alkinylene, cycloalkylene or aralkylene, and(b) at least one co-stabilizer for stabilizing plastics.
    Type: Grant
    Filed: December 5, 1975
    Date of Patent: August 29, 1978
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernard Gilg, Helmut Muller, Jean Rody
  • Patent number: 3959413
    Abstract: Bicyclic phosphites are used alone or in combination with other stabilisers for stabilising polyolefines.
    Type: Grant
    Filed: June 27, 1974
    Date of Patent: May 25, 1976
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Schwarzenbach, Bernard Gilg, Heimo Brunetti, Helmut Muller