Patents by Inventor Bernd Herzog

Bernd Herzog has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11419804
    Abstract: The present invention relates to a sunscreen formulation comprising at least one of the UV filters (A) selected from (a) triazine derivatives; (b) cinnamic acid derivatives; (c) bis-resorcinyl triazines; (f) benzimidazole derivatives; (i5) 4-Methylbenzylidene Camphor; (h) benzoyl piperazine derivatives; (j) benzoxazole derivatives; (k) diarylbutadiene derivatives; (I) phenyl benzotriazole derivatives; (n) benzylidene malonates; (o3) TEA-Salicylate; (r) imidazoline derivatives; (u) inorganic UV filters selected from metal oxides; (v) naphthalates; and (w) merocyanine derivatives; and optionally comprising at least one of the UV filters (B) selected from (d) aminobenzophenone derivatives; (e) dibenzoylmethane derivatives; (g) ?,?-Diphenylacrylate derivatives; (i5) camphor derivatives different from; (o3) salicylate derivatives different from; (p) anthranilate derivatives; and (s) benzalmalonate derivatives; wherein the ratio R of the effective irradiance for previtamin D3 formation Epvd to the effective irradia
    Type: Grant
    Filed: July 24, 2015
    Date of Patent: August 23, 2022
    Assignee: BASF SE
    Inventors: Bernd Herzog, Dieter Kockott, Heike Flösser-Müller
  • Publication number: 20220183934
    Abstract: The present invention relates to a method for increasing sun protection factor (SPF) of a sunscreen composition, use of porous metal oxide spheres (e.g., microspheres) for increasing SPF of a sunscreen composition and preparation of sunscreen compositions comprising the porous spheres.
    Type: Application
    Filed: March 12, 2020
    Publication date: June 16, 2022
    Inventors: Bernd HERZOG, Brigitte LINDEMANN, Chrisstian CREMER, Rupa Hiremath DARJI, Liangliang QU, Keith TASK
  • Publication number: 20220047483
    Abstract: Aqueous dispersions (A) containing a micronized organic UV filter (a) selected from (a1) the micronized compound of formula (a2)the micronized compound of formula (a3) the micronized compound of formula (a4) the micronized compound of formula and (b) a vinylpyrrolidone copolymer or homopolymer.
    Type: Application
    Filed: August 13, 2021
    Publication date: February 17, 2022
    Inventors: Heike Floesser-Mueller, Stephanie Acker, Louis Danoux, Henning Urch, Julie Grumelard, Thomas Ehlis, Bernd Herzog, Ullrich Menge, Antony Young, Karl Lawrence
  • Publication number: 20220008298
    Abstract: Disclosed is the use of oleogels (a) for increasing the sun protection factor of sunscreens comprising at least one organic or inorganic UV filter (b).
    Type: Application
    Filed: September 24, 2021
    Publication date: January 13, 2022
    Inventors: Bernd Herzog, Cyrille Deshayes
  • Patent number: 11103733
    Abstract: The instant invention refers to the use of a concentrated aqueous polymer dispersion with an average particle size of less than 1000 nm comprising (a) a polymer carrier prepared by heterophase radical polymerization of at least one ethylenically unsaturated monomer in the presence of (b) an oil-soluble organic UV absorber selected from the class of p-aminobenzoic acid derivatives; salicylic acid derivatives; benzophenone derivatives; diphenyl acrylate derivatives; benzofuran derivatives; polymeric UV absorbers, comprising one or more organosilicon radicals; cinnamic acid derivatives; camphor derivatives; s-triazine derivatives; trianilino-s-triazine derivatives; menthyl anthranilates; and benzotriazole derivatives; wherein the weight ratio of the oil-soluble organic UV absorber (b) to polymer carrier (a) is greater than 50 parts UV absorber per 100 parts of carrier; for the protection of human and animal hair and skin against the damaging effect of UV radiation.
    Type: Grant
    Filed: June 30, 2008
    Date of Patent: August 31, 2021
    Assignee: BASF SE
    Inventors: Stefan Müller, Brigitte Lindemann, Bernd Herzog
  • Publication number: 20210231644
    Abstract: Disclosed herein are ultraviolet (UV) filter compositions and methods relating to their preparation and use. The compositions and related method of preparation may include combining at least one or at least two UV filters with at least one other ingredient, wherein each of the UV filters is selected to have an overall environmental hazard score of 1.5 to 7.0, and determining an ecotoxicological value of the composition, wherein the ecotoxicological value ranges from 0 to 350.
    Type: Application
    Filed: April 26, 2019
    Publication date: July 29, 2021
    Inventors: Stephanie ACKER, Sascha PAWLOWSKI, Bernd HERZOG
  • Publication number: 20190274939
    Abstract: Disclosed are aqueous dispersions (A), comprising a micronized organic UV filter (a) selected from (a1) the micronized compound of formula (1), wherein R1 and R2 independently from each other are C1-C20alkyl; C2-C20alkenyl; C3-C10ocycloalkyl; C3-C10cycloalkenyl; or R1 and R2 together with the linking nitrogen atom form a 5- or 6-membered heterocyclic ring; A is —N(R3)—; —O—; or the direct bond; B is a bivalent radical selected from alkylene, cycloalkylene alkenylene or phenylene radical which is optionally substituted by a carbonyl- or carboxy group; a radical of formula *—CH2—C??C—CH2—; or the divalent radical *-B-* corresponds to the formula (1a), wherein n1 is a number from 1 to 3; A is —N(R3)—; or —O—; and R3 is hydrogen; C1-C5alkyl; or hydroxy-C1-C5alkyl; (a2) the micronized compound of formula (2), wherein T1 is hydrogen; C1-C12alkyl; preferably iso-octyl, or C1-C4alkyl substituted by phenyl; (a3) the micronized compound of formula (3a); wherein R4 and R5 independently from each other are hydrogen; C1-C
    Type: Application
    Filed: May 19, 2017
    Publication date: September 12, 2019
    Inventors: Heike FLOESSER-MUELLER, Stephanie ACKER, Louis DANOUX, Henning URCH, Julie GRUMELARD, Thomas EHLIS, Bernd HERZOG, Ullrich MENGE, Antony YOUNG, Karl LAWRENCE
  • Publication number: 20180200170
    Abstract: The present invention relates to a sunscreen formulation comprising at least one of the UV filters (A) selected from (a) triazine derivatives; (b) cinnamic acid derivatives; (c) bis-resorcinyl triazines; (f) benzimidazole derivatives; (is) 4-Methylbenzylidene Camphor; (h) benzoyl piperazine derivatives; (j) benzoxazole derivatives; (k) diarylbutadiene derivatives; (I) phenyl benzotriazole derivatives; (n) benzylidene malonates; (o3) TEA-Salicylate; (r) imidazoline derivatives; (u) inorganic UV filters selected from metal oxides; (v) naphthalates; and (w) merocyanine derivatives; and optionally comprising at least one of the UV filters (B) selected from (d) aminobenzophenone derivatives; (e) dibenzoylmethane derivatives; (g) ?,?-Diphenylacrylate derivatives; (i5) camphor derivatives different from; (o3) salicylate derivatives different from; (p) anthranilate derivatives; and (s) benzalmalonate derivatives; wherein the ratio R of the effective irradiance for previtamin D3 formation Epvd to the effective irradia
    Type: Application
    Filed: July 24, 2015
    Publication date: July 19, 2018
    Inventors: Bernd HERZOG, Dieter KOCKOTT, Heike FLÖSSER-MÜLLER
  • Patent number: 9707417
    Abstract: Described is the use of benzotropolone and their derivatives, especially the compounds of formula (1); wherein R2, R3, R4, R5 and R6 independently of one another are hydrogen; OH; C1-C30alkyl, C2-C30al-kenyl, C1-C30alkoxy, C3-C12cycloalkyl or C1C30hydroxyalkyl, which may be substituted by one or more E and/or interrupted by one or more D; C6-C20aryl, which may be substituted by one or more G; C4-C20heteroaryl, which may be substituted by one or more G, C2-C18alkenyl, C2-C18alkynyl, C7-C25aralkyl, CN, or —CO—R17; C1-C30mono- or dialkylamino; COR9; COOR9; CONR9R10; CN; SO2R9; OCOOR9; OCOR9; NHCOOR9; NR9COR10; NH2; *—(CO)—NH—(CH2)n1—(PO)—(OR11)2; —(CO)—O—(CH2)n1—(PO)—(OR11)2; sulphate; sulphonate; phosphate; phosphonate; —(CH2)n2—[O—(SO2)]n3—OR11; —O—(CH2)n4(CO)n5—R11; —(O)n6—(CH2)n7—(PO)—(OR9)2; —(O)n6—(CH2)n7—SO2—OR9; halogen; organosilanyl; organo-siloxanyl; or a sugar residue linked directly in an ?- or ?-mode via the anomeric oxygen to the benzotropolone system or via a linear or branched alkylene, alkenyle
    Type: Grant
    Filed: June 18, 2009
    Date of Patent: July 18, 2017
    Assignee: BASF SE
    Inventors: Barbara Wagner, Reinhold Öhrlein, Bernd Herzog, Kai Eichin, Gabriele Baisch, Stephanie Portmann
  • Publication number: 20160158132
    Abstract: Disclosed is the Use of UV absorbers selected from (a1) diphenylacrylates; and (a2) hydroxyphenyl triazines of formula wherein R1 is —O—R5; —COOR6; or —CO—NHR7; R2 is —O—R8, —COOR9; or —CO—NHR10; R3 is —O—R11; —COOR12; or —CO—NHR13; R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently from each other are C1-C18alkyl; R4 is hydrogen; or hydroxy; and x is 0; or 1; for stabilizing cosmetic compositions comprising an organic UV absorber selected from (b1) a benzophenone derivatives of formula wherein R14 and R15 independently from each other are; C1-C20alkyl; C2-C20alkenyl; C3-C10cycloalkyl; C3-C10cycloalkenyl; or R14 and R15 together with the linking nitrogen atom form a 5- or 6-membered heterocyclic ring; n1 is a number from 1 to 4; when n1=1, R16 is a saturated or unsaturated heterocyclic radical; hydroxy-C1-C5alkyl; cyclohexyl optionally substituted with one or more C1-C5alkyl; phenyl optionally substituted with a heterocyclic radical, aminocarbonyl or C1-C5alkylcarboxy; when n1
    Type: Application
    Filed: February 12, 2016
    Publication date: June 9, 2016
    Applicant: BASF SE
    Inventors: Bernd Herzog, Julie Grumelard
  • Patent number: 9283160
    Abstract: Disclosed is the Use of UV absorbers selected from (a1) diphenylacrylates; and (a2) specific hydroxyphenyl triazines for stabilizing cosmetic compositions comprising an organic UV absorber selected from (b1) a specific benzophenone derivative, (b2) a specific benzotriazole derivative and (b3) a specific triazine derivative and UV filters selected from (c1) cinnamic acid derivatives; and (c2) dibenzoylmethane derivatives.
    Type: Grant
    Filed: January 28, 2010
    Date of Patent: March 15, 2016
    Assignee: BASF SE
    Inventors: Bernd Herzog, Julie Grumelard
  • Publication number: 20150250695
    Abstract: Disclosed is the use of UV absorbers selected from (a1) diphenylacrylates; (a2) hydroxyphenyl triazines of formula (1), in which R1, R2 and R3 independently of one another, are C1-C18alkyl; (a3) benzotriazole derivatives of formula (2), wherein R4 is a random statistical mixture of at least three isomeric branched secondary alkyl groups each having 8 to 30 carbon atoms and having the formula (2a); E1 is a straight-chain C1-C14alkyl; E2 is a straight-chain C4-C15alkyl; wherein the total number of carbon atoms in E1 plus E2 is from 7 to 29; and R5 is C1-C5alkyl; and (a4) dialkyl naphthalate; for stabilizing cosmetic compositions comprising (b) symmetrical triazine derivatives of formula (3), wherein A is a radical of formula (3a); or (3b) R6 and R10 independently from each other are hydrogen; C1-C18alkyl; or C6-C12aryl; R7, R8 and R9 independently from each other are hydrogen; or a radical of formula (3c), wherein, in formula (3a), at least one of the radicals R7, R8 and R9 are a radical of formula (3c); R11, R
    Type: Application
    Filed: May 26, 2015
    Publication date: September 10, 2015
    Applicant: BASF SE
    Inventors: Bernd Herzog, Katja Quass, Stephanie Acker
  • Patent number: 9066872
    Abstract: Disclosed is the use of UV absorbers selected from (a1) diphenylacrylates; (a2) hydroxyphenyl triazines of formula (1), in which R1, R2 and R3 independently of one another, are C1-C18alkyl; (a3) benzotriazole derivatives of formula (2), wherein R4 is a random statistical mixture of at least three isomeric branched secondary alkyl groups each having 8 to 30 carbon atoms and having the formula (2a); E1 is a straight-chain C1-C14alkyl; E2 is a straight-chain C4-C15alkyl; wherein the total number of carbon atoms in E1 plus E2 is from 7 to 29; and R5 is C1-C5alkyl; and (a4) di-alkyl naphthalate; for stabilizing cosmetic compositions comprising (b) symmetrical triazine derivatives of formula (3), wherein A is a radical of formula (3a); or (3b) R6 and R10 independently from each other are hydrogen; C1-C18alkyl; or C6-C12aryl; R7, R8 and R9 independently from each other are hydrogen; or a radical of formula (3c), wherein, in formula (3a), at least one of the radicals R7, R8 and R9 are a radical of formula (3c); R11,
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: June 30, 2015
    Assignee: BASF SE
    Inventors: Bernd Herzog, Katja Quass, Stephanie Acker
  • Patent number: 8986662
    Abstract: Disclosed is the use of silane and siloxane bis(biphenyl)triazine derivatives of formula (1), wherein n is a number from 1 to 4; if n=1, X is *-L-Sil; or a radical of formula (11?), L is a linker selected from a radical of formula (2); R1, R2, R3 independently from each other are C1-C22alkyl; C6-C20aryl; C1-C22alkoxy; or O—C6-C20aryl; R4, R5, R6 and R7 independently from each other are hydrogen; C1-C22alkyl; C6-C20aryl; C1-C22alkoxy; or O—C6-C20aryl; b is a number from 0 to 30; c is a number from 0 to 6; and d is a number from 0 to 1; p is a number from 1 to 250; q is a number from 0 to 250; and Sil, Sil1 and Sil2 independently from each other are a silane-, oligosiloxane or polysiloxane moiety; if n=2, X is a bivalent radical of formula (1a); or (1b); x is a number from 2 to 250; y is a number from 0 to 250; and z is a number from 1 to 50; if n=3, X is a trivalent radical containing a silane-, oligosiloxane or polysiloxane moiety; If n=4, X is a tetravalent radical of formula (1c); and A is a radical of form
    Type: Grant
    Filed: October 20, 2011
    Date of Patent: March 24, 2015
    Assignee: BASF SE
    Inventors: Barbara Wagner, Bernd Herzog
  • Publication number: 20140308225
    Abstract: Disclosed is the use of oleogels (a) for increasing the sun protection factor of sunscreens comprising at least one organic or inorganic UV filter (b).
    Type: Application
    Filed: November 20, 2012
    Publication date: October 16, 2014
    Applicant: BASF SE
    Inventors: Bernd Herzog, Cyrille Deshayes
  • Patent number: 8585782
    Abstract: Disclosed is the use of mixtures comprising at least 2 structurally different bis(biphenyl)triazine derivatives of formula (1) as UV absorbers for increasing the UVA protection factor of cosmetic or dermatological compositions. Wherein X and R1-R6 are defined in the claims and in the specification.
    Type: Grant
    Filed: September 9, 2011
    Date of Patent: November 19, 2013
    Assignee: BASF SE
    Inventors: Barbara Wagner, Bernd Herzog
  • Patent number: 8535648
    Abstract: Disclosed is the use of merocyanine derivatives of formula (1) for stabilizing UV-sensitive active ingredients like dibenzoylmethane derivatives.
    Type: Grant
    Filed: January 16, 2008
    Date of Patent: September 17, 2013
    Assignee: BASF SE
    Inventors: Barbara Wagner, Bernd Herzog, Stefan Müller, Thomas Ehlis
  • Publication number: 20130202542
    Abstract: Disclosed is the use of silane and siloxane bis(biphenyl)triazine derivatives of formula (1), wherein n is a number from 1 to 4; if n=1, X is *-L-Sil; or a radical of formula (11?), L is a linker selected from a radical of formula (2); R1, R2, R3 independently from each other are C1-C22alkyl; C6-C20aryl; C1-C22alkoxy; or O—C6-C20aryl; R4, R5, R6 and R7 independently from each other are hydrogen; C1-C22alkyl; C6-C20aryl; C1-C22alkoxy; or O—C6-C20aryl; b is a number from 0 to 30; c is a number from 0 to 6; and d is a number from 0 to 1; p is a number from 1 to 250; q is a number from 0 to 250; and Sil, Sil1 and Sil2 independently from each other are a silane-, oligosiloxane or polysiloxane moiety; if n=2, X is a bivalent radical of formula (1a); or (1b); x is a number from 2 to 250; y is a number from 0 to 250; and z is a number from 1 to 50; if n=3, X is a trivalent radical containing a silane-, oligosiloxane or polysiloxane moiety; If n=4, X is a tetravalent radical of formula (1c); and A is a radical of form
    Type: Application
    Filed: October 20, 2011
    Publication date: August 8, 2013
    Applicant: BASF SE
    Inventors: Barbara Wagner, Bernd Herzog
  • Publication number: 20130164231
    Abstract: Disclosed is the use of mixtures comprising at least 2 structurally different bis(biphenyl)triazine derivatives of formula (1) wherein X is hydrogen; C1-C50alkyl which may be uninterrupted or interrupted by one or more oxygen atoms and/or substituted by one or more R8 groups; C3-C12-cycloalkyl which is substituted by R8; —CH((CH2)p—R8)—CO—O—(CH2)m—R9; —CH((CH2)p—R8)—CO—(NR10)—(CH2)m—R9; —CO—O—(CH2)p—Ra; —CH2—CH(—O(CO)—R8)—R9; —CO—(NR10)—(Ch2)p—Ra; C6-C20aryl; allyl; C4-C50alkenyl which is uninterrupted or is interrupted by one or more oxygen atoms; C3-C12cycloalkyl which is uninterrupted or interrupted by one or more oxygen atoms; C3-C20alkynyl; C6-C12cycloalkynyl; R1 is hydrogen; unsubstituted or substituted unsubstituted or substituted C3-C12cycloalkyl; unsubstituted or substituted C6-C20aryl; unsubstituted or substituted C2-C20alkenyl; OR7; OH; SR8; SOR7; SO2R7; SO2H; SO3M; or a radical of the formula (c); R2, R3, R4, R5 and R6 independently of one another are hydrogen; hydroxyl; —CN; substituted or unsubs
    Type: Application
    Filed: September 9, 2011
    Publication date: June 27, 2013
    Applicant: BASF SE
    Inventors: Barbara Wagner, Bernd Herzog
  • Patent number: 8393556
    Abstract: Disclosed is a method of preparing a composition, comprising a micronized insoluble organic UV absorber, which method comprises grinding the insoluble organic UV absorber, in coarse particle form, in a grinding apparatus comprising yttrium-stabilized zirconium oxide grinding beads, in the presence of alkyl polyglucoside having the formula CnH2n+1O(C6H10O5)xH, in which n is an integer ranging from 8 to 16 and x is the mean polymerisation level of the glucoside moiety (C6H10O5) and ranges from 1.4 to 1.6, or an ester thereof and in the presence of an antifoam agent as dispersingagent auxiliary.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: March 12, 2013
    Assignee: BASF SE
    Inventors: Stefan Müller, Bernd Herzog