Abstract: An integrated process for making propylene oxide and propylene glycol involves reacting propene with an oxidant to provide propylene oxide, reacting a fraction of the propylene oxide with water to provide an aqueous glycol solution containing monopropylene glycol and dipropylene glycol, and separating monopropylene glycol and dipropylene glycol from the glycol solution by a multi-step distillation. The propylene oxide output can be increased without increasing capacity of the unit for reacting propene to propylene oxide, by reacting propene and hydrogen peroxide in the presence of a catalyst mixture, containing a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture which contains an aqueous phase with a maximum apparent pH of 6 and an organic phase. The reaction mixture is separated into an organic phase, which is recycled to the reaction, and an aqueous phase containing monopropylene glycol and dipropylene glycol, which is passed to replace the glycol solution.

Abstract: A method for preparing 1,2-propanediol involves reacting propene with hydrogen peroxide, in the presence of a phase transfer catalyst and a heteropolytungstate, in a liquid reaction mixture containing an aqueous phase with a maximum apparent pH of 6 and an organic phase containing a solvent having a solubility in water at 20° C. of less than 500 mg/kg. The method then involves separating the liquid reaction mixture into an aqueous phase containing 1,2-propanediol and an organic phase; recycling at least a part of the separated organic phase to the reaction; and extracting the separated aqueous phase with an extractant solution containing the same phase transfer catalyst and solvent as used in the reaction to provide an extracted aqueous phase and an extract phase. The method further involves recycling at least a part of the extract phase to the reaction and recovering 1,2-propanediol from the extracted aqueous phase.

Abstract: A screw-spindle pump stage having a drive spindle and a running spindle which runs opposite the drive spindle and a pump housing for receiving the two screw spindles. The pump housing 16 has an offset interface with centering action, for a statically determined coupling to an electric motor. The pump housing has an offset section functioning as an abutment, which is able to be abutted against the electric motor for the application of an axial preload. At least one pressure region of the abutment section, which is close to the interface and, during a rolling, is encapsulated, and at the same time sealingly enclosed, by a sheet-metal casing, forms a rolling region of the pump, the screw spindles, together with the associated pump housing section, at least partially project from the rolling region of the pump on the suction side.

Abstract: A screw-spindle pump stage having a drive spindle and a running spindle which runs opposite the drive spindle and a pump housing for receiving the two screw spindles. The pump housing 16 has an offset interface with centering action, for a statically determined coupling to an electric motor. The pump housing has an offset section functioning as an abutment, which is able to be abutted against the electric motor for the application of an axial preload. At least one pressure region of the abutment section, which is close to the interface and, during a rolling, is encapsulated, and at the same time sealingly enclosed, by a sheet-metal casing, forms a rolling region of the pump, the screw spindles, together with the associated pump housing section, at least partially project from the rolling region of the pump on the suction side.

Abstract: In a process for the epoxidation of propene, comprising the steps of reacting propene with hydrogen peroxide, separating propene oxide and a recovered propene stream from the reaction mixture, separating propane from all or a part of the recovered propene stream in a C3 splitter column, and passing the overhead product stream of the C3 splitter column to the epoxidation step, a propane starting material with a propane fraction of from 0.002 to 0.10 is used, the epoxidation is operated to provide a propane fraction in the reaction mixture of from 0.05 to 0.20 and the C3 splitter column is operated to provide an overhead product stream which comprises a propane fraction of at least 0.04 in order to reduce the size and the energy consumption of the C3 splitter column.

Abstract: During start-up of a continuous epoxidation of propene with hydrogen peroxide in a methanol solvent with a shaped titanium silicalite catalyst in a tube bundle reactor with a cooling jacket, cooling medium is fed at the rate for full load of the reactor with a constant entry temperature of from 20° C. to 50° C., methanol solvent is fed at a rate of from 50 to 100% for full load of the reactor, hydrogen peroxide is fed at a rate that starts with no more than 10% of the rate for full load and is increased continuously or stepwise to maintain a maximum temperature in the fixed bed of no more than 60° C. and a difference between the maximum temperature in the fixed bed and the cooling medium entry temperature of no more than 20° C., and propene is fed at a rate of from 20 to 100% of the rate for full load, increasing the feeding rate when the molar ratio of propene to hydrogen peroxide reaches the molar ratio for full load.

Abstract: During start-up of a continuous epoxidation of propene with hydrogen peroxide in a methanol solvent with a shaped titanium silicalite catalyst in a tube bundle reactor with a cooling jacket, cooling medium is fed at the rate for full load of the reactor with a constant entry temperature of from 20° C. to 50° C., methanol solvent is fed at a rate of from 50 to 100% for full load of the reactor, hydrogen peroxide is fed at a rate that starts with no more than 10% of the rate for full load and is increased continuously or stepwise to maintain a maximum temperature in the fixed bed of no more than 60° C. and a difference between the maximum temperature in the fixed bed and the cooling medium entry temperature of no more than 20° C., and propene is fed at a rate of from 20 to 100% of the rate for full load, increasing the feeding rate when the molar ratio of propene to hydrogen peroxide reaches the molar ratio for full load.

Abstract: The process for preparing 1,2-propanediol from propene and hydrogen peroxide comprises the steps of a) reacting propene with hydrogen peroxide in the presence of a catalyst mixture comprising a phase transfer catalyst and a heteropolytungstate, wherein the reaction is carried out in a liquid mixture comprising an aqueous phase having a pH of at most 6 and an organic phase, b) separating the biphasic mixture from step a) into an aqueous phase and an organic phase comprising propene oxide, c) recycling the propene oxide present in the separated organic phase into the reaction of step a) and d) separating 1,2-propanediol from the aqueous phase separated in step b).

Abstract: Propene is continuously reacted with hydrogen peroxide in a tube bundle reactor comprising a multitude of parallel reaction tubes in the presence of a titanium silicalite catalyst arranged as a fixed bed in the reaction tubes. A cooling jacket encloses the reaction tubes, which has a feed point for cooling medium near the entry of the reaction tubes, a withdrawal point for cooling medium near the end of the reaction tubes and at least one additional withdrawal point upstream of the withdrawal point near the end of the reaction tubes. Cooling medium is fed to the feed point for cooling medium, a part of the cooling medium is withdrawn at the at least one additional withdrawal point and the remainder exits at the withdrawal point near the end of the reaction tubes.

Abstract: Propene is continuously reacted with hydrogen peroxide in a tube bundle reactor comprising a multitude of parallel reaction tubes in the presence of a titanium silicalite catalyst arranged as a fixed bed in the reaction tubes. A cooling jacket encloses the reaction tubes, which has a feed point for cooling medium near the entry of the reaction tubes, a withdrawal point for cooling medium near the end of the reaction tubes and at least one additional withdrawal point upstream of the withdrawal point near the end of the reaction tubes. Cooling medium is fed to the feed point for cooling medium, a part of the cooling medium is withdrawn at the at least one additional withdrawal point and the remainder exits at the withdrawal point near the end of the reaction tubes.

Abstract: The process for preparing 1,2-propanediol from propene and hydrogen peroxide comprises the steps of a) reacting propene with hydrogen peroxide in the presence of a catalyst mixture comprising a phase transfer catalyst and a heteropolytungstate, wherein the reaction is carried out in a liquid mixture comprising an aqueous phase having a pH of at most 6 and an organic phase, b) separating the biphasic mixture from step a) into an aqueous phase and an organic phase comprising propene oxide, c) recycling the propene oxide present in the separated organic phase into the reaction of step a) and d) separating 1,2-propanediol from the aqueous phase separated in step b).

Abstract: In a process for the epoxidation of propene, comprising the steps of reacting propene with hydrogen peroxide, separating propene oxide and a recovered propene stream from the reaction mixture, separating propane from all or a part of the recovered propene stream in a C3 splitter column, and passing the overhead product stream of the C3 splitter column to the epoxidation step, a propane starting material with a propane fraction of from 0.002 to 0.10 is used, the epoxidation is operated to provide a propane fraction in the reaction mixture of from 0.05 to 0.20 and the C3 splitter column is operated to provide an overhead product stream which comprises a propane fraction of at least 0.04 in order to reduce the size and the energy consumption of the C3 splitter column.

Abstract: In a process for the epoxidation of propene, comprising the steps: reacting propene with hydrogen peroxide in the presence of a titanium silicalite catalyst and a methanol solvent; separating non-reacted propene and propene oxide from the resulting reaction mixture to provide a solvent mixture comprising methanol and water in a combined amount of at least 90% by weight; and feeding this solvent mixture as a feed stream to a continuously operated methanol distillation column at a feed point in the middle section of said column to provide an overhead product comprising at least 90% by weight methanol and a bottoms product comprising at least 90% by weight water; the addition of a liquid defoamer, having a solubility in the feed stream of less than 10 mg/kg at 25° C. and a surface tension at the liquid air interface of less than 22 mN/m at 20° C.

Abstract: In a process for the epoxidation of propene, comprising the steps: reacting propene with hydrogen peroxide in the presence of a titanium silicalite catalyst and a methanol solvent; separating non-reacted propene and propene oxide from the resulting reaction mixture to provide a solvent mixture comprising methanol and water in a combined amount of at least 90% by weight; and feeding this solvent mixture as a feed stream to a continuously operated methanol distillation column at a feed point in the middle section of said column to provide an overhead product comprising at least 90% by weight methanol and a bottoms product comprising at least 90% by weight water; the addition of a liquid defoamer, having a solubility in the feed stream of less than 10 mg/kg at 25° C. and a surface tension at the liquid air interface of less than 22 mN/m at 20° C.

Abstract: The invention relates to a sheet-fed press (10) comprising a sheet feeding device (11) for introducing sheets that are to be printed into the sheet-fed press, at least one printing unit (12) and/or coating unit (13) for printing the sheets with a static printed image that is identical for all sheets, a discharging mechanism (14) for discharging printed sheets from the sheet-fed press, and at least one printing device (1) which includes no printing form and is integrated into the sheet-fed press (10) to print the sheets with an especially dynamic, variable printed image. According to the invention, the printing device (1) is integrated in the region of a supply strip (19) in the sheet-fed press (10) which guides a stream of products to the first of the printing units (12).

Abstract: An apparatus comprising at least one processing circuitry, and at least one memory for storing instructions to be executed by the processing circuitry, wherein the at least one memory and the instructions are configured to, with the at least one processing circuitry, cause the apparatus at least: to execute management tasks in an automated manner related to a control of security in a communication between two end points of a communication connection in a hybrid communication network, wherein the security is controlled for physical and virtual parts of the hybrid communication network, and to automatically control at least one of deployment, configuration and management of a security service including at least one security function instantiated or implemented in the hybrid communication network.

Abstract: A fuel pump, including a driven impeller, which rotates in a pump housing and on the two sides comprises guide blades that each delimit a ring of blade chambers, and further including partial ring-shaped channels, which are arranged on both sides in the region of the guide blades in the pump housing and which form delivery chambers with the blade chambers for delivering fuel, wherein an inlet channel leads into the one delivery chamber and the other delivery chamber leads into an outlet channel, and mutually opposing blade chambers are connected to each other. The cross-sectional surface of the partial ring-shaped channel arranged on the inlet side decreases toward the end of the partial ring-shaped channel to zero. The region in which the cross-sectional surface decreases extends over an angular region of more than 45°.

Abstract: A fuel pump, including a driven impeller, which rotates in a pump housing and on the two sides comprises guide blades that each delimit a ring of blade chambers, and further including partial ring-shaped channels, which are arranged on both sides in the region of the guide blades in the pump housing and which form delivery chambers with the blade chambers for delivering fuel, wherein an inlet channel leads into the one delivery chamber and the other delivery chamber leads into an outlet channel, and mutually opposing blade chambers are connected to each other. The cross-sectional surface of the partial ring-shaped channel arranged on the inlet side decreases toward the end of the partial ring-shaped channel to zero. The region in which the cross-sectional surface decreases extends over an angular region of more than 45°.

Abstract: A fuel pump, including at least one driven impeller made of plastic, which rotates in a pump housing and on the sides having guide blades that each delimit at least one ring of blade chambers, and further having partial ring-shaped channels arranged on both sides in the region of the guide blades in the pump housing, said channels forming delivery chambers with the blade chambers for delivering fuel. An inlet channel leads into the one delivery chamber and the other delivery chamber leads into an outlet channel and the impeller contains carbon fibers embedded in the plastic.

Abstract: A fuel pump for delivering fuel in a motor vehicle, having a side channel stage. The fuel pump further includes a peripheral stage. The peripheral stage produces the same pressure at lower volume flow across the periphery of the rotor as compared to a side channel stage. For this purpose, the cross-sections of the delivery compartments of the peripheral stage are smaller than the cross-sections of the delivery compartments of the side channel stage. The fuel pump therefore has a higher efficiency and is less susceptible to soiling.