Patents by Inventor Bernd Wohlmann
Bernd Wohlmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20230066426Abstract: A textile reinforcement for integrating into concrete, having carbon fibers. The reinforcement is coated with a layer which protects against oxidation, wherein the carbon fibers are provided in the form of an interlaced, twisted, or cabled thread structure and have 5 wt. % of matrix resin, and the layer which protects against oxidation is a separate layer and can produce a chemical bond to a component of the concrete. The invention additionally relates to a concrete part which has a textile reinforcement.Type: ApplicationFiled: February 18, 2021Publication date: March 2, 2023Applicant: TEIJIN CARBON EUROPE GMBHInventors: Silke STÜSGEN, Bernd WOHLMANN, Franz KÖHLER, Willem TER STEEG
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Publication number: 20200340544Abstract: A component in the form of a crash element is made of a fibre composite material, the wall of which is constructed at least predominantly from bundles of carbon fibres. The carbon fibre filaments are arranged parallel to one another within the fibre bundles, and the bundles are embedded in a polymer matrix. Within the wall of the component the bundles are distributed uniformly and have a substantially isotropic orientation as considered perpendicularly to a first and/or second surface.Type: ApplicationFiled: October 26, 2018Publication date: October 29, 2020Inventors: Bernd WOHLMANN, Christian HUNYAR, Markus SCHNEIDER
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Patent number: 9540509Abstract: A pre-impregnated yarn including a bundle of reinforcing fiber filaments having a bundle interior and a bundle outer side, a first resin composition, and a second resin composition. The first resin composition includes at least one urethane resin, H1, produced from a reaction of a bifunctional aromatic epoxy compound based on bisphenol A, an aromatic polyisocyanate, and a polyalkylene glycol; an oxyalkylated bisphenol A resin, H2; and aromatic polyhydroxy ether P1. The filaments are impregnated with and at least partially connected via the first resin composition. The first resin composition is present in a concentration of 0.1 to 4 wt % relative to a total weight of the pre-impregnated yarn. The second resin composition is on the bundle outer side in the form of particles or drops adhering to the filaments, and is in a concentration of 0.5 to 14 wt % relative to the total weight of the pre-impregnated yarn.Type: GrantFiled: January 21, 2014Date of Patent: January 10, 2017Assignee: TOHO TENAX EUROPE GMBHInventors: Sabine Kummer-Dörner, Silke Stüsgen, Silke Witzel, Jens Pusch, Markus Schneider, Bernd Wohlmann
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Publication number: 20150376404Abstract: A pre-impregnated yarn including a bundle of reinforcing fiber filaments having a bundle interior and a bundle outer side, a first resin composition, and a second resin composition. The first resin composition includes at least one urethane resin, H1, produced from a reaction of a bifunctional aromatic epoxy compound based on bisphenol A, an aromatic polyisocyanate, and a polyalkylene glycol; an oxyalkylated bisphenol A resin, H2; and aromatic polyhydroxy ether P1. The filaments are impregnated with and at least partially connected via the first resin composition. The first resin composition is present in a concentration of 0.1 to 4 wt % relative to a total weight of the pre-impregnated yarn. The second resin composition is on the bundle outer side in the form of particles or drops adhering to the filaments, and is in a concentration of 0.5 to 14 wt % relative to the total weight of the pre-impregnated yarn.Type: ApplicationFiled: January 21, 2014Publication date: December 31, 2015Inventors: Sabine KUMMER-DÖRNER, Silke STÜSGEN, Silke WITZEL, Jens PUSCH, Markus SCHNEIDER, Bernd WOHLMANN
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Publication number: 20140346409Abstract: A carbon fiber with a conductive finish includes carbon fiber filaments including a metal coating, wherein the carbon fiber filaments have a finish on the metal coating based on at least one polymer binder and containing conductive nanoparticles. The concentration of the metal coating is 8 to 25 wt. % and the concentration of the carbon nanotubes is 0.1 to 1 wt. %, each relative to the weight of the carbon fiber provided with the metal coating and finish. A method for producing fibers of this type is set forth, as well as a fiber-reinforced composite material comprising carbon fibers including carbon fiber filaments, wherein the carbon fiber filaments are coated with a metal, and a polymer-based matrix, wherein the percent by volume of the fibers in the composite material is 30 to 70 vol. % and the composite material additionally contains conductive nanoparticles which are dispersed at least partially in the matrix.Type: ApplicationFiled: December 6, 2012Publication date: November 27, 2014Inventors: Silke Witzel, Bernd Wohlmann, Silke Stüsgen
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Patent number: 8840988Abstract: A fiber preform for producing fiber composite structures, a wall thereof including a first zone made from reinforcing fiber bundles having a first resin composition and a second zone made from at least one fiber tape comprising at least one unidirectionally directed reinforcing yarn strand having a second resin composition. The reinforcing fiber bundles in the first zone are oriented in different spatial directions to each other when viewed in a direction parallel to the extension of the thickness. Each reinforcing fiber has a length of from 3 to 50 mm, and contains the first resin composition in a concentration of from 1 to 10 wt % of the fiber weight. The wall of the fiber preform has a proportion of reinforcing fibers of more than 35 vol %, and the second zone forms a discrete region when viewed in a direction perpendicular to the thickness extension of the wall.Type: GrantFiled: November 11, 2011Date of Patent: September 23, 2014Assignee: Toho Tenax Europe GmbHInventors: Bernd Wohlmann, Markus Schneider, Andreas Woginger, Frank Oberwahrenbrock
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Patent number: 8834997Abstract: Carbon fibers and carbon fiber yarn consisting of carbon fibers, the fibers having been pretreated by electrochemical oxidation, characterized in that they have a finish consisting of epoxy resin(s), a vinyl component, and a plasticizer in an amount of 0.3 to 5 wt. % relative to the carbon fibers, which are to be provided with the finish.Type: GrantFiled: April 19, 2007Date of Patent: September 16, 2014Assignee: Toho Tenax Europe GmbHInventors: Silke Stuesgen, Bernd Wohlmann, Matthias Schubert
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Publication number: 20140205831Abstract: A pre-impregnated yarn having a bundle made of reinforcing fiber filaments impregnated with a first resin composition infiltrated into the pre-impregnated yarn and at least partially connected via the first resin composition. The first resin composition contains at least two bisphenol A epichlorohydrin resins H1 and H2 in a weight ratio H1:H2 of 1.1 to 1.4, and an aromatic polyhydroxy ether P1. The pre-impregnated yarn has a second resin composition on the bundle outer side in the form of adhesive particles or drops. The second resin composition is solid at ambient temperatures and has a melting temperature in the range from 80 to 150° C. The bundle interior and at least 50% of the surface of the bundle outer side are free of the second resin composition.Type: ApplicationFiled: July 20, 2012Publication date: July 24, 2014Applicant: TOHO TENAX EUROPE GMBHInventors: Markus Schneider, Silke Stüsgen, Silke Witzel, Bernd Wohlmann
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Patent number: 8771567Abstract: A process for producing fiber preforms for composite material components makes it possible to directly produce complex geometries in a flexible and low-cost manner by applying a plurality of dry fiber rovings independently of one another even in spatially uneven contours. It is no longer necessary to use cut fabric strips since fiber preforms are produced straight from the dry fiber rovings. This obviates the need to carry out production, transport and order picking processes. It is not necessary to cut fiber strips to size, and therefore a saving may be made on material. In addition, it is possible to increase the mechanical characteristic values in the composite material because it is not necessary to sew fiber webs. The described process can also readily be scaled since the number of dry fiber rovings arranged next to one another make it possible to vary the area which can be covered.Type: GrantFiled: October 13, 2010Date of Patent: July 8, 2014Assignees: Airbus Operations GmbH, Toho Tenax Europe GmbHInventors: Joachim Piepenbrock, Carsten Barlag, Pierre Zahlen, Bernd Wohlmann, Markus Schneider
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Publication number: 20130244018Abstract: A fiber preform for producing fiber composite structures, a wall thereof including a first zone made from reinforcing fiber bundles having a first resin composition and a second zone made from at least one fiber tape comprising at least one unidirectionally directed reinforcing yarn strand having a second resin composition. The reinforcing fiber bundles in the first zone are oriented in different spatial directions to each other when viewed in a direction parallel to the extension of the thickness. Each reinforcing fiber has a length of from 3 to 50 mm, and contains the first resin composition in a concentration of from 1 to 10 wt % of the fiber weight. The wall of the fiber preform has a proportion of reinforcing fibers of more than 35 vol %, and the second zone forms a discrete region when viewed in a direction perpendicular to the thickness extension of the wall.Type: ApplicationFiled: November 11, 2011Publication date: September 19, 2013Applicant: TOHO TENAX EUROPE GMBHInventors: Bernd Wohlmann, Markus Schneider, Andreas Woginger, Frank Oberwahrenbrock
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Publication number: 20130183227Abstract: A fusible lignin has a gas transition temperature in the range between 90 and 160° C. determined using differential scanning calorimetry (DSC), a molar mass distribution with a dispersivity of less than 28, determined using gel permeation chromatography (GPC), an ash content of less than 1 wt. %, and a proportion of volatile components of a maximum of 1 wt. %. Also provided is a precursor fiber based on the fusible lignin, as well as a method for the production thereof Also provided is a method for producing a carbon fiber from the precursor fiber.Type: ApplicationFiled: September 8, 2011Publication date: July 18, 2013Applicant: TOHO TENAX EUROPE GMBHInventors: Bernd Wohlmann, Michael Wolki, Silke Stusgen
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Patent number: 8273454Abstract: A yarn includes reinforcing fiber filaments and a resin that is infiltrated into the yarn and can be repeatedly melted and solidified by cooling to room temperature, wherein the filaments of the yarn are at least partially bound to one another by the resin, wherein the yarn contains 2.5 to 25 wt.% of infiltrated resin relative to its total weight, and wherein the infiltrated resin includes a mixture of at least two epoxy resins E1 and E2, E1 having an epoxy value in the range of 2,000 to 2,300 mmol/kg of resin and E2 having an epoxy value in the range of 500 to 650 mmol/kg of resin, and the weight ratio E1:E2 of the epoxy resins E1 and E2 in the mixture is chosen so that the infiltrated resin mixture has an epoxy value between 550 and 2,100 mmol/kg of resin. A preform comprising the yarn, a method for producing the preform and its use in producing a composite are also described.Type: GrantFiled: March 29, 2005Date of Patent: September 25, 2012Assignee: Toho Tenax Europe GmbHInventors: Markus Schneider, Bernd Wohlmann
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Publication number: 20120137446Abstract: A method for stabilizing yarns made from polyacrylonitrile using chemical stabilization reactions, including: generating a field of high-frequency electromagnetic waves in an application space of an applicator, which has areas with minimum electric field strength and areas with maximum electric field strength, the maximum electric field strength in the application space being in a range from 3 to 150 kV/m; continuously supplying a precursor yarn based on a polyacrylonitrile polymer into the application space, and conveying the precursor yarn through the application space and through the field of the high-frequency electromagnetic waves; introducing a process gas into the application space and conveying the process gas through the application space with a flow rate of at least 0.1 m/s relative to the precursor yarn being conveyed through the application space, wherein a temperature of the process gas is in a range between 150 and 300° C.Type: ApplicationFiled: August 31, 2010Publication date: June 7, 2012Applicant: TOHO TENAX EUROPE GMBHInventors: Bernd Wohlmann, Michael Wolki, Christian Hunyar, Rudolf Emmerich, Mathias Kaiser, Matthias Graf, Lukas Alberts, Klaus-Dieter Nauenburg
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Publication number: 20110274612Abstract: A lignin derivative is produced from a lignin with the empirical formula L(OH)z, where L is a lignin without hydroxyl groups, OH are free hydroxyl groups bonded to L, and z is 100% of the free hydroxyl groups bonded to L. The lignin derivative has free hydroxyl groups that are derivatized with divalent residues Rx and monovalent residues Ry that are bonded to L via an ester, ether, or urethane group. A shaped body comprising the lignin derivative can take the form of a fiber, e.g. as precursor fiber for the production of a carbon fiber. A carbon fiber can be produced from the above-mentioned precursor fiber.Type: ApplicationFiled: January 11, 2010Publication date: November 10, 2011Applicants: FRAUNHOFER GESEIISCHAFT ZUR FORDERUNG DER ANGEWANDTEN FORSCHUNG E.V., TOHO TENAX EUROPE GMBHInventors: Bernd Wohlmann, Michael Wolki, Andreas Ebert, Gunnar Engelmann, Hans-Peter Fink
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Publication number: 20110104489Abstract: A process for the production of hollow carbon fibres by the treatment of a stabilised carbon fibre precursor in an application device using high-frequency electromagnetic waves. The application device includes structure supplying the electromagnetic waves to a outcoupling region and a hollow outer conductor terminating in the outcoupling region. For the treatment, a field of the high-frequency electromagnetic waves is generated and a field strength in the range from 15 to 40 kV/m is set in the outcoupling region of the application device. The stabilised carbon fibre precursor is conveyed continuously as an inner conductor through the hollow outer conductor, thereby forming a coaxial conductor having an outer and an inner conductor, and through the subsequent outcoupling region. An inert gas atmosphere is created in the coaxial conductor and in the outcoupling region by passing through an inert gas.Type: ApplicationFiled: September 17, 2008Publication date: May 5, 2011Applicant: TOHO TENAX CO., LTD.Inventors: Michael Wolki, Bernd Wohlmann, Mathias Kaiser, Rudolf Emmerich, Frank Henning
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Patent number: 7867612Abstract: A composite material is described that contains a reinforcing resin and reinforcing fibers, wherein the reinforcing fibers have a coating containing polyphenylene sulfide and the proportion of polyphenylene sulfide relative to the uncoated fibers is 0.001 to <0.01 wt. %. The composite material shows higher apparent interlaminar shear strength and bending strength as compared with similar composite materials having no PPS coating in the above concentration range.Type: GrantFiled: March 28, 2003Date of Patent: January 11, 2011Assignee: Toho Tenax Europe GmbHInventors: Klaus Peter Schwung, Bernd Wohlmann
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Publication number: 20090277772Abstract: A process for continuous production of carbon fibres whereby stabilised precursor fibres are carbonised and graphitised with the help of high-frequency electromagnetic waves, characterised in that the stabilised precursor fibres are continuously conveyed, as the inner conductor of a coaxial conductor consisting of an outer and an inner conductor, through the coaxial conductor and a treatment zone; that the stabilised precursor fibres are irradiated in the treatment zone with high-frequency electromagnetic waves that are absorbed by the precursor fibres, which are thereby heated and converted into carbon fibres; and that the stabilised precursor fibres or carbon fibres are conveyed under an inert gas atmosphere through the coaxial conductor and the treatment zone.Type: ApplicationFiled: March 31, 2007Publication date: November 12, 2009Applicant: TOHO TENAX CO., LTD.Inventors: Mathias Kaiser, Lukas Alberts, Frank Henning, Rudolf Emmerich, Christian Hunyar, Klaus-Dieter Nauenburg, Ralf Dreher, Peter Elsner, Bernd Wohlmann
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Publication number: 20090092831Abstract: Carbon fibers and carbon fiber yarn consisting of carbon fibers, the fibers having been pretreated by electrochemical oxidation, characterized in that they have a finish consisting of epoxy resin(s), a vinyl component, and a plasticizer in an amount of 0.3 to 5 wt. % relative to the carbon fibers, which are to be provided with the finish.Type: ApplicationFiled: April 19, 2007Publication date: April 9, 2009Applicant: TOHO TENAX EUROPE GMBHInventors: Silke Stusgen, Bernd Wohlmann, Matthias Schubert
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Publication number: 20090014119Abstract: A process for manufacturing bonded laid structures from yarns, characterized in that a thermally fusible material is applied to the yarns at least at the contact or intersection points via a thermal spray process and the yarns are subsequently brought together, as well as a process for manufacturing a fiber-reinforced composite material, characterized in that, initially, laid structures according to the invention are manufactured and subsequently, with the addition of further thermally fusible material if necessary, the structures are molded under heat and pressure into the fiber-reinforced composite material.Type: ApplicationFiled: February 27, 2007Publication date: January 15, 2009Applicant: Toho Tenax Europe GmbHInventors: Bernd Wohlmann, Andreas Woeginger
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Publication number: 20070196636Abstract: A yarn includes reinforcing fiber filaments and a resin that is infiltrated into the yarn and can be repeatedly melted and solidified by cooling to room temperature, wherein the filaments of the yarn are at least partially bound to one another by the resin, wherein the yarn contains 2.5 to 25 wt. % of infiltrated resin relative to its total weight, and wherein the infiltrated resin includes a mixture of at least two epoxy resins E1 and E2, E1 having an epoxy value in the range of 2,000 to 2,300 mmol/kg of resin and E2 having an epoxy value in the range of 500 to 650 mmol/kg of resin, and the weight ratio E1:E2 of the epoxy resins E1 and E2 in the mixture is chosen so that the infiltrated resin mixture has an epoxy value between 550 and 2,100 mmol/kg of resin. A preform comprising the yarn, a method for producing the preform and its use in producing a composite are also described.Type: ApplicationFiled: March 29, 2005Publication date: August 23, 2007Applicant: Toho Tenax Europe GmbHInventors: Markus Schneider, Bernd Wohlmann