Abstract: The present invention relates to a method for producing a multicoat paint system on a metallic substrate, in which a basecoat or a plurality of directly successive basecoats are produced directly on a metallic substrate coated with a cured electrocoat, a clearcoat is produced directly on the one basecoat or the uppermost of the plurality of basecoats, and then the one or more basecoats and the clearcoat are jointly cured, and wherein at least one basecoat material used for production of the basecoats comprises the following components: an aqueous dispersion comprising at least one specific copolymer, a specific linear hydroxy-functional reaction product and a polyurethane resin, the preparation of which involves using at least one compound containing at least one carboxylic acid group and at least one group reactive toward isocyanate groups.

Abstract: The present invention relates to a reaction product preparable by reacting (a) dimer fatty acids with (b) at least one compound (b) of the general structural formula (I) where R is a C3 to C6 alkylene radical and n correspondingly is selected such that the compound (b) possesses a number-average molecular weight of 120 to 445 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.6/1.7, and the resulting reaction product possesses a number-average molecular weight of 600 to 4000 g/mol and an acid number of less than 10 mg KOH/g. The invention further relates to a pigmented aqueous basecoat material which comprises this reaction product, and to the use of the reaction product in pigmented aqueous basecoat materials for improving adhesion. The present invention further relates to a method for producing multicoat paint systems, and also to the multicoat paint systems producible by means of said method.

Abstract: Described herein is a method of using aromatic and/or araliphatic carboxylic acids in preparation of aqueous basecoat materials for the purpose of improving the adhesion of the aqueous basecoat materials to overbaked clearcoat materials. Also described herein is a method for producing a multicoat paint system, where a basecoat material is applied directly to an overbaked clearcoat film.

Abstract: Described herein is a method of using organic carboxylic acids having 1 to 10 carbon atoms in preparation of aqueous basecoat materials for the purpose of improving the adhesion of the aqueous basecoat materials to overbaked clearcoat materials. Also described herein is a method for producing a muilticoat paint system, where a basecoat material is applied directly to an overbaked clearcoat film.

Abstract: Described herein is a pigmented aqueous basecoat material including a polyether-based reaction product which is preparable by reaction of (a) at least one cyclic tetracarboxylic dianhydride having an aliphatic, aromatic, or araliphatic radical X bridging the two anhydride groups with (b) at least one polyether of the general structural formula (II) in which R is a C3 to C6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 500 to 5000 g/mol, the components (a) and (b) being used in the reaction in a molar ratio of 0.7/2.3 to 1.6/1.7 and the resulting reaction product possessing an acid number of 5 to 80 mg KOH/g. Also described herein is a reaction product of specific dianhydrides and a polyether, and the use of the pigmented aqueous basecoat material or the reaction product.

Abstract: The present invention relates to a dimer fatty acid/dimer diol reaction product which is preparable by reacting (a) dimer fatty acids with (b) at least one dimer diol, where components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7 and the resulting dimer fatty acid/dimer diol reaction product possesses a number-average molecular weight of 1200 to 5000 g/mol and an acid number <10 mg KOH/g. The invention further relates to a pigmented aqueous basecoat material which comprises this dimer fatty acid/dimer diol reaction product, and also to the use of said dimer fatty acid/dimer diol reaction product in pigmented aqueous basecoat materials. It relates, further, to a method for producing multicast paint systems, and also to the multicoat paint systems producible by means of said method. The present invention relates, furthermore, to the refinishing of defects on multicoat paint systems.

Abstract: A pigmented aqueous basecoat material is disclosed. The pigmented aqueous basecoat material includes a polyether-based reaction product which is preparable by a reaction of trimesic acid with at least one polyether of the general structural formula (I) R is a C3 to C6 alkylene radical and n is selected accordingly such that the at least one polyether possesses a number-average molecular weight of 500 to 5000 g/mol. The trimesic acid and the at least one polyether are used in the reaction in a molar ratio of 0.7/2.3 to 1.6/1.7 and the resulting reaction product possesses an acid number of 10 to 50 mg KOH/g.

Abstract: The present invention relates to a pigmented aqueous basecoat material comprising a polyether-based reaction product which is preparable by reaction of (a) at least one cyclic carboxylic anhydride comprising a free carboxylic acid group and/or the halide of a carboxylic acid group with (b) at least one polyether of the general structural formula (I) in which R is a C3 to C6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 800 to 4000 g/mol, the components (a) and (b) being used in the reaction in a molar ratio of 0.7/2.3 to 1.6/1.7 and the resulting reaction product possessing an acid number of 10 to 50 mg KOH/g.

Abstract: The present invention relates to a pigmented aqueous basecoat material including a polyether-based reaction product which is preparable by reaction of (a) at least one carboxy-functional component which is preparable by esterification reaction of at least one dihydroxycarboxylic acid (a1) with at least one dicarboxylic acid (a2) and/or the anhydride of a dicarboxylic acid (a2), the components (a1) and (a2) being used in a molar ratio of 0.5/3.0 to 1.7/1.8, with (b) at least one polyether of a general structural formula (I) in which R is a C3 to C6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 500 to 5000 g/mol, the components (a) and (b) being used in the reaction in a molar ratio of 0.7/2.3 to 1.6/1.7, and the resulting reaction product possessing an acid number of 10 to 50 mg KOH/g.

Abstract: The present invention relates to an aqueous polyurethane-polyurea dispersion (PD) having polyurethane-polyurea particles, present in the dispersion, having an average particle size of 40 to 2000 nm, and having a gel fraction of at least 50%, obtainable by (I) preparing a composition (Z) comprising, based in each case on the total amount of the composition (Z), (Z.1) 15 to 65 wt % of at least one intermediate containing isocyanate groups and having blocked primary amino groups, its preparation comprising the reaction (Z.1.1) of at least one polyurethane prepolymer containing isocyanate groups and comprising anionic groups and/or groups which can be converted into anionic groups, with (Z.1.2) at least one polyamine comprising at least two blocked primary amino groups and at least one free secondary amino group, by addition reaction of isocyanate groups from (Z.1.1) with free secondary amino groups from (Z.1.2), (Z.

Abstract: Provided herein is a pigmented aqueous basecoat material including an aqueous polyurethane-polyurea dispersion (PD) having polyurethane-polyurea particles present in the dispersion, an average particle size (volume average) of 40 to 2000 nm, and a gel fraction of at least 50 wt %. The polyurethane-polyurea particles, in each case in reacted form, include: at least one polyurethane prepolymer containing isocyanate groups and including anionic groups and/or groups which can be converted into anionic groups, and at least one polyamine comprising two primary amino groups and one or two secondary amino groups. The aqueous basecoat material includes a specific solvent composition. Also provided herein is a method of using basecoat materials including the dispersion (PD) and multicoat paint systems produced using the basecoat materials.

Abstract: The present invention relates to a pigmented aqueous basecoat material comprising a polyether-based reaction product which is preparable by reaction of (a) at least one dicarboxylic acid of the formula (I) HOOC—Y—COOH??(I) in which Y is a divalent aliphatic, aromatic or araliphatic hydrocarbon radical having from 4 to 11 carbon atoms, with (b) at least one polyether of the general structural formula (II) in which R is a C4 to C6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 200 to 4000 g/mol, where components (a) and (b) are used in the reaction in a molar ratio of 0.7/2.3 to 1.6/1.7 and the resulting reaction product possesses a number-average molecular weight of 500 to 15 000 g/mol and an acid number of less than 10 mg KOH/g.

Abstract: The present invention relates to a pigment paste comprising at least one aqueous dispersion comprising at least one copolymer, said copolymer being preparable by (i) initially charging an aqueous dispersion of at least one polyurethane, and then (ii) polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane from (i), in which (a) a water-soluble initiator is used, (b) the olefinically unsaturated monomers are metered in such that a concentration of 6.0% by weight, based on the total amount of olefinically unsaturated monomers used for polymerization, in the reaction solution is not exceeded over the entire reaction time, and (c) the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer, and further comprising a pigment, where the weight ratio of pigment to copolymer is at least 1.5. The invention further relates to the use of the copolymer for dispersion of pigments.

Abstract: The present invention relates to a pigmented aqueous basecoat material comprising a polyether-based reaction product which is preparable by reaction of (a) at least one dicarboxylic acid of the formula (I) HOOC—Y—COOH??(I) in which Y is a divalent aliphatic, aromatic or araliphatic hydrocarbon radical having from 4 to 11 carbon atoms, with (b) at least one polyether of the general structural formula (II) in which R is a C4 to C6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 200 to 4000 g/mol, where components (a) and (b) are used in the reaction in a molar ratio of 0.7/2.3 to 1.6/1.7 and the resulting reaction product possesses a number-average molecular weight of 500 to 15 000 g/mol and an acid number of less than 10 mg KOH/g.

Abstract: The present invention relates to an aqueous coating composition comprising at least one aqueous dispersion comprising at least one copolymer (CP), said copolymer (CP) being preparable by (i) initially charging an aqueous dispersion of at least one polyurethane, and then (ii) polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane from (i), in which (a) a water-soluble initiator is used, (b) the olefinically unsaturated monomers are metered in such that a concentration of 6.0% by weight, based on the total amount of olefinically unsaturated monomers used for polymerization, in the reaction solution is not exceeded over the entire reaction time, and (c) the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer, at least one linear hydroxy-functional reaction product (R) having an acid number less than 20 mg KOH/g, the preparation of which involves using at least one compound (v) containing two functional groups (v.

Abstract: The invention relates to the use of phosphoric acid and/or of monoesters and/or diesters of phosphoric acid in aqueous basecoat materials for improving adhesion of these coating materials to overbaked clearcoat materials which comprise boron compounds.

Abstract: The present invention relates to a method for producing a multicoat paint system on a metallic substrate, in which a basecoat or a plurality of directly successive basecoats are produced directly on a metallic substrate coated with a cured electrocoat, a clearcoat is produced directly on the one basecoat or the uppermost of the plurality of basecoats, and then the one or more basecoats and the clearcoat are jointly cured, and wherein at least one basecoat material used for production of the basecoats comprises at least one aqueous dispersion comprising at least one copolymer (CP), said copolymer (CP) being preparable by initially charging an aqueous dispersion of at least one polyurethane, and then polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane from (i), in which a water-soluble initiator is used, the olefinically unsaturated monomers are metered in such that a concentration of 6.

Abstract: Described is a method for producing a multicoat color and/or effect paint system. The method is characterized in that a pigmented aqueous basecoat material is used which comprises at least one phosphine oxide of formula (I): wherein the radicals R1 to R3 are selected from the group of aliphatic or aromatic hydrocarbons. The sum total of the weight percentage fractions of all of the phosphine oxides of formula (I) is 0.1% to 5% by weight, based on the total weight of the basecoat material. Also described are the corresponding basecoat materials, a corresponding multicoat color and/or effect paint system, and use of the phosphine oxides in pigmented aqueous coating materials. Further describes is a method for repairing defects on multicoat color and/or effect paint systems produced with the aid of the method of the invention.

Abstract: The present invention relates to an aqueous polyurethane-polyurea dispersion (PD) having polyurethane-polyurea particles, present in the dispersion, having an average particle size of 40 to 2000 nm, and having a gel fraction of at least 50%, the polyurethane-polyurea particles comprising, in each case in reacted form, (Z.1.1) at least one polyurethane prepolymer containing isocyanate groups and comprising anionic groups and/or groups which can be converted into anionic groups, and (Z.1.2) at least one polyamine comprising two primary amino groups and one or two secondary amino groups, and the dispersion (PD) consisting to an extent of at least 90 wt % of the polyurethane-polyurea particles and water. The present invention also relates to basecoat materials comprising the dispersion (PD), and to multicoat paint systems produced using the basecoat materials.

Abstract: An aqueous dispersion containing at least one copolymer, the copolymer being preparable by initially charging an aqueous dispersion of at least one polyurethane, and then polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane, where a water-soluble initiator is used, the metered addition of the olefinically unsaturated monomers is effected in such a way that a concentration of 6.0% by weight, based on the total amount of olefinically unsaturated monomers, in the reaction solution is not exceeded over the entire duration of the reaction, and the mixture of the olefinically unsaturated monomers contains at least one polyolefinically unsaturated monomer.