Patents by Inventor Bert Klesczewski

Bert Klesczewski has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20160264519
    Abstract: The present invention relates to a process for preparing polyether polyols by addition of alkylene oxides onto H-functional starter substances, characterized in that at least one urethane alcohol of formula (H) where R1 is linear or branched C2 to C24-alkylene which may optionally be interrupted by heteroatoms such as O, S or N and may be substituted, R2 is linear or branched C2 to C24-alkylene which may optionally be interrupted by heteroatoms such as O, S or N and may be substituted, R3 is H, linear or branched C1 to C24-alkyl, C3 to C24-cycloalkyl, C4 to C24-aryl, C5 to C24-aralkyl. C2 to C24-alkenyl, C2 to C24-alkynyl, each of which may optionally be interrupted by heteroatoms such as O, S or N and/or each of which may be substituted by alkyl, aryl and/or hydroxyl, is used as H-functional starter compound.
    Type: Application
    Filed: November 19, 2014
    Publication date: September 15, 2016
    Inventors: Jörg HOFMANN, Kai LAEMMERHOLD, Hartmut NEFZGER, Monika HEINZ, Bert KLESCZEWSKI, Klaus LORENZ
  • Publication number: 20160257776
    Abstract: The present invention relates to a method for producing flexible polyurethane foams, wherein an isocyanate component (component B) is used which comprises polyether carbonate polyol, and to the isocyanate component itself. The invention also provides an NCO-terminated, urethane group-comprising prepolymer obtainable by reaction of one or more polyisocyanates (B1) with one or more polyether carbonate polyols.
    Type: Application
    Filed: May 16, 2016
    Publication date: September 8, 2016
    Inventors: Gundolf Jacobs, Sven Meyer-Ahrens, Bert klesczewski, Angelika Schultz
  • Patent number: 9328196
    Abstract: The present invention relates to a process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups. It furthermore relates to polyricinoleic acid ester polyols obtainable according to the invention and polyurethane polymers prepared using these polyols. The process comprises the steps: a) polycondensation of ricinoleic acid until a hydroxyl number of >0 mg of KOH/g to <60 mg of KOH/g is reached; and b) reaction of the product obtained in step a) or of a secondary product of the product obtained in step a) comprising carboxyl groups with an epoxide of the general formula (I), wherein R1 represents hydrogen, an alkyl radical or an aryl radical, with the proviso that >80% by weight to <100% by weight, based on the total amount of the epoxide (I) employed, is ethylene oxide and the reaction is carried out in the presence of an amine as the catalyst.
    Type: Grant
    Filed: November 18, 2011
    Date of Patent: May 3, 2016
    Assignee: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Jörg Hofmann, Erika Bauer, Bert Klesczewski, Klaus Lorenz
  • Patent number: 9193822
    Abstract: The invention relates to a process for producing polyester polyols with secondary hydroxyl end groups, including the step of the reaction of a polyester including carboxyl end groups with an epoxide of the general formula (1): wherein R1 stands for an alkyl residue or an aryl residue and the reaction is carried out in the presence of a catalyst that includes at least one nitrogen atom per molecule. The process is distinguished in that the polyester including carboxyl end groups exhibits an acid value from ?25 mg KOH/g to ?400 mg KOH/g and a hydroxyl value from ?5 mg KOH/g and in that the polyester including carboxyl end groups is produced by ?1.03 mol to ?1.90 mol carboxyl groups or carboxyl-group equivalents of an acid component being employed per mol hydroxyl groups of an alcohol. The polyester polyols obtained, including secondary hydroxyl end groups, can be used for the purpose of producing polyurethane polymers.
    Type: Grant
    Filed: May 4, 2010
    Date of Patent: November 24, 2015
    Assignee: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Erika Bauer, Jörg Hofmann, Klaus Lorenz, Bert Klesczewski
  • Publication number: 20150299373
    Abstract: The present invention relates to a process for the production of flexible polyurethane foams, wherein there is used as starting material a polyester polyol component which is composed of at least two dicarboxylic acids.
    Type: Application
    Filed: October 23, 2013
    Publication date: October 22, 2015
    Applicant: BAYER MATERIALSCIENCE AG
    Inventors: Hartmut NEFZGER, Bert KLESCZEWSKI, Sven MEYER-AHRENS, Harald KNAUP
  • Patent number: 9139685
    Abstract: The invention relates to a process for the preparation of a polyurethane polymer, comprising the step of reaction of A) polyester polyols with secondary hydroxyl end groups, which are obtainable from the reaction of a polyester comprising carboxyl end groups with an epoxide of the general formula (1): wherein R1 represents an alkyl radical or an aryl radical and wherein the polyester comprising carboxyl end groups has an acid number of from ?25 mg of KOH/g to ?400 mg of KOH/g and a hydroxyl number of ?5 mg of KOH/g, with B) polyisocyanates which are chosen from the group comprising toluoylene-diisocyanate, diphenylmethane-diisocyanate, polymeric diphenylmethane-diisocyanate, xylylene-diisocyanate, naphthylene-diisocyanate, hexamethylene-diisocyanate, diisocyanatodicyclohexylmethane and/or isophorone-diisocyanate. The invention furthermore relates to polyurethane polymers prepared by such a process.
    Type: Grant
    Filed: June 29, 2010
    Date of Patent: September 22, 2015
    Assignee: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Jörg Hofmann, Bert Klesczewski, Erika Bauer, Klaus Lorenz
  • Publication number: 20150141542
    Abstract: The present invention provides a method for producing flame-retardant polyurethane foams, the resulting flame-retardant polyurethane foams having particularly low densities.
    Type: Application
    Filed: May 17, 2013
    Publication date: May 21, 2015
    Applicant: BAYER MATERIALSCIENCE AG
    Inventors: Sven Meyer-Ahrens, Stefan Lindner, Bert Klesczewski
  • Publication number: 20140329985
    Abstract: The present invention provides a process for producing polyether ester polyols on the basis of renewable raw materials, the polyether ester polyols produced by the process according to the invention, the use thereof for the purpose of producing polyurethanes, and also polyurethanes containing the polyether ester polyols according to the invention
    Type: Application
    Filed: December 19, 2011
    Publication date: November 6, 2014
    Inventors: Klaus Lorenz, Jörg Hofmann, Bert Klesczewski, Norber Hahn
  • Patent number: 8715778
    Abstract: The present invention relates to ballast which have a high stability and a long service life and to a process for the production of ballast. These ballast are suitable for railway track laying and road construction and dike systems used for example in costal protection. These ballast comprise ballast stones and polyurethane foams based on a reaction mixture of selected polyisocyanates and selected compounds with isocyanate-reactive groups.
    Type: Grant
    Filed: January 17, 2007
    Date of Patent: May 6, 2014
    Assignee: Bayer MaterialScience AG
    Inventors: Andreas Hoffmann, Heinz-Dieter Ebert, Bert Klesczewski
  • Publication number: 20140107245
    Abstract: The invention relates to a method for producing polyether carbonate polyols, wherein (i) in a first step a polyether carbonate polyol is produced from one or more H-functional starter substances, one or more alkylene oxides, and carbon dioxide in the presence of at least one DMC catalyst, and (ii) in a second step the polyether carbonate polyol is chain-extended with a mixture of at least two different alkylene oxides in the presence of at least one DMC catalyst. The invention further relates to polyether carbonate polyols that contain a terminal mixed block of at least two alkylene oxides and to a method for producing soft polyurethane foams, wherein a polyol component containing a polyether carbonate polyol according to the invention is used.
    Type: Application
    Filed: May 30, 2012
    Publication date: April 17, 2014
    Applicant: Bayer Intellectual Property GmbH
    Inventors: Jörg Hofmann, Bert Klesczewski, Michael Schneider
  • Publication number: 20140066535
    Abstract: The present invention relates to a method for producing flexible polyurethane foams, wherein an isocyanate component (component B) is used which comprises polyether carbonate polyol, and to the isocyanate component itself. The invention also provides an NCO-terminated, urethane group-comprising prepolymer obtainable by reaction of one or more polyisocyanates (B1) with one or more polyether carbonate polyols.
    Type: Application
    Filed: March 23, 2012
    Publication date: March 6, 2014
    Applicant: Bayer Intellectual Property GmbH
    Inventors: Gundolf Jacobs, Sven Meyer-Ahrens, Bert Klesczewski, Angelika Schulz
  • Publication number: 20130345330
    Abstract: A process for the preparation of polyricinoleic acid esters comprising the step of reaction of ricinoleic acid with an alcohol component which comprises mono- and/or polyfunctional alcohols having a molecular weight of ?32 g/mol to ?40 g/mol, wherein the reaction is carried out at least partly in the presence of a catalyst. The amount of catalyst, based on the total weight of the ricinoleic acid and the alcohol component, is in a range of from ?10 ppm to ?100 ppm. The reaction is ended when the acid number of the reaction product obtained is ?5 mg of KOH/g to ?100 mg of KOH/g. The invention furthermore relates to a polyurethane polymer, in particular a flexible polyurethane foam, which is obtainable using these polyricinoleic acid esters.
    Type: Application
    Filed: November 18, 2011
    Publication date: December 26, 2013
    Applicant: BAYER INTELLECTUAL PROPERTY GMBH
    Inventors: Hartmut Nefzger, Erika Bauer, Bert Klesczewski, Jüergen Schlossmacher, Sven Meyer-Ahrens, Manfred Schmidt
  • Publication number: 20130261205
    Abstract: The present invention relates to a process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups. It furthermore relates to polyricinoleic acid ester polyols obtainable according to the invention and polyurethane polymers prepared using these polyols. The process comprises the steps: a) polycondensation of ricinoleic acid until a hydroxyl number of >0 mg of KOH/g to <60 mg of KOH/g is reached; and b) reaction of the product obtained in step a) or of a secondary product of the product obtained in step a) comprising carboxyl groups with an epoxide of the general formula (I), wherein R1 represents hydrogen, an alkyl radical or an aryl radical, with the proviso that >80% by weight to <100% by weight, based on the total amount of the epoxide (I) employed, is ethylene oxide and the reaction is carried out in the presence of an amine as the catalyst.
    Type: Application
    Filed: November 18, 2011
    Publication date: October 3, 2013
    Applicant: Bater Intellectual Property GmbH
    Inventors: Hartmut Nefzger, Jörg Hofmann, Erika Bauer, Bert Klesczewski, Klaus Lorenz
  • Publication number: 20130237624
    Abstract: The present invention relates to a method for producing flexible polyurethane foams, wherein a polyol component which comprises polyricinoleic acid esters is used as starting substance. The flexible polyurethane foams according to the invention have a bulk density according to DIN EN ISO 3386-1-98 in the range of ?10 kg/m3 to ?150 kg/m3, preferably ?20 kg/m3 to ?70 kg/m3, and in general their compressive strength according to DIN EN ISO 3386-1-98 is in the range of ?0.5 kPa to ?20 kPa (at 40% deformation and 4th cycle). The polyricinoleic acid esters are obtainable by the reaction of ricinoleic acid with an alcohol component which comprises mono- and/or polyhydric alcohols with a molecular mass of ?32 g/mol to ?400 g/mol, the reaction being carried out at least in part in the presence of a catalyst.
    Type: Application
    Filed: November 18, 2011
    Publication date: September 12, 2013
    Applicant: BAYER INTELLECTUAL PROPERTY GMBH
    Inventors: Bert Klesczewski, Gundolf Jacobs, Sven Meyer-Ahrens, Hartmut Nefzger
  • Patent number: 8183302
    Abstract: The present invention relates to polyether polyol compositions containing renewable raw materials, a process for preparing visco-elastic polyurethane foams using such compositions, correspondingly prepared visco-elastic foam materials, and the use thereof.
    Type: Grant
    Filed: February 23, 2009
    Date of Patent: May 22, 2012
    Assignee: Bayer MaterialScience AG
    Inventors: Bert Klesczewski, Sebastien Triouleyre, Matthäus Gossner, Sven Meyer-Ahrens, Alice Mosbach-Rosenberger
  • Publication number: 20120123008
    Abstract: The invention relates to a process for the preparation of a polyurethane polymer, comprising the step of reaction of A) polyester polyols with secondary hydroxyl end groups, which are obtainable from the reaction of a polyester comprising carboxyl end groups with an epoxide of the general formula (1): wherein R1 represents an alkyl radical or an aryl radical and wherein the polyester comprising carboxyl end groups has an acid number of from ?25 mg of KOH/g to ?400 mg of KOH/g and a hydroxyl number of ?5 mg of KOH/g, with B) polyisocyanates which are chosen from the group comprising toluoylene-diisocyanate, diphenylmethane-diisocyanate, polymeric diphenylmethane-diisocyanate, xylylene-diisocyanate, naphthylene-diisocyanate, hexamethylene-diisocyanate, diisocyanatodicyclohexylmethane and/or isophorone-diisocyanate. The invention furthermore relates to polyurethane polymers prepared by such a process.
    Type: Application
    Filed: June 29, 2010
    Publication date: May 17, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Jörg Hofmann, Bert Klesczewski, Erika Bauer, Klaus Lorenz
  • Publication number: 20120116114
    Abstract: The invention relates to a process for producing polyester polyols with secondary hydroxyl end groups, including the step of the reaction of a polyester including carboxyl end groups with an epoxide of the general formula (1): wherein R1 stands for an alkyl residue or an aryl residue and the reaction is carried out in the presence of a catalyst that includes at least one nitrogen atom per molecule. The process is distinguished in that the polyester including carboxyl end groups exhibits an acid value from ?25 mg KOH/g to ?400 mg KOH/g and a hydroxyl value from ?5 mg KOH/g and in that the polyester including carboxyl end groups is produced by ?1.03 mol to ?1.90 mol carboxyl groups or carboxyl-group equivalents of an acid component being employed per mol hydroxyl groups of an alcohol. The polyester polyols obtained, including secondary hydroxyl end groups, can be used for the purpose of producing polyurethane polymers.
    Type: Application
    Filed: May 4, 2010
    Publication date: May 10, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Hartmut Nefzger, Erika Bauer, Jörg Hofmann, Klaus Lorenz, Bert Klesczewski
  • Publication number: 20120108690
    Abstract: The subject-matter of the present invention relates to a process for the production of flame-retardant polyurethane foams, preferably for the production of flame-retardant flexible polyurethane foams, from A1 a filler-containing polyether polyol (component A1.1), wherein the filler is a reaction product of a di- or poly-isocyanate with a compound containing isocyanate-reactive hydrogen atoms, and optionally further compounds containing isocyanate-reactive hydrogen atoms and having a molecular weight of from 400 to 18,000 (component A1.
    Type: Application
    Filed: July 6, 2010
    Publication date: May 3, 2012
    Applicant: Bayer MaterialScience AG
    Inventors: Bert Klesczewski, Manduela Otten, Sven Meyer-Ahrens
  • Publication number: 20100305228
    Abstract: The present invention provides a process for the production of polyurethane foams from A1 compounds which contain hydrogen atoms which are reactive towards isocyanates and have a molecular weight of 400-15,000, A2 optionally compounds which contain hydrogen atoms which are reactive towards isocyanates and have a molecular weight of 62-399, A3 water and/or physical blowing agents, A4 optionally auxiliary substances and additives, such as a) catalysts which differ from component A5, b) surface-active additives, c) pigments or flameproofing agents, A5 at least one tin(II) salt of carboxylic acids, the carboxylic acid having from 10 to 16 carbon atoms, and B di- or polyisocyanates, wherein the resulting polyurethane foams have low emission values and a good resistance to ageing.
    Type: Application
    Filed: May 21, 2010
    Publication date: December 2, 2010
    Applicant: Bayer MaterialScience AG
    Inventors: Matthäus Gossner, Peter Haas, Sven Meyer-Ahrens, Bert Klesczewski
  • Publication number: 20090264547
    Abstract: The present invention relates to polyether polyol compositions containing renewable raw materials, a process for preparing visco-elastic polyurethane foams using such compositions, correspondingly prepared visco-elastic foam materials, and the use thereof.
    Type: Application
    Filed: February 23, 2009
    Publication date: October 22, 2009
    Applicant: Bayer MaterialScience AG
    Inventors: Bert Klesczewski, Sebastien Triouleyre, Matthaeus Gossner, Sven Meyer-Ahrens, Alice Mosbach-Rosenberger