Abstract: An apparatus and method for producing a hydrogen-enriched reformate. The apparatus includes a fuel processor for converting a fuel to a reformate having fluctuations in pressure and or flow rate, means for reducing the fluctuations, a compression unit for compressing the reformate and one or more of a purification unit and a storage unit downstream of a compression unit. Means for reducing the fluctuations in the reformate can include one or more of a buffer and a conduit for providing a controlled flow of a supplemental fluid to an inlet of the compression unit. The supplemental fluid can include the compressed reformate, a hydrogen-enriched reformate, and mixtures thereof. The apparatus can include means for regulating power to the compression unit that can incrementally increase power to the compression unit particularly during start up. The purification unit can include one or more of a hydrogen selective membrane and a pressure swing adsorption unit. Methods for producing hydrogen are also disclosed.

Abstract: An apparatus and method for producing a hydrogen-enriched reformate. The apparatus includes a fuel processor for producing a reformate having fluctuations in a pressure and/or flow rate and means for reducing the fluctuations. The reformate comprises impurities that are removed by a purification unit having a plurality of adsorbent beds. A valve assembly controls the flow of reformate to the adsorbent beds based upon sensed product data generated by a product sensor. A compression unit optionally compresses the reformate prior to entering the purification unit. Means for reducing fluctuations in the pressure and/or flow rate include a buffer and/or a conduit for providing a controlled flow of a supplemental fluid to an inlet of the compression unit. A product valve can control the flow of hydrogen-enriched reformate out of the purification unit.

Abstract: A method for operating a combustor having a catalyst bed. The method includes the steps of directing a flow of air through a catalyst bed, providing heat to the catalyst bed, sensing the temperature in an upstream portion of the catalyst bed to provide an upstream temperature, directing a flow of a fuel through the catalyst bed when the upstream temperature reaches a light-off temperature to produce a combustion reaction, increasing the flow of the fuel until the flow of air and the flow of fuel have a selected air to fuel ratio, and controlling the combustion reaction within the catalyst bed by adjusting the flow of air and the flow of fuel while maintaining the selected air to fuel ratio. The method can include sensing temperatures within the catalyst bed and controlling the combustion reaction in response to the sensed temperatures. The heat provided to the catalyst bed can also be adjusted in response to the sensed temperatures.

Abstract: A method and apparatus for use in controlling the reaction temperature of a fuel processor are disclosed. The apparatus includes a fuel processor reactor, the reactor including a water gas shift reaction section; a temperature sensor disposed within the reaction section; a coolant flow line through the reaction section; and an automated control system. The automated control system controls the reaction temperature by determining a first component for a setting adjustment for the actuator from the measured temperature and a setpoint for the measured temperature; determining a second component for the setting adjustment from a hydrogen production rate for the fuel processor; and determining the setting adjustment from the first and second components.

Abstract: In one embodiment, an electrochemical cell system comprises: a fuel cell stack comprising a fuel cell having a fuel cell hydrogen inlet and a fuel cell hydrogen outlet, and a first electrochemical hydrogen compressor in fluid communication with the fuel cell hydrogen outlet, wherein the first electrochemical hydrogen compressor comprises electrodes in electrical communication with an electricity source, and a compressed hydrogen outlet in fluid communication with the fuel cell hydrogen inlet. In one embodiment, the method of operating the electrochemical cell system comprises: introducing hydrogen feed to a fuel cell at a feed rate of greater than stoichiometry, directing excess hydrogen from the fuel cell to a first electrochemical hydrogen compressor, electrochemically compressing the excess hydrogen to compressed hydrogen, and recirculating the compressed hydrogen gas to the fuel cell.

Abstract: A method and apparatus for use in generating hydrogen are disclosed. The apparatus includes a fuel processor capable of producing a reformate from a fuel; a hydrogen purifier capable of generating a purified hydrogen gas stream from the reformate; a compressor capable of providing the reformate from the fuel processor to the pressure swing adsorption unit at a desired pressure; and a control system capable of integrating and controlling the operation of the fuel processor, the pressure swing adsorption unit, and the compressor. In another aspect, the invention includes a method for controlling the operation of a purified hydrogen generator, the method comprising: controlling the operation of a hydrogen generator; controlling the operation of a hydrogen purifier; and synchronizing the controlled operation of the hydrogen generator with the controlled operation of the hydrogen purifier.

Abstract: A method and apparatus for use in regenerating a reactor shift bed catalyst are disclosed. The method comprises monitoring the saturation level of a reactor shift bed catalyst in a reformer; automatically detecting that the reactor shift bed catalyst has entered a saturated state; and automatically regenerating the reactor shift bed catalyst in response to automatically detecting the saturated state. The apparatus may be, in various aspects, a program storage method encoded with instructions that, when executed by a computing device, performs such a method; a computing apparatus programmed to perform such a method, or a control system performing such a method.

Abstract: Herein we disclose an apparatus, comprising: an air feed; a fuel feed; a combustion zone, capable of mixing and combusting air and fuel therein; a temperature sensor positioned within the combustion zone, capable of measuring the temperature of at least one point within the combustion zone; and a control system, comprising: a processor to which the temperature sensor is capable of reporting the measured temperature; and an air flow adjustment apparatus controlled by the processor and capable of adjusting the flow rate of air to the combustion zone in response to the reported temperature. We also disclose a reformer, a power plant, and a fuel cell comprising or associated with the apparatus.

Abstract: In one embodiment, an electrochemical cell system comprises: a fuel cell stack comprising a fuel cell having a fuel cell hydrogen inlet and a fuel cell hydrogen outlet, and a first electrochemical hydrogen compressor in fluid communication with the fuel cell hydrogen outlet, wherein the first electrochemical hydrogen compressor comprises electrodes in electrical communication with an electricity source, and a compressed hydrogen outlet in fluid communication with the fuel cell hydrogen inlet. In one embodiment, the method of operating the electrochemical cell system comprises: introducing hydrogen feed to a fuel cell at a feed rate of greater than stoichiometry, directing excess hydrogen from the fuel cell to a first electrochemical hydrogen compressor, electrochemically compressing the excess hydrogen to compressed hydrogen, and recirculating the compressed hydrogen gas to the fuel cell.

Abstract: An electrochemical cell having a membrane electrode assembly comprises a first active area and an opposingly positioned second active area with a flow field support member disposed adjacent to the membrane electrode assembly. Each of the active areas comprise electrodes, and each of the active areas have length to width ratios such that a temperature differential measured across the shortest distance from a center of each of the active areas to an edge of the active areas is less than about 15° C. The flow field support member includes a flow region that aligns with either the first or second active areas of the membrane electrode assembly. A method of cooling an electrochemical cell comprises radiating heat from fins extending from edges of a flow field member of the electrochemical cell.

Abstract: In a fuel cell system, sufficient water to supply the consumption needs of the system, particularly by the system humidifiers and fuel processor, can be obtained from the exhaust of the fuel cell stack without the use of a condenser, by controlling the operating temperature of the fuel cell stack. The operating temperature can be controlled, for example, using a controller that monitors water level in the process water reservoir and increases or decreases the operating temperature through control of the fuel cell cooling system to maintain the water level within a predetermined range representative of neutral water balance in the system.

Abstract: In a fuel cell system, sufficient water to supply the consumption needs of the system, particularly by the system humidifiers and fuel processor, can be obtained from the exhaust of the fuel cell stack without the use of a condenser, by controlling the operating temperature of the fuel cell stack. The operating temperature can be controlled, for example, using a controller that monitors water level in the process water reservoir and increases or decreases the operating temperature through control of the fuel cell cooling system to maintain the water level within a predetermined range representative of neutral water balance in the system.