Patents by Inventor Bi Le-Khac

Bi Le-Khac has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5641858
    Abstract: A process for making an epoxide polymer comprises polymerizing an epoxide in the presence of an activated polyurethane foam-supported double metal cyanide (DMC) catalyst prepared by (a) exposing a DMC compound to an epoxide and a hydroxyl group-containing starter to activate the DMC compound, (b) isolating the activated DMC compound from the mixture, and .COPYRGT. reacting a polyol, polyisocyanate and water in the presence of a surfactant, a foaming catalyst and the activated DMC compound to produce the activated polyurethane foam-supported DMC catalyst.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: June 24, 1997
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5637673
    Abstract: Improved double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC compound, an organic complexing agent, and from about 5 to about 80 wt. % of a polyether polyol that has tertiary hydroxyl groups. Compared with other DMC catalysts, those of the invention have excellent activity for epoxide polymerization, and they can be used to make polyols having very low unsaturation even at high epoxide polymerization temperatures.
    Type: Grant
    Filed: May 16, 1996
    Date of Patent: June 10, 1997
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5627120
    Abstract: Highly active double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC complex, and organic complexing agent, and from about 5 to about 80 wt. %, based on the amount of catalyst, of a polyether having a number average molecular weight less than about 500. The catalysts polymerize propylene oxide at a rate in excess of about 1 kg PO/g Co/min. at 100 ppm catalyst, based on the weight of finished polyether, at 105.degree. C. The catalysts, which are easy to prepare, give polyether polyols with exceptionally low unsaturation levels.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: May 6, 1997
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5627122
    Abstract: Highly active double metal cyanide (DMC) complex catalysts and methods for making them are disclosed. The catalysts contain less than about 0.2 moles of metal salt per mole of DMC compound in the catalyst, and unlike other highly active DMC catalysts, are substantially crystalline. Polyether polyols made from the catalysts have low unsaturation and are useful for making many types of polyurethane products.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: May 6, 1997
    Assignee: ARCO Chemical Technology, L.P.
    Inventors: Bi Le-Khac, Harry R. Hinney, Paul T. Bowman
  • Patent number: 5596075
    Abstract: Polyurethane foam-supported double metal cyanide (DMC) catalysts are disclosed as useful catalysts for epoxide polymerization. The foam-supported catalysts are easy to prepare, and are more active and show reduced induction periods compared with conventional powdered DMC catalysts. The catalysts of the invention can be recovered from the epoxide polymer products and can be reused to catalyze additional epoxide polymerizations.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: January 21, 1997
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5589431
    Abstract: Improved double metal cyanide catalysts are disclosed. The substantially amorphous catalysts of the invention are more active for polymerizing epoxides than conventional DMC catalysts, which have a substantial crystalline component. Polyol products made with the catalysts are unusually clear, have exceptionally low unsaturations, and contain no detectable amount of low molecular weight polyol impurities. A method of making the improved DMC catalysts, which involves intimately combining the reactants, is also disclosed.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: December 31, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5545601
    Abstract: Improved double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC compound, an organic complexing agent, and from about 5 to about 80 wt. % of a polyether polyol that has tertiary hydroxyl groups. Compared with other DMC catalysts, those of the invention have excellent activity for epoxide polymerization, and they can be used to make polyols having very low unsaturation even at high epoxide polymerization temperatures.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: August 13, 1996
    Assignee: Arco Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5536883
    Abstract: Highly active double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC complex, and organic complexing agent, and from about 5 to about 80 wt. %, based on the amount of catalyst, of a polyether having a number average molecular weight greater than about 500. A method of preparing the catalysts is also disclosed. The catalysts are easy to prepare, have exceptional activity, and are readily removed, if desired, from polymer products. The catalysts are used for polymerizing epoxides.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: July 16, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5527880
    Abstract: Polyurethane foam-supported double metal cyanide (DMC) catalysts are disclosed as useful catalysts for epoxide polymerization. The foam-supported catalysts are easy to prepare, and are more active and show reduced induction periods compared with conventional powdered DMC catalysts. The catalysts of the invention can be recovered from the epoxide polymer products and can be reused to catalyze additional epoxide polymerizations.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: June 18, 1996
    Assignee: ARCO Chemical Technology, I.P.
    Inventor: Bi Le-Khac
  • Patent number: 5525565
    Abstract: Foam-supported double metal cyanide (DMC) catalysts are disclosed as useful catalysts for epoxide polymerization. Polyurethane foam-supported catalysts of the invention are more active and show reduced induction periods compared with conventional powdered DMC catalysts. The catalysts of the invention can be recovered from the epoxide polymer products and can be reused to catalyze additional epoxide polymerizations.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: June 11, 1996
    Assignee: ARCO Chemical Technology, L.P
    Inventor: Bi Le-Khac
  • Patent number: 5523386
    Abstract: Foam-supported double metal cyanide (DMC) catalysts are disclosed as useful catalysts for epoxide polymerization. Polyurethane foam-supported catalysts of the invention are more active and show reduced induction periods compared with conventional powdered DMC catalysts. The catalysts of the invention can be recovered from the epoxide polymer products and can be reused to catalyze additional epoxide polymerizations.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: June 4, 1996
    Assignee: ARCO Chemical Technology L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5498583
    Abstract: Polyurethane foam-supported double metal cyanide (DMC) catalysts are disclosed as useful catalysts for epoxide polymerization. The foam-supported catalysts are easy to prepare, and are more active and show reduced induction periods compared with conventional powdered DMC catalysts. The catalysts of the invention can be recovered from the epoxide polymer products and can be reused to catalyze additional epoxide polymerizations.
    Type: Grant
    Filed: December 1, 1994
    Date of Patent: March 12, 1996
    Assignee: ARCO Chemical Technology, Inc.
    Inventor: Bi Le-Khac
  • Patent number: 5482908
    Abstract: Highly active double metal cyanide (DMC) catalysts are disclosed. The catalysts comprise a DMC complex, and organic complexing agent, and from about 5 to about 80 wt. %, based on the amount of catalyst, of a polyether having a number average molecular weight greater than about 500. A method of preparing the catalysts is also disclosed. The catalysts are easy to prepare, have exceptional activity, and are readily removed, if desired, from polymer products.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: January 9, 1996
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5470813
    Abstract: Improved double metal cyanide catalysts are disclosed. The substantially amorphous catalysts of the invention are more active for polymerizing epoxides than conventional DMC catalysts, which have a substantial crystalline component. Polyol products made with the catalysts are unusually clear, have exceptionally low unsaturations, and contain no detectable amount of low molecular weight polyol impurities. A method of making the improved DMC catalysts, which involves intimately combining the reactants, is also disclosed.
    Type: Grant
    Filed: November 23, 1993
    Date of Patent: November 28, 1995
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5426081
    Abstract: Polyurethane foam-supported double metal cyanide (DMC) compounds are disclosed as useful catalysts for epoxide polymerization. The catalysts are easy to prepare, and are more active and show reduced induction periods compared with conventional powdered DMC catalysts. The catalysts of the invention can be recovered from the epoxide polymer products and can be reused to catalyze additional epoxide polymerizations.
    Type: Grant
    Filed: December 23, 1993
    Date of Patent: June 20, 1995
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5239007
    Abstract: Oil-absorbent compositions are disclosed. The compositions are crosslinked interpolymers of an alkylated styrene and a rubber. The compositions of the invention have high absorption capacities and absorption rates compared with prior-art compositions.
    Type: Grant
    Filed: October 22, 1991
    Date of Patent: August 24, 1993
    Assignee: ARCO Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5151465
    Abstract: Aqueous, uncured but curable, polymer compositions which are stable at room temperature and possess excellent shelf life in uncured form are disclosed. The uncured polymer compositions can be made into fibers using conventional fiber forming processes and cured to produce absorbent fibers capable of absorbing at least 60 times their weight of brine.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: September 29, 1992
    Assignee: Arco Chemical Technology, L.P.
    Inventor: Bi Le-Khac
  • Patent number: 5079306
    Abstract: Aqueous, uncured but curable, polymer compositions which are stable at room temperature and possess excellent shelf life in uncured form are disclosed. The uncured polymer compositions can be made into fibers using conventional fiber forming processes and cured to produce absorbent fibers capable of absorbing at least 60 times their weight of brine.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: January 7, 1992
    Assignee: Arco Chemical Technology, Inc.
    Inventor: Bi Le-Khac
  • Patent number: 5026784
    Abstract: Aqueous, uncured but curable, polymer compositions which are stable at room temperature and possess excellent shelf life in uncured form are disclosed. The uncured polymer compositions can be made into fibers using conventional fiber forming processes and cured to produce absorbent fibers capable of absorbing at least 60 times their weight of brine.
    Type: Grant
    Filed: January 4, 1990
    Date of Patent: June 25, 1991
    Assignee: Arco Chemical Technology, Inc.
    Inventor: Bi Le-Khac
  • Patent number: 4892533
    Abstract: A copolymer of recurring units of at least one .alpha.,.beta.-unsaturated monomer and recurring units of at least one copolymerizable comonomer comprising, in its preferred embodiment from about 20 to about 80 percent pendant carboxylic acid units and from about 80 to about 20 percent pendant carboxylate salt units, is blended with a heterocyclic carbonate to produce a water-absorbing composition upon curing. The composition is particularly suitable for fiber formation.
    Type: Grant
    Filed: August 4, 1988
    Date of Patent: January 9, 1990
    Assignee: Arco Chemical Technology, Inc.
    Inventor: Bi Le-Khac