Abstract: A battery cell includes a cell can including a plurality of walls forming a cell stack receiving zone. Each of the plurality of walls includes an inner surface. A cell stack is arranged in the cell stack receiving zone. The cell stack has an outer surface that is spaced from the inner surface of at least one of the plurality of walls. A cell can insert is arranged between the outer surface of the cell stack and the inner surface of the at least one of the plurality of walls. The cell can insert provides structural support and a thermal flow path between the cell stack and the cell can.

Abstract: A method of manufacturing a battery cell includes providing a battery cell container. The method also includes generating a first battery monocell having a respective anode, cathode, first separator arranged therebetween, and a second separator arranged adjacent to the corresponding anode. The method additionally includes generating a second battery monocell having a respective anode, cathode, first separator arranged therebetween, and a second separator arranged adjacent to the corresponding anode. The method also includes stacking the first battery monocell and the second battery monocell such that the second separator of the first battery monocell is adjacent to the cathode of the second battery monocell. The method further includes arranging the stacked first and second battery monocells in the battery cell container.

Abstract: A battery cell includes a first electrode stack and a second electrode stack, each having at least one pair of anode and cathode elements. The cell also includes a container defining an internal chamber housing the first and second electrode stacks and having external first and second battery terminals. The cell additionally includes a first electrically conductive tab connected to the first battery terminal and to each anode element in the first and second electrode stacks and having a first expandable portion arranged between the first and second electrode stacks. The cell also includes a second electrically conductive tab connected to the second battery terminal and to each cathode element in the first and second electrode stacks and having a second expandable portion arranged between the first and second electrode stacks. The expandable portions absorb alternating expansion and contraction of the subject electrode stacks during cell charging and discharging.

Abstract: A battery cell includes a case and an electrode stack disposed within the case. The battery cell includes an anode including a first conductive tab, a cathode including a second conductive tab, and a separator. The battery cell further includes two electrical connections, each attached to one of the first conductive tab or the second conductive tab and to one of a negative terminal and a positive terminal, respectively. The anode, the cathode, and the separator each include a common perimeter including a first portion matching a shape of an interior surface of the case and a second portion including a cut-out configured to recede from the interior surface. The second portion of the anode, the cathode, and the separator are aligned and create a region between the stack and the interior surface. The tabs and electrical connections are disposed within the region.

Abstract: A prismatic battery cell is provided. The prismatic battery cell includes a hard outer case including an internal volume and an electrode stack or a jelly roll electrode disposed within the internal volume. The prismatic battery cell further includes a foam structure disposed within the internal volume. The foam structure is configured for applying a desirable pressure upon the electrode stack or the jelly roll electrode and for compressing when the electrode stack or the jelly roll electrode expands.

Abstract: A prismatic battery cell assembly has a prismatic container that includes a body portion composed of opposed first and second side portions, opposed first and second end portions, a bottom portion, and a top portion. An electrode stack is composed as anodes interleaved with cathodes. Each of the anodes includes a first current collector having an uncoated anode current collector portion that extends in a first direction away from the electrode stack, and each of the cathodes includes a second current collector having an uncoated cathode current collector portion that extends in a second direction away from the electrode stack. A first terminal is joined to the uncoated anode current collector portions of the first current collectors of the anodes, and a terminal is joined to the uncoated cathode current collector portions of the second current collectors of the cathodes.

Abstract: An apparatus for prismatic battery cell is provided. The apparatus includes a hard outer case defining an internal volume. The apparatus further includes an electrode stack disposed within the internal volume and includes a pair of an anode electrode and a cathode electrode. The electrode stack further includes a plurality of electrode pair layers stacked parallel to each other. The electrode pair layers each include a planar surface. The apparatus further includes a built-in spring configured for pressing against the electrode stack in a direction perpendicular to the planar surface of each of the electrode pair layers.

Abstract: An electrode including an electrode active material including lithium (Li) and a polymer layer coating at least a portion of the electrode active material is provided. The polymer layer includes a polymerization product of a monomer having Formula I: where R1 and R2 are independently an aryl or a branched or unbranched C1-C10 alkyl and X1 and X2 are independently chlorine (Cl), bromine (Br), or iodine (I).

Abstract: Double-layered protective coatings for lithium metal electrodes, as well as methods of formation relating thereto, are provided. The negative electrode assembly includes an electroactive material layer including lithium metal and a protective dual-layered coating. The protective dual-layered coating includes a polymeric layer disposed on a surface of the electroactive material layer and an inorganic layer disposed on an exposed surface of the polymeric layer. The polymeric layer has an elastic modulus of greater than or equal to about 0.01 GPa to less than or equal to about 410 GPa. The inorganic layer has an elastic modulus of greater than or equal to about 10 GPa to less than or equal to about 1000 GPa.

Abstract: A negative electrode for an electrochemical cell of a secondary lithium metal battery may comprise a metal substrate, a lithium metal layer overlying a major surface of the metal substrate, and a protective interfacial layer formed on a major surface of the lithium metal layer over the metal substrate. The protective interfacial layer may comprise a stack of monomolecular layers including at least one aryl siloxane monomolecular layer overlying the major surface of the lithium metal layer. The protective interfacial layer may be formed on the major surface of the lithium metal layer by applying a mixture of monoaryl silanes to the major surface of the lithium metal layer.

Abstract: An electrode including an electrode active material including lithium (Li) and a polymer layer coating at least a portion of the electrode active material is provided. The polymer layer includes a polymerization product of a monomer having Formula I: where R1 and R2 are independently an aryl or a branched or unbranched C1-C10 alkyl and X1 and X2 are independently chlorine (Cl), bromine (Br), or iodine (I).

Abstract: Double-layered protective coatings for lithium metal electrodes, as well as methods of formation relating thereto, are provided. The negative electrode assembly includes an electroactive material layer including lithium metal and a protective dual-layered coating. The protective dual-layered coating includes a polymeric layer disposed on a surface of the electroactive material layer and an inorganic layer disposed on an exposed surface of the polymeric layer. The polymeric layer has an elastic modulus of greater than or equal to about 0.01 GPa to less than or equal to about 410 GPa. The inorganic layer has an elastic modulus of greater than or equal to about 10 GPa to less than or equal to about 1000 GPa.

Abstract: A negative electrode for an electrochemical cell of a secondary lithium metal battery may comprise a metal substrate, a lithium metal layer overlying a major surface of the metal substrate, and a protective interfacial layer formed on a major surface of the lithium metal layer over the metal substrate. The protective interfacial layer may comprise a stack of monomolecular layers including at least one aryl siloxane monomolecular layer overlying the major surface of the lithium metal layer. The protective interfacial layer may be formed on the major surface of the lithium metal layer by applying a mixture of monoaryl silanes to the major surface of the lithium metal layer.

Abstract: A mechanical compression method can be used to tune semiconductor nanoparticle lattice structure and synthesize new semiconductor nanostructures including nanorods, nanowires, nanosheets, and other three-dimensional interconnected structures. II-VI or IV-VI compound semiconductor nanoparticle assemblies can be used as starting materials, including CdSe, CdTe, ZnSe, ZnS, PbSe, and PbS.

Abstract: The present invention provides a pressure-induced phase transformation process to engineer metal nanoparticle architectures and to fabricate new nanostructured materials. The reversible changes of the nanoparticle unit cell dimension under pressure allow precise control over interparticle separation in 2D or 3D nanoparticle assemblies, offering unique robustness for interrogation of both quantum and classic coupling interactions. Irreversible changes above a threshold pressure of about 8 GPa enables new nanostructures, such as nanorods, nanowires, or nanosheets.