Abstract: A supported three-center catalyst, a preparation method and the use are provided. The catalyst comprises a porous inorganic carrier, an organic chromium active component, an inorganic chromium active component and an inorganic vanadium active component, and may further comprise a catalyst modifying component. A method involves, by means of one or more steps of dipping and drying or dipping, drying and high-temperature roasting procedures, respectively converting an organic chromium source, a chromium source, a vanadium source and a Q component into an organic chromium active component precursor, an inorganic chromium active component precursor, an inorganic vanadium active component precursor and a catalyst modifying component that are supported on the surface of the porous inorganic carrier, and then activating same with an organometallic cocatalyst or a polymerization monomer, so as to obtain the supported three-center catalyst.

Abstract: A supported three-center catalyst, a preparation method and the use are provided. The catalyst comprises a porous inorganic carrier, an organic chromium active component, an inorganic chromium active component and an inorganic vanadium active component, and may further comprise a catalyst modifying component. A method involves, by means of one or more steps of dipping and drying or dipping, drying and high-temperature roasting procedures, respectively converting an organic chromium source, a chromium source, a vanadium source and a Q component into an organic chromium active component precursor, an inorganic chromium active component precursor, an inorganic vanadium active component precursor and a catalyst modifying component that are supported on the surface of the porous inorganic carrier, and then activating same with an organometallic cocatalyst or a polymerization monomer, so as to obtain the supported three-center catalyst.

Abstract: The present invention relates to a supported polymetal olefin polymerization catalyst, comprising a porous support, a magnesium-containing support component, a transition metal titanium component supported on the porous support, and further comprising at least one non-magnesium metal component supported on the porous support. Further provided is a preparation method and a use of the supported polymetal olefin polymerization catalyst. An efficient composite support supported polymetal Ziegler-Natta catalyst is provided in the present invention, wherein a porous support, a soluble magnesium compound, and a soluble non-magnesium metal compound are used as raw materials. The supporting of titanium is achieved while a composite support containing magnesium and non-magnesium metal components is formed in situ in the surface of the porous support. The present invention has the advantage of a simple preparation method, a low cost, a controllability of morphology, properties of the catalyst, etc.

Abstract: The present invention relates to a supported polymetal olefin polymerization catalyst, comprising a porous support, a magnesium-containing support component, a transition metal titanium component supported on the porous support, and further comprising at least one non-magnesium metal component supported on the porous support. Further provided is a preparation method and a use of the supported polymetal olefin polymerization catalyst. An efficient composite support supported polymetal Ziegler-Natta catalyst is provided in the present invention, wherein a porous support, a soluble magnesium compound, and a soluble non-magnesium metal compound are used as raw materials. The supporting of titanium is achieved while a composite support containing magnesium and non-magnesium metal components is formed in situ in the surface of the porous support. The present invention has the advantage of a simple preparation method, a low cost, a controllability of morphology, properties of the catalyst, etc.

Abstract: The present invention relates to a supported hybrid vanadium-chromium-based catalyst, characterized in the catalyst is supported on a porous inorganic carrier and a V active site and a inorganic Cr active site are present on the porous inorganic carrier at the same time. The present invention further relates to a process for producing a supported hybrid vanadium-chromium-based catalyst. The invention also provides the preparation method of the catalyst, titanium or fluorine compounds, vanadium salt and chromium salt according to the proportion, different methods of sequence and load on the inorganic carrier, after high temperature roasting, still can further add organic metal catalyst promoter prereduction activation treatment on it. The catalyst of the present invention can be used for producing ethylene homopolymers and ethylene/?-olefin copolymers.

Abstract: The present invention relates to a carriered hybrid vanadium-chromium-based catalyst, characterized in the catalyst is carriered on a porous inorganic carrier and a V active site and an organic Cr active site are present on the porous inorganic carrier at the same time. The present invention further relates to a process for producing a carriered hybrid vanadium-chromium-based catalyst. The catalyst of the present invention can be used for producing ethylene homopolymers and ethylene/?-olefin copolymers. The hybrid vanadium-chromium-based catalyst can have high activity and produce polyethylene polymers having the properties of broad molecular weight distribution (Part of the products are bimodal distribution) and excellent ?-olefin copolymerization characteristic.

Abstract: A supported catalyst for olefin polymerization, a preparation method and use thereof. The catalyst comprises a porous carrier A, a magnesium-containing carrier B, and a supported active component containing a transitional metal of titanium. The catalyst is a highly efficient Ziegler-Natta titanium-based catalyst having a composite support formed by a magnesium compound and a silicon compound, wherein the raw material for the magnesium compound may be any soluble magnesium salt. The supported catalyst may be used for preparing olefin homopolymers or olefin copolymers. According to the present invention, the molecular weight, molecular weight distribution of the olefin homopolymer or olefin copolymer as well as the contents and distribution of the comonomers may be adjusted conveniently by means of changing the factors such as types and amounts of organometallic co-catalyst and molecular weight regulator.

Abstract: The present invention relates to a carriered hybrid vanadium-chromium-based catalyst, characterized in the catalyst is carriered on a porous inorganic carrier and a V active site and an organic Cr active site are present on the porous inorganic carrier at the same time. The present invention further relates to a process for producing a carriered hybrid vanadium-chromium-based catalyst. The catalyst of the present invention can be used for producing ethylene homopolymers and ethylene/?-olefin copolymers. The hybrid vanadium-chromium-based catalyst can have high activity and produce polyethylene polymers having the properties of broad molecular weight distribution (Part of the products are bimodal distribution) and excellent ?-olefin copolymerization characteristic.

Abstract: The present invention relates to a supported hybrid vanadium-chromium-based catalyst, characterized in the catalyst is supported on a porous inorganic carrier and a V active site and a inorganic Cr active site are present on the porous inorganic carrier at the same time. The present invention further relates to a process for producing a supported hybrid vanadium-chromium-based catalyst. The invention also provides the preparation method of the catalyst, titanium or fluorine to compounds, vanadium salt and chromium salt according to the proportion, different methods of sequence and load on the inorganic carrier, after high temperature roasting, still can further add organic metal catalyst promoter prereduction activation treatment on it. The catalyst of the present invention can be used for producing ethylene homopolymers and ethylene/?-olefin copolymers.

Abstract: Disclosed are a supported hybrid chromium-based catalyst comprising a porous inorganic support, at least one inorganic oxide Cr active site (A), and at least one organic Cr active site (B), wherein the at least one inorganic oxide Cr active site (A) and the at least one organic Cr active site (B) are both supported on the porous inorganic support, processes for producing the supported hybrid chromium-based catalyst and processes for producing ethylene homopolymers and/or ethylene copolymers using the catalysts of the present disclosure.