Abstract: A dynamic precious metal assay which includes the steps of introducing a controlled amount of liquid electrolyte onto a sample of precious metal alloys, placing an inert electrode in contact with the sample in the presence of the electrolyte to create a wet junction, driving a first pulse of electric current through the electrolyte in the wet junction to cause an oxidation/reduction reaction of the alloying materials present in the alloyed sample to form an electrolytic-based paste, terminating the electric current and allowing the current in the paste to decay to an asymptotic level, driving a second pulse of electric current through the electrolytic paste in the junction at an amplitude above the asymptotic level, driving a third pulse of electric current, at a higher amplitude than the second pulse, through the electrolytic paste in the junction, instantaneously measuring the electrolytic conductance of the electrolytic paste, comparing the conductance with an empirical table of electrolytic paste conducta

Abstract: The invention describes a method for determining the assay of gold alloy. It utilizes a dynamic electrochemical process. The specimen gold is wetted by a described electrolyte, and a small current anodizes the surface of the specimen for a metered period of time. A potential sensing device is then applied to the charged surface, and a potential decay is observed. The potential decay information is compared with empirical data and by interpolating said potential decay with the empirical data a determination of the karat quality of the gold alloy may be determined. This same method may be used for other precious metals, employing different electrolytes, empirical standards, and potentiometers.