Abstract: A current collector including: a polymer film including a first major surface, an opposite second major surface, and a plurality of openings extending through a thickness of the polymer film; a first layer on the first major surface of the polymer film; a second layer on the second major surface of the polymer film; and a third layer on an inner surface of an opening of the plurality of openings, wherein the third layer contacts the first layer and the second layer, and wherein the first layer, the second layer, and the third layer each independently has an electrical conductivity of greater than 10 Siemens per meter.

Abstract: A current collector including: a polymer film including a first major surface, an opposite second major surface, and a plurality of openings extending through a thickness of the polymer film; a first layer on the first major surface of the polymer film; a second layer on the second major surface of the polymer film; and a third layer on an inner surface of an opening of the plurality of openings, wherein the third layer contacts the first layer and the second layer, and wherein the first layer, the second layer, and the third layer each independently has an electrical conductivity of greater than 10 Siemens per meter.

Abstract: Thermally stable electrolytes for Li-ion batteries obtained with the use of Lewis base additives to the electrolytes are disclosed. The Lewis bases stabilize electrolytes composed of solutions of LiPF6 in organic carbonates against decomposition at temperatures as high as 85° C. Additives suitable for stabilizing LiPF6-containing electrolytes include amines, for example, triethylenediamine (TEDA) and 2,2′-bipyridine (BIPY), phosphines, for example, triphenylphosphine (TPP) and tributylphosphine (TBP), and nitrogen-phosphorus bonded compounds such as hexamethoxycyclotriphosphazene ([N═P(OCH3)2]3) (HMOPA), hexamethyl phosphoramide (HMPA), and N-phenyl-P,P,P-trimethylphosphorimidate (PhTMI). These additives are also capable of stabilizing electrolytes in solvents other than carbonates including ethers, esters and sulfones.