Abstract: Novel polymers are depolymerizable by metathesis of a cleavable unit. As an example, a series of linear and crosslinked polyurethanes were prepared that can be selectively depolymerized under mild conditions. Two unique polyols were synthesized bearing unsaturated units in a configuration designed to favor ring-closing metathesis to five- and six-membered cycloalkenes. These polyols were co-polymerized with toluene diisocyanate to generate linear polyurethanes and trifunctional hexamethylene- and diphenylmethane-based isocyanates to generate crosslinked polyurethanes. The polyol design is such that the ring-closing metathesis reaction cleaves the backbone of the polymer chain. Upon exposure to dilute solutions of Grubbs' catalyst under ambient conditions, the polyurethanes were rapidly depolymerized to low molecular weight, soluble products bearing vinyl and cycloalkene functionalities. These functionalities enabled further re-polymerization by traditional strategies for polymerization of double bonds.

Abstract: The invention is directed to latent metathesis-active resin compositions and additive manufacturing approaches. The latent metathesis-active compositions comprise at least one latent metathesis catalyst, at least one curable metathesis-active monomer, and optional fillers, photosensitizers, and/or a secondary monomer resin system for dual-cure. A method comprises extruding a latent metathesis-active resin from a dispensing apparatus and spatially triggering a ring-opening metathesis polymerization by directed irradiation with light or directed application of a thermal stimuli for direct-ink write printing of objects. Another method uses a latent metathesis-active resin for vat photopolymerization and stereolithographic printing of objects.

Abstract: Polymerization-induced phase separation enables fine control over thermoset network morphologies, yielding heterogeneous structures with domain sizes tunable over 1-100 nm. However, the controlled chain-growth polymerization techniques exclusively employed to regulate morphology at these length scales are unsuitable for most thermoset materials typically formed through step-growth mechanisms. By employing binary mixtures in place of the classic constituents of phase-separating thermosets—resin, curing agent, and secondary polymer—facile tunability over morphology can be achieved through a single compositional parameter. Indeed, this method yields morphologies spanning nano-scale to macro-scale, controlled by the relative reactivities and thermodynamic compatibility of the network components. Due to the connection between chain dynamics and microstructure in these materials, the tunable morphology enables exquisite control over glass transition and other physical and mechanical properties.

Abstract: The invention is directed to the selective dual wavelength olefin metathesis polymerization for additive manufacturing. Dual-wavelength stereolithographic printing uses ring-opening metathesis polymerization of the metathesis-active polymers. As an example, a resin formulation based on dicyclopentadiene was produced using a photolatent olefin metathesis catalyst, various photosensitizers and photobase generators to achieve efficient initiation by light at one wavelength (e.g., blue) and fast catalyst decomposition and polymerization deactivation by light at a second wavelength (e.g., ultraviolet). This process enables 2-dimensional stereolithographic printing, either using photomasks or with patterned, collimated light. Importantly, the same process was readily adapted for 3-dimensional continuous additive manufacturing, with printing rates of up to 36 mm h?1 for patterned light and up to 180 mm h?1 using un-patterned, high intensity light.

Abstract: The invention is directed to latent metathesis-active resin compositions and additive manufacturing approaches. The latent metathesis-active compositions comprise at least one latent metathesis catalyst, at least one curable metathesis-active monomer, and optional fillers, photosensitizers, and/or a secondary monomer resin system for dual-cure. A method comprises extruding a latent metathesis-active resin from a dispensing apparatus and spatially triggering a ring-opening metathesis polymerization by directed irradiation with light or directed application of a thermal stimuli for direct-ink write printing of objects. Another method uses a latent metathesis-active resin for vat photopolymerization and stereolithographic printing of objects.

Abstract: Novel polymers are depolymerizable by metathesis of a cleavable unit. As an example, a series of linear and crosslinked polyurethanes were prepared that can be selectively depolymerized under mild conditions. Two unique polyols were synthesized bearing unsaturated units in a configuration designed to favor ring-closing metathesis to five- and six-membered cycloalkenes. These polyols were co-polymerized with toluene diisocyanate to generate linear polyurethanes and trifunctional hexamethylene- and diphenylmethane-based isocyanates to generate crosslinked polyurethanes. The polyol design is such that the ring-closing metathesis reaction cleaves the backbone of the polymer chain. Upon exposure to dilute solutions of Grubbs' catalyst under ambient conditions, the polyurethanes were rapidly depolymerized to low molecular weight, soluble products bearing vinyl and cycloalkene functionalities. These functionalities enabled further re-polymerization by traditional strategies for polymerization of double bonds.

Abstract: A method for encoding an audio/video (AV) program for muting on a sink device includes generating or recovering at least one digital transport stream having the AV program, augmenting the at least one digital transport stream with control information, the control information being configured to invoke a muting of at least one component of the AV program by the sink device, and transmitting the augmented digital transport stream over a digital link coupled to the sink device.

Abstract: The present invention provides methods and apparatus for passing an on-screen display (OSD) from a source device, such as a television terminal, to a sink device, such as a high definition television (HDTV), over a serial interface, such as an IEEE-1394 interface. The source device includes a tuner adapted for receiving an active isochronous MPEG data stream and graphic data for an OSD. A serial interface at the source device enables communication with a sink device. A processor at the source device detects an action requiring an OSD at the sink device. The source device also includes an MPEG encoder adapted for encoding the graphic data as an isochronous MPEG data stream carrying the OSD. The isochronous MPEG data stream carrying the OSD may then be passed to the sink device via the serial interface.

Abstract: Simultaneous display of multiple audio/video (AV) programs transmitted over a digital link is described. At a source device, at least one non-composited digital transport stream is generated from the plurality of AV programs. The at least one non-composited digital transport stream is augmented with control information. The control information is operative to invoke simultaneous display of the plurality of AV programs on a display device. The at least one non-composited digital transport stream is then transmitted as augmented over the digital link. At a sink device, at least one non-composited digital transport stream having the plurality of AV programs is received over the digital link. Control information is extracted from the at least one non-composited digital transport stream. The plurality of AV programs are identified within said non-composited digital transport stream in response to the control information. The identified AV programs are then simultaneously displayed on the display device.

Abstract: A method of removing regions of an anti-reflective coating includes etching the anti-reflective coating with a fluorinated hydrocarbon-based plasma etch and etching the anti-reflective coating with an oxygen-based plasma etch. In some implementations, the oxygen-based plasma etch is performed following the fluorinated hydrocarbon-based etch. The technique can be used to remove regions of an anti-reflective coating so that a more uniform and controlled etch of an underlayer can subsequently be performed. The disclosed technique is particularly useful for etching organic or organometallic anti-reflective layers, but can be used to etch other anti-reflective layers as well. In addition, the techniques are particularly advantageous for etching anti-reflective coatings disposed on certain oxide and nitride layers, although the underlayer can be formed of other materials as well.

Abstract: A system and method for compressing related data sets of a sequence are disclosed. The process compares domain blocks from a current frame buffer to range blocks in a previous frame buffer or vector quantization ("VQ") tables to generate affine map codes. The affine map codes are preferably encoded by an entropy encoder before being transmitted to a remote site for decompression. The cost for the encoded affine map codes are computed and used to determine whether affine map codes for representing smaller blocks should be included in the affine map codes which represent the domain blocks into which the original frame was segmented. The methods are preferably implemented on a commercially available discrete cosine transform ("DCT") processor having a process controller and a data comparator. The results of the affine map code generating process on the DCT processor achieves a more consistent bit rate and image quality than methods operating the DCT processor to generate DCT codes.