Patents by Inventor Brad M. Rosen

Brad M. Rosen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10696850
    Abstract: The present invention comprises a crosslinkable polymer compound comprising a fluorinated Unit A, an optional hydrophilic Unit B, an optional acidic or neutralized acid Unit C, a crosslinkable pendant olefin group-containing Unit D, and an optional hydrophobic alkyl Unit E. Such polymeric compounds are useful as coatings additives such that, when the coating is applied to a substrate, the additive compound is allowed to first migrate to the surface and subsequently crosslink to form a durable oil-, dirt-, and water-repellent surface.
    Type: Grant
    Filed: April 28, 2016
    Date of Patent: June 30, 2020
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Anilkumar Raghavanpillai, James J. Hughes, Vincent Franco, John Russell Crompton, Jr., Brad M Rosen, Hau-Nan Lee, Michael Henry Ober, Dan Qing Wu
  • Patent number: 10442952
    Abstract: The present invention comprises a composition and method of use for providing durable dirt pickup resistance to architectural coatings. Such compositions comprise a coating base and a post-modified crosslinkable fluoropolymer additive, such that the coatings additive is allowed to migrate to the coating surface and further cure once applied to a substrate. The compositions of the present invention provide durability to coating compositions, while also providing surface effects such as increased water and oil contact angles, enhanced dirt pickup resistance, and enhanced cleanability to the coating films.
    Type: Grant
    Filed: April 27, 2016
    Date of Patent: October 15, 2019
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Anilkumar Raghavanpillai, Brad M. Rosen, James J. Hughes, Vincent Franco, John Russell Crompton, Jr., Kai Qi, Michael Henry Ober
  • Patent number: 10011727
    Abstract: This invention provides methods and technology related to increased hiding power of a coating through mediating the interaction of the pigment with other system components including but not limited to other pigment particles, latex paint particles, latex binding particles, and organic or inorganic hollow particles. Organization and spacing are tailored via pH sensitive functionalities hosted on ligands or polymeric spacers that are located at/within the surface of one of the components.
    Type: Grant
    Filed: February 25, 2015
    Date of Patent: July 3, 2018
    Assignee: THE CHEMOURS COMPANY FC, LLC
    Inventors: Andrew Jay Duncan, Jelena Lasio, Hau-Nan Lee, Carl Andrew Menning, Brad M Rosen
  • Publication number: 20180118956
    Abstract: The present invention comprises a crosslinkable polymer compound comprising a fluorinated Unit A, an optional hydrophilic Unit B, an optional acidic or neutralized acid Unit C, a crosslinkable pendant olefin group-containing Unit D, and an optional hydrophobic alkyl Unit E. Such polymeric compounds are useful as coatings additives such that, when the coating is applied to a substrate, the additive compound is allowed to first migrate to the surface and subsequently crosslink to form a durable oil-, dirt-, and water-repellent surface.
    Type: Application
    Filed: April 28, 2016
    Publication date: May 3, 2018
    Inventors: ANILKUMAR RAGHAVANPILLAI, JAMES J. HUGHES, VINCENT FRANCO, JOHN RUSSELL CROMPTON, JR., BRAD M. ROSEN, HAU-NAN LEE, MICHAEL HENRY OBER, DAN QING WU
  • Publication number: 20180112097
    Abstract: The present invention comprises a composition and method of use for providing durable dirt pickup resistance to architectural coatings. Such compositions comprise a coating base and a post-modified crosslinkable fluoropolymer additive, such that the coatings additive is allowed to migrate to the coating surface and further cure once applied to a substrate. The compositions of the present invention provide durability to coating compositions, while also providing surface effects such as increased water and oil contact angles, enhanced dirt pickup resistance, and enhanced cleanability to the coating films.
    Type: Application
    Filed: April 27, 2016
    Publication date: April 26, 2018
    Inventors: ANILKUMAR RAGHAVANPILLAI, BRAD M. ROSEN, JAMES J. HUGHES, VINCENT FRANCO, JOHN RUSSELL CROMPTON JR, KAI QI, MICHAEL HENRY OBER
  • Patent number: 9777170
    Abstract: The present invention comprises a composition and method of use for providing cleanability to paint comprising an aqueous emulsion of Formula (I) wherein the composition of Formula (I) is a random copolymer; wherein said composition of formula (I) further comprises residue from a hydrophilic chain transfer agent. The compositions of the present invention provide durability to coating compositions, while also providing surface effects such as increased water and oil contact angles, enhanced dirt pickup resistance, and enhanced cleanability to the coating films. For these reasons, the composition of the present invention is particularly suitable for use as additives to exterior coatings and paints.
    Type: Grant
    Filed: February 23, 2015
    Date of Patent: October 3, 2017
    Assignee: THE CHEMOURS COMPANY TT, LLC
    Inventors: Anilkumar Raghavanpillai, Timothy Pellenbarg, Hau-Nan Lee, James J. Hughes, Kai Qi, John Russell Crompton, Jr., Brad M Rosen
  • Publication number: 20170066676
    Abstract: The disclosure provides a process for making hollow inorganic particles comprising: providing a recyclable template particle in an aqueous dispersion, wherein the recyclable template particle is prepared from an organic monomer; coating the recyclable template particle with a solvent based silica precursor; maintaining the pH at about 7 to about 10 to form core/shell particles comprising a silica treatment on the recyclable template particle; removing the core/shell particles; and removing the recyclable template particle from the core/shell particles to form a hollow silica particle.
    Type: Application
    Filed: February 25, 2015
    Publication date: March 9, 2017
    Inventors: JELENA LASIO, BRAD M ROSEN, DEVIN T. WHIPPLE, FRANCIS J WOERNER
  • Publication number: 20170066653
    Abstract: The disclosure provides a process for making hollow inorganic particles comprising: providing a recyclable template particle in an aqueous dispersion, wherein the recyclable template particle is prepared from an organic monomer; coating the recyclable template particle with a water-based silica precursor; maintaining the pH at about 2 to about 10 to form core/shell particles comprising a silica treatment on the recyclable template particle; removing the core/shell particles; and removing the recyclable template particle from the core/shell particles to form a hollow silica particle.
    Type: Application
    Filed: February 27, 2015
    Publication date: March 9, 2017
    Applicant: THE CHEMOURS COMPANY TT, LLC
    Inventors: JELENA LASIO, HAU-NAN LEE, BRAD M ROSEN, DEVIN T WHIPPLE, FRANCIS J. WOERNER
  • Publication number: 20150240090
    Abstract: The present invention comprises a composition and method of use for providing cleanability to paint comprising an aqueous emulsion of Formula (I) wherein the composition of Formula (I) is a random copolymer; wherein said composition of formula (I) further comprises residue from a hydrophilic chain transfer agent. The compositions of the present invention provide durability to coating compositions, while also providing surface effects such as increased water and oil contact angles, enhanced dirt pickup resistance, and enhanced cleanability to the coating films. For these reasons, the composition of the present invention is particularly suitable for use as additives to exterior coatings and paints.
    Type: Application
    Filed: February 23, 2015
    Publication date: August 27, 2015
    Inventors: ANILKUMAR RAGHAVANPILLAI, Timothy Pellenbarg, Hau-Nan Lee, James J. Hughes, Kai Qi, John Russell Crompton, JR., Brad M. Rosen
  • Patent number: 8808868
    Abstract: A stain resistant, oil and water repellent copolymer comprising a copolymer prepared from fluorinated (meth)acrylate and amine salts of (meth)acrylic acid, and a method of providing stain resistance, oil and water repellency to substrates and a treated substrate.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: August 19, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Siddhartha Shenoy, Joel M. Pollino, Anilkumar Raghavanpillai, Brad M. Rosen, John Russell Crompton, Jr.
  • Patent number: 8809209
    Abstract: A stain resistant, oil and water repellent composition comprising a copolymer prepared from fluorinated methacrylate, carbonate methacrylate, and methacrylic acid or salt thereof, a method of providing stain resistance, oil and water repellency to substrates, and a treated substrate.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: August 19, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Joel M. Pollino, Anilkumar Raghavanpillai, Brad M. Rosen, Siddhartha Shenoy, Libby Xiaowei Hu
  • Patent number: 8642177
    Abstract: A method to provide acid etch resistance to contacting a calcareous substrate with a copolymer prepared from fluorinated methacrylate, short chain branched (meth)acrylate, and (meth)acrylic acid salt and a treated substrate.
    Type: Grant
    Filed: March 20, 2012
    Date of Patent: February 4, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Brad M Rosen, Siddhartha R. Shenoy, Anilkumar Raghavanpillai, Ernest Bryon Wysong, Joel M Pollino, James J Hughes, John Russell Crompton, Jr.
  • Patent number: 8563672
    Abstract: A process for producing copolymers of (meth)acrylates:(meth)acrylic acid amine complexes useful for hard surfaces having increased performance for stain resistance, oil and water repellency properties.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: October 22, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Siddhartha Shenoy, Joel M. Pollino, Anilkumar Raghavanpillai, Brad M. Rosen, Ernest Byron Wysong
  • Publication number: 20130251908
    Abstract: A method to provide acid etch resistance to contacting a calcareous substrate with a copolymer prepared from fluorinated methacrylate, short chain branched (meth)acrylate, and (meth)acrylic acid salt and a treated substrate.
    Type: Application
    Filed: March 20, 2012
    Publication date: September 26, 2013
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: Brad M. Rosen, Siddhartha R. Shenoy, Anilkumar Raghavanpillai, Ernest Bryon Wysong, Joel M. Pollino, James J. Hughes, John Russell Crompton, JR.
  • Publication number: 20120156417
    Abstract: A stain resistant, oil and water repellent composition comprising a copolymer prepared from fluorinated methacrylate, carbonate methacrylate, and methacrylic acid or salt thereof, a method of providing stain resistance, oil and water repellency to substrates, and a treated substrate.
    Type: Application
    Filed: November 21, 2011
    Publication date: June 21, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Joel M. Pollino, Anilkumar Raghavanpillai, Brad M. Rosen, Siddhartha Shenoy, Libby Xiaowei Hu
  • Publication number: 20120156515
    Abstract: A stain resistant, oil and water repellent copolymer comprising a copolymer prepared from fluorinated (meth)acrylate and amine salts of (meth)acrylic acid, and a method of providing stain resistance, oil and water repellency to substrates and a treated substrate.
    Type: Application
    Filed: November 21, 2011
    Publication date: June 21, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Siddhartha Shenoy, Joel M. Pollino, Anilkumar Raghavanpillai, Brad M. Rosen, John Russell Crompton, JR.
  • Publication number: 20120157640
    Abstract: A process for producing copolymers of (meth)acrylates:(meth)acrylic acid amine complexes useful for hard surfaces having increased performance for stain resistance, oil and water repellency properties.
    Type: Application
    Filed: November 21, 2011
    Publication date: June 21, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Siddhartha Shenoy, Joel M. Pollino, Anilkumar Raghavanpillai, Brad M. Rosen, Ernest Byron Wysong