Abstract: A method for a redox flow battery may include, interrupting cycling of the redox flow battery, including charging the redox flow battery to a threshold charge condition, draining positive and negative electrolyte from the redox flow battery, circulating a wash solution through the redox flow battery, and returning the positive and negative electrolyte to the redox flow battery, and resuming cycling of the redox flow battery. In this way, contamination of the redox flow battery system can be reduced, thereby prolonging the life and increasing performance of the redox flow battery system.

Abstract: Systems and methods are provided for electrochemical and/or chemical pretreatment of bipolar plates, for example, for plating electrodes in redox flow batteries. In one example, a method may include pretreating a bipolar plate for the redox flow battery by disrupting a surface of the bipolar plate. In some examples, pretreating the bipolar plate may include positioning the bipolar plate within the redox flow battery, and thereafter charging the redox flow battery at multiple discrete plating current densities for each of one or more initial charging cycles to electrochemically etch the surface. In additional or alternative examples, pretreating the bipolar plate may include soaking the bipolar plate in solution to chemically treat the surface. In this way, the bipolar plate may be pretreated via electrochemical etching and/or chemical treatment so as to reduce electrochemical performance losses and dendrite formation in the redox flow battery.

Abstract: Methods and systems are provided for iron preformation in a redox flow battery. In one example, a method may include, in a first condition, discharging and then charging the redox flow battery, and in a second condition, charging the redox flow battery including preforming iron metal at a negative electrode of the redox flow battery, and thereafter entering an idle mode of the redox flow battery including adjusting one or more electrolyte conditions. In some examples, each of preforming the iron metal and adjusting the one or more electrolyte conditions may increase a battery charge capacity to greater than a threshold battery charge capacity.

Abstract: Systems and methods are provided for a redox flow battery. In one example, a method of operating a redox flow battery includes charging the redox flow battery, including supplying a pulsed power signal to the redox flow battery in response to the redox flow battery state of charge (SOC) decreasing below a lower threshold redox flow battery SOC, wherein supplying the pulsed power signal includes supplying a pulse-width-modulated (PWM) charging voltage signal to the redox flow battery, the PWM charging voltage signal fluctuating between an upper threshold charging voltage and an open circuit voltage (OCV).

Abstract: Systems and methods are provided for electrochemical and/or chemical pretreatment of bipolar plates, for example, for plating electrodes in redox flow batteries. In one example, a method may include pretreating a bipolar plate for the redox flow battery by disrupting a surface of the bipolar plate. In some examples, pretreating the bipolar plate may include positioning the bipolar plate within the redox flow battery, and thereafter charging the redox flow battery at multiple discrete plating current densities for each of one or more initial charging cycles to electrochemically etch the surface. In additional or alternative examples, pretreating the bipolar plate may include soaking the bipolar plate in solution to chemically treat the surface. In this way, the bipolar plate may be pretreated via electrochemical etching and/or chemical treatment so as to reduce electrochemical performance losses and dendrite formation in the redox flow battery.

Abstract: Methods and systems are provided for iron preformation in a redox flow battery. In one example, a method may include, in a first condition, discharging and then charging the redox flow battery, and in a second condition, charging the redox flow battery including preforming iron metal at a negative electrode of the redox flow battery, and thereafter entering an idle mode of the redox flow battery including adjusting one or more electrolyte conditions. In some examples, each of preforming the iron metal and adjusting the one or more electrolyte conditions may increase a battery charge capacity to greater than a threshold battery charge capacity.

Abstract: Systems and methods are provided for electrochemical and/or chemical pretreatment of bipolar plates, for example, for plating electrodes in redox flow batteries. In one example, a method may include pretreating a bipolar plate for the redox flow battery by disrupting a surface of the bipolar plate. In some examples, pretreating the bipolar plate may include positioning the bipolar plate within the redox flow battery, and thereafter charging the redox flow battery at multiple discrete plating current densities for each of one or more initial charging cycles to electrochemically etch the surface. In additional or alternative examples, pretreating the bipolar plate may include soaking the bipolar plate in solution to chemically treat the surface. In this way, the bipolar plate may be pretreated via electrochemical etching and/or chemical treatment so as to reduce electrochemical performance losses and dendrite formation in the redox flow battery.

Abstract: Methods and systems are provided for iron preformation in a redox flow battery. In one example, a method may include, in a first condition, discharging and then charging the redox flow battery, and in a second condition, charging the redox flow battery including preforming iron metal at a negative electrode of the redox flow battery, and thereafter entering an idle mode of the redox flow battery including adjusting one or more electrolyte conditions. In some examples, each of preforming the iron metal and adjusting the one or more electrolyte conditions may increase a battery charge capacity to greater than a threshold battery charge capacity.

Abstract: A method for a redox flow battery may include, interrupting cycling of the redox flow battery, including charging the redox flow battery to a threshold charge condition, draining positive and negative electrolyte from the redox flow battery, circulating a wash solution through the redox flow battery, and returning the positive and negative electrolyte to the redox flow battery, and resuming cycling of the redox flow battery. In this way, contamination of the redox flow battery system can be reduced, thereby prolonging the life and increasing performance of the redox flow battery system.