Abstract: Passivated Li7La3Zr2O12 (LLZO) particles, tape casting powders and slip compositions including the particles, methods of forming the particles, methods of tape casting using the particles, green tapes including the particles, cast LLZO films formed from the particles, and lithium batteries including the cast LLZO film. A passivated LLZO particle includes an LLZO core, wherein the LLZO is optionally doped with one or more elements. The passivated LLZO particle also includes a shell including H-LLZO, H3O+-LLZO, and/or Li2CO3.

Abstract: A ceramic article and method of manufacturing. The ceramic article comprises a porous ceramic material having a microstructure comprising an interconnected network of porous spheroidal ceramic beads. The microstructure has a total open porosity defined as the sum of an open intrabead porosity of the beads and an interbead porosity defined by interstices between the beads in the interconnected network. The microstructure has a bimodal pore size distribution having an intrabead peak corresponding to the open intrabead porosity and an interbead peak corresponding to the interbead porosity. An intrabead median pore size of the intrabead porosity is less than an interbead median pore size of the interbead porosity.