Abstract: Disclosed is a method of preparing treated metal oxide nanoparticles from sols prepared from metal alkoxides and organosilanes. The treated nanoparticles are useful high refractive index additives in the manufacture of optical articles.

Abstract: Blends of oligomeric urethane multi(meth)acrylate; optionally at least one other monomer selected from the group consisting of acrylic monomers, styrenic monomers and ethylenically unsaturated nitrogen heterocycles, preferably a polyol multi(meth)acrylate; and nanoparticles of an ethylenically unsaturated, preferably (meth)acrylic-functionalized, titanium or zirconium compound can be cured by ultraviolet radiation in contact with a photoinitiator to produce optical resinous articles having high refractive indices, haze ratings of at most 5% and other properties which may be tailored according to the desired use.

Abstract: Optical articles, including light management films, prepared from brominated polycarbonate material are disclosed. The brominated polycarbonate provides a film exhibiting good light transmittance, high refractive index, good flame resistance, and good mechanical properties.

Abstract: A curable composition includes a multifunctional (meth)acrylate; a substituted or unsubstituted arylether (meth)acrylate monomer; a brominated aromatic (meth)acrylate monomer; and a polymerization intiator. The compositions exhibit high refractive indices and, upon polymerization, the compositons provide films having excellent thermomechanical properties.

Abstract: Blends of monofunctional and multifunctional (meth)acrylate monomers, optionally in addition to oligomeric multifunctional (meth)acrylates), can be cured by ultraviolet radiation in contact with a photoinitiator to produce optical resinous articles having a glass transition temperature of at least 35° C. and having physical properties making them suitable for use as microstructure-bearing articles.

Abstract: Resinous compositions are disclosed which comprise at least one ionomeric polyester and at least one organoclay. Also a method is disclosed for improving the modulus properties of a resinous composition comprising at least one organoclay, the method comprising the steps of combining the resinous composition with at least one ionomeric polyester, and intimately mixing the composition.

Abstract: A curable composition includes a multifunctional (meth)acrylate; a substituted or unsubstituted arylether (meth)acrylate monomer; a brominated aromatic (meth)acrylate monomer; and a polymerization initiator. The compositions exhibit high refractive indices and, upon polymerization, the compositions provide films having excellent thermomechanical properties.

Abstract: A curable composition includes a multifunctional (meth)acrylate; a substituted or unsubstituted arylether (meth)acrylate monomer; and a polymerization initiator. The compositions exhibit high refractive indices and, upon polymerization, the compositions provide films having excellent thermomechanical properties.

Abstract: Blends of monofunctional and multifunctional (meth)acrylate monomers, optionally in addition to oligomeric multifunctional (meth)acrylates), can be cured by ultraviolet radiation in contact with a photoinitiator to produce optical resinous articles having a glass transition temperature of at least 35° C. and having physical properties making them suitable for use as microstructure-bearing articles.

Abstract: Blends of oligomeric urethane multi(meth)acrylate; optionally at least one other monomer selected from the group consisting of acrylic monomers, styrenic monomers and ethylenically unsaturated nitrogen heterocycles, preferably a polyol multi(meth)acrylate; and nanoparticles of an ethylenically unsaturated, preferably (meth)acrylic-functionalized, titanium or zirconium compound can be cured by ultraviolet radiation in contact with a photoinitiator to produce optical resinous articles having high refractive indices, haze ratings of at most 5% and other properties which may be tailored according to the desired use.

Abstract: Systems and methods for creating a combinatorial coating library including a coating system operatively coupled to at least one of a plurality of materials suitable for forming at least one coating layer on a surface of one or more substrates. The systems and methods also including a curing system operative to apply at least one of a plurality of curing environments to each of a plurality of regions associated with the at least one coating layer, the curing system comprising a plurality of waveguides each having a first end corresponding to at least one of the plurality of regions and a second end associated with at least one curing source. The combinatorial coating library comprising a predetermined combination of at least one of the plurality of materials and at least one of the plurality of curing environments associated with each of the plurality of regions.

Abstract: Systems and methods for creating a combinatorial coating library including a coating system operatively coupled to at least one of a plurality of materials suitable for forming at least one coating layer on a surface of one or more substrates and a curing system operative to apply at least one of a plurality of curing environments to each of a plurality of regions associated with the at least one coating layer. The curing system including a scanning mirror system having a mirrored surface positionable relative to an incoming radiation beam, wherein the mirrored surface is positionable to direct the incoming radiation beam to a selected one of the plurality of regions associated with the coating layer. The combinatorial coating library comprising a predetermined combination of at least one of the plurality of materials and at least one of the plurality of curing environments associated with each of the plurality of regions.

Abstract: Systems and methods for creating a combinatorial coating library including a coating system operatively coupled to at least one of a plurality of materials suitable for forming at least one coating layer on a surface of one or more substrates. The systems and methods also including a curing system operative to apply at least one of a plurality of curing environments to each of a plurality of regions associated with the at least one coating layer, the curing system comprising a plurality of waveguides each having a first end corresponding to at least one of the plurality of regions and a second end associated with at least one curing source. The combinatorial coating library comprising a predetermined combination of at least one of the plurality of materials and at least one of the plurality of curing environments associated with each of the plurality of regions.

Abstract: Systems and methods for creating a combinatorial coating library including a coating system operatively coupled to at least one of a plurality of materials suitable for forming at least one coating layer on a surface of one or more substrates and a curing system operative to apply at least one of a plurality of curing environments to each of a plurality of regions associated with the at least one coating layer. The curing system including a scanning mirror system having a mirrored surface positionable relative to an incoming radiation beam, wherein the mirrored surface is positionable to direct the incoming radiation beam to a selected one of the plurality of regions associated with the coating layer. The combinatorial coating library comprising a predetermined combination of at least one of the plurality of materials and at least one of the plurality of curing environments associated with each of the plurality of regions.

Abstract: A device and method for the high throughput screening of the abrasion resistance of coatings. The device includes a plurality of transducers, each of the plurality of transducers having at least one external surface, and a plurality of coatings, each of the plurality of coatings deposited onto the external surface(s) of one of the plurality of transducers. The device also includes a plurality of oscillation sources, coupled to the plurality of transducers, for generating and applying an oscillation potential to each of the plurality of transducers. Further, the device includes a plurality of oscillation detectors, coupled to the plurality of transducers, for measuring the oscillation frequency and a variation in oscillation frequency associated with abrasion resistance in each of the plurality of transducers. The method includes exposing each of the plurality of coatings to an abrasive material, the abrasive material causing a change in mass and/or viscoelastic property in each of the plurality of coatings.

Abstract: Systems and methods for creating a combinatorial coating library including a coating system operatively coupled to at least one of a plurality of materials suitable for forming at least one coating layer on a surface of one or more substrates and a curing system operative to apply at least one of a plurality of curing environments to each of a plurality of regions associated with the at least one coating layer. The curing system including a scanning mirror system having a mirrored surface positionable relative to an incoming radiation beam, wherein the mirrored surface is positionable to direct the incoming radiation beam to a selected one of the plurality of regions associated with the coating layer. The combinatorial coating library comprising a predetermined combination of at least one of the plurality of materials and at least one of the plurality of curing environments associated with each of the plurality of regions.

Abstract: Systems and methods for creating a combinatorial coating library including a coating system operatively coupled to at least one of a plurality of materials suitable for forming at least one coating layer on a surface of one or more substrates. The systems and methods also including a curing system operative to apply at least one of a plurality of curing environments to each of a plurality of regions associated with the at least one coating layer, the curing system comprising a plurality of waveguides each having a first end corresponding to at least one of the plurality of regions and a second end associated with at least one curing source. The combinatorial coating library comprising a predetermined combination of at least one of the plurality of materials and at least one of the plurality of curing environments associated with each of the plurality of regions.

Abstract: The present invention provides a method for quantifying structural defects of a coating composition on a given substrate, where certain structural defect-inducing tests are performed. In this method, a coating formulation is doped with a colorimetric or luminescent material. Concentration of the material depends on the quantum efficiency, excitation and emission wavelengths, and employed detection techniques, and can range from about 1 fM to about 1 mM. Before, during and/or after such tests, the coating is illuminated with a wavelength of radiation at which the reflected or transmitted color or emitted luminescence of the material in the coating is detectable with an optical detector or by visual inspection. In this fashion, the percentage of failure of the coating can be quantified as well as the level of interdiffusion of coating into substrate or substrate into coating. The method of the invention is thus particularly well-suited for the combinatorial analysis of an array of coating samples.

Abstract: An end capped polyester ionomer composition comprising alkylene aryl polyester copolymer metal sulfonate units with end capping units formed by a reaction of the polyester copolymer with an epoxy compound having at least one cyclohexane ring moiety and a terminal epoxy functional group being a substituent on at least one cyclohexane ring moiety.

Abstract: This invention relates to methods for testing elongation and cracking of coating arrays. The method includes simultaneously applying an elongating force to each of a plurality of coatings, and monitoring the coating integrity including cracks and thickness decrease in each coating. A relative performance characteristic of each coating is then determined based on a correlation between a detected crack and/or thickness decrease in the coating, and the corresponding elongating force.