Patents by Inventor Brian A. Cunningham
Brian A. Cunningham has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10870806Abstract: Systems and methods are provided for upgrading a mixture of catalytic slurry oil and coker bottoms by hydroprocessing. Optionally, the upgrading can further include deasphalting the mixture of catalytic slurry oil and coker bottoms to form a deasphalted oil and a deasphalter residue or rock fraction. The mixture of catalytic slurry oil and coker bottoms and/or the deasphalted oil can then be hydroprocessed to form an upgraded effluent that includes fuels boiling range products. Optionally, in some aspects where the feed mixture is deasphalted prior to hydroprocessing, the feed mixture can further include a portion of a (sour) vacuum resid.Type: GrantFiled: March 22, 2018Date of Patent: December 22, 2020Assignee: ExxonMobil Research and Engineering CompanyInventors: Stephen H. Brown, Brian A. Cunningham, Randolph J. Smiley, Samia Ilias, Brenda A. Raich, Tien V. Le
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Patent number: 10752846Abstract: Systems and methods are provided for improving the processing of heavy or challenged feeds in a refinery based on integrated use of deasphalting, coking, and hydroprocessing. An optional fluid catalytic cracking unit can be included in the integrated system to allow for further improvements. The improved processing can be facilitated based on a process configuration where the vacuum resid fractions and/or other difficult fractions are deasphalted to generate a deasphalted oil and a deasphalter residue or rock fraction. The deasphalted oil can be passed into a hydroprocessing unit for further processing. The rock fraction can be used as the feed to a coking unit. Although deasphalter residue or rock is typically a feed with a high content of micro carbon residue, a high lift deasphalting process can allow a portion of the micro carbon residue in the initial feed to remain with the deasphalted oil.Type: GrantFiled: March 23, 2018Date of Patent: August 25, 2020Assignee: ExxonMobil Research & Engineering CompanyInventors: Stephen H. Brown, Brian A. Cunningham, Randolph J. Smiley, Samia Ilias, Brenda A. Raich, Tien V. Le
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Patent number: 10752849Abstract: Systems and methods are provided for upgrading catalytic slurry oil. The upgrading can be performed by deasphalting the catalytic slurry oil to form a deasphalted oil and a residual or rock fraction. The deasphalted oil can then be hydroprocessed to form an upgraded effluent that includes fuels boiling range products.Type: GrantFiled: March 22, 2018Date of Patent: August 25, 2020Assignee: ExxonMobil Research & Engineering CompanyInventors: Stephen H. Brown, Brian A. Cunningham, Randolph J. Smiley, Samia Ilias, Keith K. Aldous, Sara K. Green, Patrick L. Hanks, Kendall S. Fruchey
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Publication number: 20200248079Abstract: Systems and methods are provided for conversion of light paraffinic gases to form liquid products in a two-stage reaction system. In a first stage, the light paraffinic gas is exposed to heat transfer particles in a side riser, where the heat transfer particles correspond to particles used in a separate process. Examples of a separate process include fluidized coking and fluid catalytic cracking. The conditions in the side riser can be selected to allow for conversion of at least a portion of the paraffins to olefins. After conversion, the converted olefin stream is passed to the second reaction stage while the heat transfer particles are returned to the separate process. The converted olefin stream is then exposed to a conversion catalyst under conditions for forming aromatics from the converted olefin stream in a second reaction stage. By performing the initial alkane conversion to olefins in the first reaction stage, the amount of coke formed during the aromatics formation process is reduced or minimized.Type: ApplicationFiled: January 31, 2019Publication date: August 6, 2020Inventors: Arsam Behkish, Brian A. Cunningham, Anjaneya S. Kovvali, Brenda A. Raich, Christopher G. Smalley
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Publication number: 20190382663Abstract: Systems and methods are provided for forming specialty products from hydrotreated FCC fractions. Optionally, the hydrotreated FCC fractions used for forming the specialty products can further include a (hydrotreated) portion of a steam cracker tar fraction. The specialty products that can be formed from hydrotreated FCC fractions include, but are not limited to, carbon blacks, resins, and carbon fibers. A convenient method for forming the hydrotreated FCC fractions can be fixed bed hydrotreatment.Type: ApplicationFiled: August 23, 2019Publication date: December 19, 2019Inventors: Stephen H. BROWN, Brian A. CUNNINGHAM, Randolph J. SMILEY
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Patent number: 10435629Abstract: Systems and methods are provided for forming specialty products from hydrotreated FCC fractions. Optionally, the hydrotreated FCC fractions used for forming the specialty products can further include a (hydrotreated) portion of a steam cracker tar fraction. The specialty products that can be formed from hydrotreated FCC fractions include, but are not limited to, carbon blacks, resins, and carbon fibers. A convenient method for forming the hydrotreated FCC fractions can be fixed bed hydrotreatment.Type: GrantFiled: October 23, 2017Date of Patent: October 8, 2019Assignee: ExxonMobil Research and Engineering CompanyInventors: Stephen H. Brown, Brian A. Cunningham, Randolph J. Smiley
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Patent number: 10323196Abstract: Methods and systems producing gasoline boiling range hydrocarbons from light paraffins are disclosed. Such methods may include exposing a paraffin-containing stream to a catalyst in a side riser of a fluid catalytic cracking reactor under effective conditions for dehydrogenating at least a portion of paraffins in the stream into olefins and thereby producing an olefin-containing stream, wherein the paraffin-containing stream comprises greater than 50 wt % isobutane; and alkylating olefins in the olefin-containing stream to produce a product stream comprising an alkylate fraction comprising hydrocarbons boiling between 100° F. and 400° F.Type: GrantFiled: March 5, 2018Date of Patent: June 18, 2019Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: William R. Gunther, Christopher G. Smalley, Brian A. Cunningham, James R. Bielenberg
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Publication number: 20190010410Abstract: Systems and methods are provided for upgrading a high density cracked feedstock, such as a catalytic slurry oil, by hydroprocessing. The upgrading can further include performing a separation on the effluent from hydroprocessing of the cracked feedstock, such as a distillation (i.e., separation based on boiling point) or a solvent-based separation. The separation on the hydroprocessed effluent can allow for separation of an aromatics-enriched fraction and an aromatics-depleted fraction from the hydroprocessed effluent. The aromatics-enriched fraction and aromatics-depleted fraction can then be separately used and/or separately undergo further processing.Type: ApplicationFiled: June 22, 2018Publication date: January 10, 2019Inventors: Stephen H. Brown, Brian A. Cunningham, Randolph J. Smiley, Samia Ilias, Jesse R. McManus
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Publication number: 20180291287Abstract: Systems and methods are provided for improving operation of a fluid catalytic cracker as part of an integrated processing environment including a deasphalting unit and a hydroprocessor. Optionally, a coker can be included in the integrated system to allow for further improvements. The improved processing can be facilitated based on a process configuration where a combination of deasphalting and hydroprocessing are used to perform conversion on more refractory compounds, so that the fluid catalytic cracker can be operated at lower severity conditions. This can allow for improved production of desirable olefins and reduced production of light paraffins and coke. Additionally or alternately, the processing configuration can allow the bottoms fraction from fluid catalytic cracking to be incorporated into a higher value use than the typical regular sulfur fuel oil disposition.Type: ApplicationFiled: March 28, 2018Publication date: October 11, 2018Inventors: Stephen H. BROWN, Brian A. CUNNINGHAM, Randolph J. SMILEY, Samia ILIAS, Brenda A. RAICH, Tien V. LE
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Publication number: 20180291288Abstract: Systems and methods are provided for improving the processing of heavy or challenged feeds in a refinery based on integrated use of deasphalting, coking, and hydroprocessing. An optional fluid catalytic cracking unit can be included in the integrated system to allow for further improvements. The improved processing can be facilitated based on a process configuration where the vacuum resid fractions and/or other difficult fractions are deasphalted to generate a deasphalted oil and a deasphalter residue or rock fraction. The deasphalted oil can be passed into a hydroprocessing unit for further processing. The rock fraction can be used as the feed to a coking unit. Although deasphalter residue or rock is typically a feed with a high content of micro carbon residue, a high lift deasphalting process can allow a portion of the micro carbon residue in the initial feed to remain with the deasphalted oil.Type: ApplicationFiled: March 23, 2018Publication date: October 11, 2018Inventors: Stephen H. BROWN, Brian A. CUNNINGHAM, Randolph J. SMILEY, Samia ILIAS, Brenda A. RAICH, Tien V. LE
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Publication number: 20180291291Abstract: Systems and methods are provided for upgrading a mixture of catalytic slurry oil and coker bottoms by hydroprocessing. Optionally, the upgrading can further include deasphalting the mixture of catalytic slurry oil and coker bottoms to form a deasphalted oil and a deasphalter residue or rock fraction. The mixture of catalytic slurry oil and coker bottoms and/or the deasphalted oil can then be hydroprocessed to form an upgraded effluent that includes fuels boiling range products. Optionally, in some aspects where the feed mixture is deasphalted prior to hydroprocessing, the feed mixture can further include a portion of a (sour) vacuum resid.Type: ApplicationFiled: March 22, 2018Publication date: October 11, 2018Inventors: Stephen H. BROWN, Brian A. CUNNINGHAM, Randolph J. SMILEY, Samia ILIAS, Brenda A. RAICH, Tien V. LE
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Publication number: 20180291290Abstract: Systems and methods are provided for upgrading catalytic slurry oil. The upgrading can be performed by deasphalting the catalytic slurry oil to form a deasphalted oil and a residual or rock fraction. The deasphalted oil can then be hydroprocessed to form an upgraded effluent that includes fuels boiling range products.Type: ApplicationFiled: March 22, 2018Publication date: October 11, 2018Inventors: Stephen H. BROWN, Brian A. CUNNINGHAM, Randolph J. SMILEY, Samia ILIAS, Keith K. ALDOUS, Sara K. GREEN, Patrick L. HANKS, Kendall S. FRUCHEY
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Publication number: 20180265789Abstract: Methods and systems producing gasoline boiling range hydrocarbons from light paraffins are disclosed. Such methods may include exposing a paraffin-containing stream to a catalyst in a side riser of a fluid catalytic cracking reactor under effective conditions for dehydrogenating at least a portion of paraffins in the stream into olefins and thereby producing an olefin-containing stream, wherein the paraffin-containing stream comprises greater than 50 wt % isobutane; and alkylating olefins in the olefin-containing stream to produce a product stream comprising an alkylate fraction comprising hydrocarbons boiling between 100° F. and 400° F.Type: ApplicationFiled: March 5, 2018Publication date: September 20, 2018Inventors: William R. Gunther, Christopher G. Smalley, Brian A. Cunningham, James R. Bielenberg
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Patent number: 10047299Abstract: Systems and methods are provided for upgrading catalytic slurry oil to form naphtha boiling range and/or distillate boiling range fuel products. It has been unexpectedly discovered that catalytic slurry oil can be separately hydroprocessed under fixed bed conditions to achieve substantial conversion of asphaltenes within the slurry oil (such as substantially complete conversion) while reducing or minimizing the amount of coke formation on the hydroprocessing catalyst. After hydroprocessing, the hydroprocessed effluent can be processed under fluid catalytic cracking conditions to form various products, including distillate boiling range fuels and/or naphtha boiling range fuels. Another portion of the effluent can be suitable for use as a low sulfur fuel oil, such as a fuel oil having a sulfur content of 0.1 wt % or less.Type: GrantFiled: June 30, 2016Date of Patent: August 14, 2018Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Sheryl B. Rubin-Pitel, Kenneth C. H. Kar, Stephen H. Brown, Federico Barrai, Brian A. Cunningham
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Publication number: 20180134965Abstract: Systems and methods are provided for forming specialty products from hydrotreated FCC fractions. Optionally, the hydrotreated FCC fractions used for forming the specialty products can further include a (hydrotreated) portion of a steam cracker tar fraction. The specialty products that can be formed from hydrotreated FCC fractions include, but are not limited to, carbon blacks, resins, and carbon fibers. A convenient method for forming the hydrotreated FCC fractions can be fixed bed hydrotreatment.Type: ApplicationFiled: October 23, 2017Publication date: May 17, 2018Inventors: Stephen H. BROWN, Brian A. CUNNINGHAM, Randolph J. SMILEY
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Publication number: 20180134972Abstract: Systems and methods are provided for upgrading blends of catalytic slurry oil and steam cracker tar to form fuel and/or fuel blending products. The steam cracker tar can optionally correspond to a fluxed steam cracker tar that includes steam cracker gas oil and/or another type of gas oil or other diluent. It has been unexpectedly discovered that blends of catalytic slurry oil and steam cracker tar can be hydroprocessed under fixed bed conditions while reducing or minimizing the amount of coke formation on the hydroprocessing catalyst and/or while reducing or minimizing plugging of the fixed bed, as would be conventionally expected during fixed bed processing of a feed containing a substantial portion of steam cracker tar. Additionally or alternately, it has been unexpectedly discovered that formation of coke fines within steam cracker tar can be reduced or minimized by blending steam cracker tar with catalytic slurry oil.Type: ApplicationFiled: October 23, 2017Publication date: May 17, 2018Inventors: Stephen H. BROWN, Brian A. CUNNINGHAM, Randolph J. SMILEY, Samia ILIAS, Jesse R. McMANUS, Aldrin G. CUEVAS, Teng XU, Gregory R. JOHNSON, John P. GREELEY
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Patent number: 9850434Abstract: A method of predicting the tendency of a heavy oil feed to generate coke deposits in the FCC riser under a given set of operating parameters in the unit; thus, by utilizing operating parameters appropriate to the feed, the formation of coke deposits in the riser may be minimized. The margin between the theoretical dew point of the hydrocarbon feed established from unit operating parameters and the theoretical mix zone temperature in the feed injection zone of the unit is developed by applying a regression-derived linear model from multiple rigorous model runs. The mix zone of the unit is then operated at a temperature which reduces the level of riser coking predicted from this ascertainable margin or, at least, maintains it within levels which are predictable and acceptable.Type: GrantFiled: November 30, 2015Date of Patent: December 26, 2017Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Masaaki Sugita, Christopher Gordon Smalley, Brian A. Cunningham, Timothy Forbes, Tarrant Jay Falcke, Nicholas E. Smith
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Publication number: 20170002279Abstract: Systems and methods are provided for upgrading catalytic slurry oil to form naphtha boiling range and/or distillate boiling range fuel products. It has been unexpectedly discovered that catalytic slurry oil can be separately hydroprocessed under fixed bed conditions to achieve substantial conversion of asphaltenes within the slurry oil (such as substantially complete conversion) while reducing/minimizing the amount of coke formation on the hydroprocessing catalyst. After hydroprocessing, the hydroprocessed effluent can be processed under fluid catalytic cracking conditions to form various products, including distillate boiling range fuels and/or naphtha boiling range fuels. Another portion of the effluent can be suitable for use as a low sulfur fuel oil, such as a fuel oil having a sulfur content of 0.1 wt % or less.Type: ApplicationFiled: June 30, 2016Publication date: January 5, 2017Inventors: Stephen H. BROWN, Federico BARRAI, Brian A. CUNNINGHAM, Sheryl B. RUBIN-PITEL, Kenneth C.H. KAR
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Publication number: 20170002273Abstract: Systems and methods are provided for upgrading catalytic slurry oil to form naphtha boiling range and/or distillate boiling range fuel products. It has been unexpectedly discovered that catalytic slurry oil can be separately hydroprocessed under fixed bed conditions to achieve substantial conversion of asphaltenes within the slurry oil (such as substantially complete conversion) while reducing or minimizing the amount of coke formation on the hydroprocessing catalyst. After hydroprocessing, the hydroprocessed effluent can be processed under fluid catalytic cracking conditions to form various products, including distillate boiling range fuels and/or naphtha boiling range fuels. Another portion of the effluent can be suitable for use as a low sulfur fuel oil, such as a fuel oil having a sulfur content of 0.1 wt % or less.Type: ApplicationFiled: June 30, 2016Publication date: January 5, 2017Inventors: Sheryl B. RUBIN-PITEL, Kenneth C.H. KAR, Stephen H. BROWN, Federico BARRAI, Brian A. CUNNINGHAM
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Publication number: 20160362613Abstract: A potentially heat-deficient fluid catalytic cracking process for effecting a bulk boiling point conversion of a high boiling point petroleum feed to lower boiling products in which the overall enthalpy balance between the endothermic cracking and exothermic regeneration is maintained by combustion of a supplemental fuel in the middle or upper region of the dense bed in the regenerator (including the region immediately above the dense phase bed). There is a direct economic benefit from operation of the cracking process in this way since the preferred supplemental fuel is methane (natural gas) which is currently a low cost fuel while liquid products are higher value. Use of natural gas as a supplemental fuel will allow re-optimization of the catalyst and operations separately from the heat balance demand.Type: ApplicationFiled: May 17, 2016Publication date: December 15, 2016Inventors: Brian A. Cunningham, Christopher G. Smalley, Mohsen N. Harandi