Abstract: A passive flow modulation device for a machine defining an axial direction and a radial direction, the passive flow modulation device including: a first ring with a first coefficient of thermal expansion; a second ring disposed coaxially with the first ring and positioned at least partially inward of the first ring along the radial direction, spaced from the first ring along the axial direction, or both, the first ring, the second ring, or both defining at least in part one or more passages, the second ring with a second coefficient of thermal expansion that is less than the first coefficient of thermal expansion to passively modulate a size of the one or more passages during operation.

Abstract: Nozzle segment assemblies for gas turbine engines include an outer band, inner band, and at least one airfoil body between the outer band and inner band. The airfoil body includes an outer end extending through the outer band and having an outer end reinforced wall portion engaging with the outer band and an inner end extending through the inner band and having an inner end reinforced wall portion engaging with the inner band. A thickness of the outer end and inner end reinforced wall portions are each greater than a thickness of a central wall portion of the airfoil body to reduce stresses in the airfoil body. The outer band, the inner band, and the airfoil bodies are ceramic matrix composite (CMC) materials. Direct mounting of the airfoil bodies to the inner and outer hangers of the nozzle further reduce stress.

Abstract: Composite components having a T or L-shaped configuration that include features that reduce void defects between abutting laminate portions and provide improved mechanical properties are provided. Methods for forming such components are also provided. In one exemplary aspect, a composite component defines a first direction and a second direction and includes a wedged-shaped noodle at a joint interface between an abutting first laminate portion extending along the first direction and a second laminate portion extending along the second direction. The noodle has a first surface that is angled with respect to the second direction. At least one of the plies of the second laminate portion terminate and attach to the angled first surface of the noodle.

Abstract: A ceramic matrix composite (CMC) component including a subcomponent, such as a band flowpath, a load bearing wall and a wall support, each comprised of a ceramic matrix composite (CMC) including reinforcing fibers embedded in a matrix. The CMC component further including at least one mechanical joint joining the subcomponent, the load bearing wall and the wall support to form the CMC component. The reinforcing fibers of the load bearing wall are oriented substantially normal to the reinforcing fibers of the subcomponent and the wall support. Methods are also provided for joining the subcomponent, the load bearing wall and the wall support to form a mechanical joint.

Abstract: A ceramic matrix composite (CMC) component including a subcomponent, such as a band flowpath, a load bearing wall and a wall support, each comprised of a ceramic matrix composite (CMC) including reinforcing fibers embedded in a matrix. The CMC component further including at least one mechanical joint joining the subcomponent, the load bearing wall and the wall support to form the CMC component. The reinforcing fibers of the load bearing wall are oriented substantially normal to the reinforcing fibers of the subcomponent and the wall support. Methods are also provided for joining the subcomponent, the load bearing wall and the wall support to form a mechanical joint.

Abstract: Composite components having a T or L-shaped configuration that include features that reduce void defects between abutting laminate portions and provide improved mechanical properties are provided. Methods for forming such components are also provided. In one exemplary aspect, a composite component defines a first direction and a second direction and includes a wedged-shaped noodle at a joint interface between an abutting first laminate portion extending along the first direction and a second laminate portion extending along the second direction. The noodle has a first surface that is angled with respect to the second direction. At least one of the plies of the second laminate portion terminate and attach to the angled first surface of the noodle.

Abstract: An airfoil assembly for a gas turbine engine and a method of transferring load from the ceramic matrix composite (CMC) airfoil assembly to a metallic vane assembly support member are provided. The airfoil assembly includes a forward end and an aft end with respect to an axial direction of the gas turbine engine. The airfoil assembly includes a radially outer end component, a radially inner end component, and a hollow airfoil body extending therebetween. The radially outer end component including a radially outwardly-facing end surface having a non-compression load-bearing feature extending radially outwardly and formed integrally with the outer end component, the load-bearing feature configured to mate with a complementary feature formed in a radially inner surface of a first airfoil assembly support structure and selectively positioned orthogonally to a force imparted into the airfoil assembly.

Abstract: The invention includes processes for the synthesis of amphetamine, dexamphetamine, methamphetamine, derivatives of these, including their salts, and novel precursors and intermediates obtained thereby, by synthesizing aziridine phosphoramidate compounds in specified solvents at specified temperatures, and then converting to a novel aryl or aryl-alkyl phosphoramidate precursors using an organometallic compound such as a copper salt, where the novel aryl or aryl-alkyl phosphoramidate precursor is then easily converted to the target compounds using known reactions.

Abstract: The invention includes processes for the synthesis of amphetamine, dexamphetamine, methamphetamine, derivatives of these, including their salts, and novel precursors and intermediates obtained thereby, by synthesizing aziridine phosphoramidate compounds in specified solvents at specified temperatures, and then converting to a novel aryl or aryl-alkyl phosphoramidate precursors using an organometallic compound such as a copper salt, where the novel aryl or aryl-alkyl phosphoramidate precursor is then easily converted to the target compounds using known reactions,

Abstract: The invention includes processes for the synthesis of amphetamine, dexamphetamine, methamphetamine, derivatives of these, including their salts, and novel precursors and intermediates obtained thereby, by synthesizing aziridine phosphoramidate compounds in specified solvents at specified temperatures, and then converting to a novel aryl or aryl-alkyl phosphoramidate precursors using an organometallic compound such as a copper salt, where the novel aryl or aryl-alkyl phosphoramidate precursor is then easily converted to the target compounds using known reactions.

Abstract: An airfoil assembly for a gas turbine engine and a method of transferring load from the ceramic matrix composite (CMC) airfoil assembly to a metallic vane assembly support member are provided. The airfoil assembly includes a forward end and an aft end with respect to an axial direction of the gas turbine engine. The airfoil assembly further includes a radially outer end component including a radially outwardly-facing end surface having a non-compression load-bearing feature extending radially outwardly from the outwardly-facing end surface and formed integrally with the outer end component, the feature configured to mate with a complementary feature formed in a radially inner surface of a first airfoil assembly support structure, the feature selectively positioned orthogonally to a force imparted into the airfoil assembly.

Abstract: The invention includes processes for the synthesis of amphetamine, dexamphetamine, methamphetamine, derivatives of these, including their salts, and novel precursors and intermediates obtained thereby, by synthesizing aziridine phosphoramidate compounds in specified solvents at specified temperatures, and then converting to a novel aryl or aryl-alkyl phosphoramidate precursors using an organometallic compound such as a copper salt, where the novel aryl or aryl-alkyl phosphoramidate precursor is then easily converted to the target compounds using known reactions,

Abstract: A bi-layer photovoltaic cell, and method (100) of making same, with an electric field applied at the p-n heterojunction interface. The cell includes a first semiconductor layer including a binder, nanocrystals of an n-type semiconductor, and spatially bound cations and a second semiconductor layer contacting the first semiconductor layer that includes a binder, nanocrystals of a p-type semiconductor, and spatially bound anions. The cell further includes a p-n heterojunction at the contacting interface between the first and second semiconductor layers. An electric field is created by the spatially bound cations and anions that are located in the layers proximal to the p-n heterojunction. The nanocrystals are single crystals of organic semiconductors that are less than 50 nanometers in size and that comprise a majority of the volume of their respective layers. The binder is a polymer matrix, such as an epoxy. The cell includes electrical contacts abutting the semiconductor layers.

Abstract: A bi-layer photovoltaic cell, and method (100) of making same, with an electric field applied at the p-n heterojunction interface. The cell includes a first semiconductor layer including a binder, nanocrystals of an n-type semiconductor, and spatially bound cations and a second semiconductor layer contacting the first semiconductor layer that includes a binder, nanocrystals of a p-type semiconductor, and spatially bound anions. The cell further includes a p-n heterojunction at the contacting interface between the first and second semiconductor layers. An electric field is created by the spatially bound cations and anions that are located in the layers proximal to the p-n heterojunction. The nanocrystals are single crystals of organic semiconductors that are less than 50 nanometers in size and that comprise a majority of the volume of their respective layers. The binder is a polymer matrix, such as an epoxy. The cell includes electrical contacts abutting the semiconductor layers.

Abstract: A modular heat sink decoupling capacitor array includes a plurality of modules, each defining parallel distributed decoupling plates, and each module forming a heat sink fin. Each module includes multiple spaced apart contacts for providing low inductance connections with an associated device. A power distribution interposer module is attached to a heat sink surface of the modular decoupling capacitor. The interposer module is used for implementing power delivery without using valuable ball grid array (BGA) connections and printed circuit board (PCB) layers.

Abstract: A method and apparatus are provided for implementing very high density signal probing of a printed circuit board having a pad pattern connected to signals of interest. A metal plate includes a plurality of through holes arranged in a predefined pattern that corresponds to the pad pattern on the printed circuit board. At least one signal module is inserted within a selected one of the through holes of the metal plate. Each signal module defines a coaxial connector for electrical mating engagement with a coaxial cable connector and has an embedded resistor. At least one power/ground module is inserted within a selected one of the through holes. Each power/ground module contains a high dielectric constant material between an outer conductor and a center conductor defining a capacitor. The capacitor provides a low impedance path between the metal plate and a power or ground pad of the printed circuit board.

Abstract: A photoelectrochemical-electrochromic device comprising a first transparent electrode and a second transparent electrode in parallel, spaced relation to each other. The first transparent electrode is electrically connected to the second transparent electrode. An electrochromic material is applied to the first transparent electrode and a nanoporous semiconductor film having a dye adsorbed therein is applied to the second transparent electrode. An electrolyte layer contacts the electrochromic material and the nanoporous semiconductor film. The electrolyte layer has a redox couple whereby upon application of light, the nanoporous semiconductor layer dye absorbs the light and the redox couple oxidizes producing an electric field across the device modulating the effective light transmittance through the device.

Abstract: Advanced batteries having a long cycle lifetime are provided. More specifically, the present invention relates to electrodes made from redox polymer films and batteries in which either the positive electrode, the negative electrode, or both, comprise redox polymers. Suitable redox polymers for this purpose include pyridyl or polypyridyl complexes of transition metals like iron, ruthenium, osmium, chromium, tungsten and nickel; porphyrins (either free base or metallo derivatives); phthalocyanines (either free base or metallo derivatives); metal complexes of cyclams, such as tetraazacyclotetradecane; metal complexes of crown ethers and metallocenes such as ferrocene, cobaltocene and ruthenocene.

Abstract: An amperometric biosensor and method for the detection of hydrogen peroxide, NADH, or NADPH with high sensitivity includes an electrode having on its testing surface a three-dimensional redox polymer network in which peroxidase is immobilized.

Abstract: An improved enzyme electrode includes a three-dimensional redox polymer network having redox enzymes bound thereto, and also having a protein excluding polymeric coating.