Abstract: Golf balls having an inner core made of a foamed composition are provided. The core assembly preferably includes a foam inner core (center) and surrounding outer core layer. A cross-linked thermoplastic, preferably an ethylene acid copolymer ionomer, is used to form the foam composition. The core layers have different hardness gradients and specific gravity values. The ethylene acid copolymer is reacted with a metallic acrylate salt and peroxide free-radical initiator to form the cross-linked polymer. The foamed, cross-linked composition helps provide the inner core with good resiliency, thermal stability, and durability. Non-foamed thermoplastics or thermosets such as polybutadiene rubber may be used to form the outer core layer. The ball further includes a cover that may be multi-layered.

Abstract: A golf ball comprising a core and a cover layer, wherein at least one of the core or cover layer comprises a plasticized polyurethane composition comprising at least one polyurethane and at least one plasticizer.

Abstract: Multi-layered golf balls having a core, intermediate layer, and cover are provided. The ball includes a non-foamed inner core (center) made of a thermoplastic or thermoset composition such as polybutadiene rubber. An intermediate layer comprising a foamed composition, such as polyurethane foam, is disposed about the inner core. The foamed intermediate layer may have a specific gravity gradient within the layer, wherein the outer surface specific gravity is greater than the midpoint specific gravity. Ball constructions having two intermediate layers, wherein at least one layer is a foamed layer can be made. A cover having at least one layer is disposed about the intermediate layer.

Abstract: Multi-piece golf balls having a solid core made of a foamed composition and a cover are provided. Preferably, the core is dual-layered having has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition containing mineral filler particulate, for example, nanoclay particles, is used to form the foam center. The concentration of clay particulate is preferably in a range of 0.1 to 60% by weight. The surrounding outer core layer may be made from non-foamed or foamed compositions. For example, polybutadiene rubber or highly neutralized olefin acid copolymers may be used in the outer core layer. The core layers have different hardness gradients and specific gravity values.

Abstract: Multi-layered golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) made from a foam or metal-containing composition, or it has a hollow shell construction, and the outer core layer is made of a thermoplastic composition. Preferably, the thermoplastic composition comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. The core assembly preferably has a positive hardness gradient extending across the entire assembly. The core structure and resulting ball have relatively good resiliency at given compressions.

Abstract: Golf balls comprising a core having at least one layer and a cover having at least one layer are provided. At least one of the layers is made from a thermoplastic composition preferably comprising a telechelic ionomer derived from alkyl-cis-cyclooctene and cis-cyclooctene. The telechelic ionomer composition also may be used to form intermediate layers. Blends of telechelic ionomers and polybutadiene rubbers or ethylene acid copolymers can be prepared. The telechelic ionomer compositions can be used to make a cover layer having good impact durability and shear resistance and that also helps provide the ball with high resiliency.

Abstract: The present invention provides a golf ball comprising an inner core and an outer cover layer, wherein at least one of the inner core and outer cover layer is formed from a thermoplastic polyurethane ionomer.

Abstract: Golf balls having covers made of thermoplastic polyurethane compositions are provided. Multi-piece golf balls can be made. In one embodiment, the outer cover layer is formed from a composition comprising a thermoplastic polyurethane and acid copolymer ionomer. The cover composition also can contain hydroxyl-containing compounds. The golf ball having the thermoplastic polyurethane cover can be treated with an isocyanate compound. The golf ball also can be treated with a hydroxyl and/or silane-containing compound. The cover composition and surface coatings can further include catalysts, ultraviolet (UV)-light stabilizers, and other additives. The coating methods have many benefits and the finished balls have good physical properties.

Abstract: A video slot machine has M reels, each displaying N symbols when stopped. Above the display of the reels is a set of generally valuable replacement symbols that have been independently selected at random independent from the reel display. Each reel is associated with a particular replacement symbol in the set. If a special symbol is displayed on a reel, the replacement symbol associated with that reel substitutes for the special symbol when determining the award. Examples of the replacement symbols include wild symbols, bonus symbols, and multiplier symbols. After each game, the replacement symbols are shifted, and used replacement symbols are randomly replaced to vary the possibilities for each game. The player is incentivized to play longer due to the possibility of using valuable replacement symbols in the symbol array and the possibility of very high awards being granted by multiple special symbols being displayed.

Abstract: Golf ball comprising cast layer of thermoset polymer mixture having centering time Ct1 and comprising: (i) a polyurethane composition, polyurea composition, and/or polyurethane/polyurea hybrid composition; and (ii) a treated fumed silica compound in an amount such that centering time Ct1 is independent of the thermoset polymer mixture's degree of cure and lower than a centering time Ct2 of the thermoset polymer composition (which is dependent on its gel window Gw). The treated fumed silica compound may be surface treated with at least one of polydimethylsiloxane, hexamethyldisilazane, and dimethyldichlorosilane. In some embodiments, delta time ?t1 between a dispensing time Dt1 of the thermoset polymer mixture and centering time Ct1 is less than a delta time ?t2 between Ct1 and centering time Ct2. Centering time Ct1 and dispensing time Da may differ by less than 10 seconds or even by 5 seconds or less.

Abstract: Multi-piece golf balls having a solid core made of a foamed composition and a cover are provided. Preferably, the core is dual-layered having has a foam inner core (center) and surrounding thermoset or thermoplastic outer core layer. Preferably, a polyurethane foam composition containing mineral filler particulate, for example, nanoclay particles, is used to form the foam center. The concentration of clay particulate is preferably in a range of 0.1 to 60% by weight. The surrounding outer core layer may be made from non-foamed or foamed compositions. For example, polybutadiene rubber or highly neutralized olefin acid copolymers may be used in the outer core layer. The core layers have different hardness gradients and specific gravity values.

Abstract: Multi-piece golf balls containing a dual-core structure are provided. The core structure includes an inner core (center) comprising a foam composition, preferably foamed polyurethane. The outer core layer is preferably formed from a non-foamed thermoset composition such as polybutadiene rubber. The inner and outer core layers can have different hardness gradients. Preferably, the specific gravity (density) of the foam inner core is less than the density of the outer core layer. The ball further includes a cover of at least one layer and may include at least one casing layer. The core structure and resulting ball have relatively good resiliency.

Abstract: Multi-layered golf balls having at least one layer made of a polyester composition containing a polyester thermoplastic elastomer and plasticizer are provided. The plasticizers help reduce the glass transition temperature (Tg) of the composition and various plasticizers may be used. For example, the composition may include alkyl oleate plasticizers such as ethyl oleate and octyl oleate. Polyester-ether block copolymers are particularly preferred. The golf ball includes a core having at least one layer and a cover having at least one layer. The polyester composition may be used to form any core, cover, or other layer in the golf ball.

Abstract: Method of making a golf ball comprising: providing a subassembly and a thermoset polymer composition; partially curing the thermoset polymer composition and elongating same while in a partial cure state; forming a layer about the subassembly comprising the thermoset polymer composition; and further curing the thermoset polymer composition. A moldable thermoset polymer composition may be elongated while in state of partial cure. The thermoset polymer composition may be stepwise elongated by: stretching a thermoset polymer composition in at least one plane while in partial cure state and before forming into first and second half shells; forming the thermoset polymer composition into first and second half shells and elongating the thermoset polymer composition in three dimensions while in the partial cure state and before mating the first and second half shells about the subassembly; and mating the first and second half shells about the subassembly and forming a stepwise-elongated thermoset layer.

Abstract: Golf ball constructions incorporating at least one layer comprising a polycyclopentene rubber having advantageously modified end groups.

Abstract: A golf ball includes a core having an outer surface and a geometric center. The core is formed from a substantially homogenous rubber composition. An ionomeric inner cover layer is formed about the core and has a material hardness of about 60 Shore D or greater. The golf ball includes an outer cover layer formed from a polyurea or a polyurethane and having a material hardness of about 60 Shore D or less. The outer surface of the core has a trans content of about 12% or less and a hardness of about 71 to 88 Shore C. The geometric center of the core has a trans content of about 10% or less and a hardness of about 60 to 80 Shore C. The core has an outer surface hardness greater than a geometric center hardness by about 5 to 19 Shore C to define a positive hardness gradient.

Abstract: Multi-layered golf balls containing a two-layered core assembly are provided. Preferably, at least one of the core layers is formed from a thermoplastic composition that comprises: a) thermoplastic non-acid polymer, and b) plasticizer. In one preferred embodiment, the inner core is made of a first thermoplastic composition comprising the non-acid polymer and plasticizer; and the outer core layer is made of a second thermoplastic composition. For example, an ethylene acid copolymer may be used to form the outer core layer. A fatty acid ester such as ethyl oleate is preferably used as the plasticizer. Suitable non-acid polymers include, for example, polyesters, polyamides, polyolefins, and polyurethanes. The core assembly has a relatively high resiliency at given compressions.

Abstract: Golf ball comprising cast layer of thermoset polymer mixture having centering time Ct1 and consisting of: (i) a thermoset polymer composition consisting of polyurethane composition, polyurea composition, and/or polyurethane/polyurea hybrid composition; and (ii) a treated fumed silica compound in an amount such that centering time Ct1 is independent of the thermoset polymer mixture's degree of cure and lower than a centering time Ct2 of the thermoset polymer composition (which is dependent on its gel window Gw). The treated fumed silica compound may be surface treated with at least one of polydimethylsiloxane, hexamethyldisilazane, and dimethyldichlorosilane. In some embodiments, delta time ?t1 between a dispensing time Dt1 of the thermoset polymer mixture and centering time Ct1 is less than a delta time ?t2 between Ct1 and centering time Ct2. Centering time Ct1 and dispensing time Dt1 may differ by less than 10 seconds or even by 5 seconds or less.

Abstract: Golf balls comprising a multi-layer core and a cover are disclosed. The multi-layer core comprises at least one intermediate core layer formed from a metallic, composite, or inorganic/organic hybrid composition.

Abstract: Golf balls having a multi-layered core made of a foamed composition are provided. The core assembly preferably includes a foam inner core (center) and surrounding outer core layer. Preferably, a polyurethane foam composition is used to form the foam center. The core layers have different hardness gradients and specific gravity values. The foamed inner core assembly includes a geometric center, outer surface (skin), and thermal barrier layer that helps protect the foamed center region from the negative effects of high temperatures used during the ball-manufacturing process. Non-foamed thermoset materials such as polybutadiene rubber may be used to form the thermal barrier layer. The foam cores have good resiliency, thermal stability, and durability over a wide temperature range. The ball further includes a cover that may be multi-layered.