Patent number: 9300008
Abstract: A main object of the present invention is to provide a Li—La—Ti—O based solid electrolyte material having high Li ion conductivity in the crystal grain boundary. The present invention attains the object by providing solid electrolyte material represented by a general formula: Li3x(La(2/3?x)?aM1a) (Ti1?bM2b)O3, wherein “x” is 0<x<0.17; “a” is 0?a?0.5; “b” is 0?b?0.5; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga, and wherein the solid electrolyte material is a crystalline material, is in thin film form, and has a thickness of 250 nm to 850 nm.
Type:
Grant
Filed:
April 13, 2010
Date of Patent:
March 29, 2016
Assignee:
TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventors:
Chihiro Yada, Shoji Yokoishi, Brian Elliott Hayden, Thierry Le Gall, Duncan Clifford Alan Smith, Christopher Edward Lee
Patent number: 9196924
Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La2?aM1a)(Ti3?bM2b)O9+?, characterized in that “x” is 0<x?1; “a” is 0?a?2; “b” is 0?b?3; “?” is ?2???2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.
Type:
Grant
Filed:
April 13, 2010
Date of Patent:
November 24, 2015
Assignee:
TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventors:
Chihiro Yada, Hiroshi Suyama, Shoji Yokoishi, Brian Elliott Hayden, Thierry Le Gall, Duncan Clifford Alan Smith, Christopher Edward Lee
Patent number: 8945779
Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zO?, characterized in that “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.652?x/(x+y+z)?0.753, and 0.167?y/(y+z)?0.232; “a” is 0?a?1; “b” is 0?b?1; “?” is 0.8???1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.
Type:
Grant
Filed:
April 13, 2010
Date of Patent:
February 3, 2015
Assignee:
Toyota Jidosha Kabushiki Kaisha
Inventors:
Chihiro Yada, Hiroshi Suyama, Shoji Yokoishi, Brian Elliott Hayden, Thierry Le Gall, Duncan Clifford Alan Smith, Christopher Edward Lee
Publication number: 20130071756
Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La2-aM1a)(Ti3-bM2b)O9+?, characterized in that “x” is 0<x?1; “a” is 0?a?2; “b” is 0?b?3; “?” is ?2???2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.
Type:
Application
Filed:
April 13, 2010
Publication date:
March 21, 2013
Applicant:
TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventors:
Chihiro Yada, Hiroshi Suyama, Shoji Yokoishi, Brian Elliott Hayden, Thierry Le Gall, Duncan Clifford Alan Smith, Christopher Edward Lee
Publication number: 20130071757
Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zO?, characterized in that “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.652?x/(x+y+z)?0.753, and 0.167?y/(y+z)?0.232; “a” is 0?a?1; “b” is 0?b?1; “?” is 0.8???1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.
Type:
Application
Filed:
April 13, 2010
Publication date:
March 21, 2013
Applicant:
TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventors:
Chihiro Yada, Hiroshi Suyama, Shoji Yokoishi, Brian Elliott Hayden, Thierry Le Gall, Duncan Clifford Alan Smith, Christopher Edward Lee