Abstract: An all-additive apparatus for direct fabrication of nanometer-scale planar and multilayer structures that performs “pick-and-place” retrieval and deposition of materials comprises a tip and a controller and transport mechanism configured for causing the tip to acquire a transferable material and deposit at least a portion of the acquired transferable material at a predetermined location onto a substrate, without the use of a bridging medium, in order to directly assemble a structure. The tip may be submillimeter-scale, may comprise a plurality of sub-tips disposed in a predetermined arrangement, and/or may mechanically vibrate. Mechanical vibration of the tip may be monitored. The tip may acquire the transferable material from a reservoir. The assembled structure may be cured on the substrate.

Abstract: An all-additive method for direct fabrication of nanometer-scale planar and multilayer structures comprises the steps of acquiring a transferable material with a submillimeter-scale tip, depositing at least a portion of the acquired first transferable material at a predetermined location onto a substrate without a bridging medium, and repeating to create a structure using the transferable material.

Abstract: Materials, compounds and compositions for radiation patternable functional thin films, methods of synthesizing such materials and compounds, and methods for forming an electronically functional thin film and structures including such a film. The compounds and compositions generally include (a) nanoparticles of an electronically functional material or substance and (b) ligands containing a (photo)reactive group. The method generally includes the steps of (1) irradiating the compound and/or composition, and (2) curing the irradiated compound and/or composition, generally to form an electronically functional film. The functional thin film includes a sintered mixture of nanoparticles. The thin film exhibits improved morphology and/or resolution relative to an otherwise identical structure made by an identical process, but without the (photo)functional group on the ligand, and/or relative to an otherwise identical material patterned by a conventional graphics art-based printing process.

Abstract: A method of and device for controlled printing using liquid embossing techniques is disclosed. In accordance with the embodiments of the invention a stamp comprises a differentiated embossing surface with protruding and recessed surfaces to enhance the ability of the stamp to selectively displace liquid ink from a print surface and/or remove solvent from the liquid in a soft curing process. A stamp with differentiated surfaces is fabricated by selectively coating, or otherwise treating the protruding features, the recessed features, or a combination thereof, such that the surface energies and/or wettability of the protruding surfaces and the recessed surfaces are differentiated.

Abstract: An all-additive method for direct fabrication of nanometer-scale planar and multilayer structures utilizes the tip of a scanning probe microscope and a material reservoir. True “pick-and-place” retrieval and deposition of materials with a wide range of electrical, chemical, and mechanical properties is thereby facilitated.

Abstract: The current invention is directed to micro-stencil devices and methods. A micro-stencil, in accordance with this invention, comprises a patterned stencil membrane formed from a polymeric layer patterned with stencil features preferably having lateral dimensions in a range of 10 micron to 100 nanometers or less. The micro-stencil preferably includes a porous backing membrane coupled to the stencil membrane to control the flow of print fluids, to allow for two-way flow of print fluids and/or curing gases during a printing operation. The stencil membrane is preferably configured to directly print the stencil features onto a suitable print medium surface. The micro-stencil of the instant invention, is preferably utilized for printing structures comprising interconnected layers, such as micro-circuits, and/or structures comprising polymer arrays.