Abstract: A nitrogen liquefier configured to be integrated with an argon and nitrogen producing cryogenic air separation unit and method of nitrogen liquefaction are provided. The integrated nitrogen liquefier and associated methods may be operated in at least three distinct modes including: (i) a nil liquid nitrogen mode; (ii) a low liquid nitrogen mode; and (iii) a high liquid nitrogen mode. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

Abstract: A highly efficient refrigeration system and process for precooling/liquefaction of a hydrogen feed stream and method of turndown of such system is disclosed. The disclosed refrigeration system and associated methods employ a reverse Brayton refrigeration cycle using a nitrogen based refrigerant and a fully integrated three pinion bridge (BriM) machine operatively coupling at least two turbine/expanders and at least four nitrogen refrigerant compression stages. Turndown of the hydrogen precooling and liquefaction process requires removal of nitrogen refrigerant from the refrigeration recycle loop by retaining liquid nitrogen in the phase separator, which is sized to accommodate the bulk of the nitrogen refrigerant used in the refrigeration circuit.

Abstract: A highly efficient refrigeration system and process for precooling of a hydrogen feed stream with concurrent nitrogen liquefaction is disclosed. The disclosed refrigeration system and associated methods employ a reverse Brayton refrigeration cycle using a nitrogen based refrigerant and a fully integrated three pinion bridge (BriM) machine operatively coupling at least two turbine/expanders and at least four nitrogen refrigerant compression stages.

Abstract: A system and method for the production and supply of a densified, liquid oxidant to a space vehicle launch facility with one or more launch platforms is provided. In one embodiment, a low pressure gaseous oxygen stream is piped from a nearby air separation unit to the space vehicle launch facility where it is then liquefied and densified in a two-stage, integrated liquefaction/densification system. In an alternate embodiment, a liquid oxygen stream produced at an air separation unit is densified in a two-stage, integrated densification system at or near the air separation unit with the resulting densified liquid oxygen product transported via truck/trailer to a nearby space vehicle launch facility.

Abstract: A system and method for the production and supply of a densified, liquid oxidant to a space vehicle launch facility is provided. A stream of liquid oxygen taken from a co-located, liquid producing air separation unit is densified in a two refrigeration stage, integrated densification system. The first refrigeration stage is a nitrogen based reverse Brayton cycle refrigeration cycle that provides refrigeration to the second refrigeration stage. The second refrigeration stage is a helium and/or neon comprising refrigerant loop that densifies the liquid oxygen to a temperature between about 70 Kelvin and 57 Kelvin. The integrated densification system may also be configured to densify liquid methane or other propellants used in space vehicle launches.

Abstract: A system and method for the production and supply of a densified, liquid oxidant to a space vehicle launch facility with one or more launch platforms is provided. A low pressure gaseous oxygen stream is piped from a nearby air separation unit and is then liquefied and densified in a two-stage, integrated liquefaction/densification system. The first refrigeration stage is a nitrogen based reverse Brayton cycle refrigeration cycle, that liquefies the gaseous oxygen and subcools the resulting liquid oxygen to a temperature of about 81 Kelvin. The second refrigeration stage is a mixed refrigerant loop containing some combination of helium and/or neon refrigerants that densifies the liquid oxygen to a temperature of about 57 Kelvin. The integrated liquefaction and densification system may also be configured to densify liquid methane or other propellants used in space vehicle launches.

Abstract: A system and method for the co-production of a densified, liquid oxidant and a densified liquid methane fuel to a space vehicle launch facility is provided. In one embodiment, a low pressure gaseous oxygen stream is piped from a nearby air separation unit to the space vehicle launch facility where it is then liquefied and densified in a two-stage, integrated liquefaction/densification system that also densifies a source of liquid methane. In an alternate embodiment, a liquid oxygen stream produced at an air separation unit is densified in a two-stage, integrated densification system configured to densify both the liquid oxygen as well a source of liquid methane at or near the air separation unit with the resulting densified liquid products transported via truck/trailer to a nearby space vehicle launch facility.

Abstract: A moderate pressure nitrogen and argon producing cryogenic air separation unit is provided that includes a three distillation column system and turbine air stream bypass arrangement or circuit. The turbine air stream bypass arrangement or circuit is configured to improve argon and nitrogen recoveries in select operating modes by optionally diverting a portion of the turbine air stream to a nitrogen waste stream circuit drawn from the lower pressure column of the cryogenic air separation unit such that the diverted portion of the turbine air stream bypasses the distillation column system.

Abstract: A nitrogen liquefier configured to be integrated with an argon and nitrogen producing cryogenic air separation unit and method of nitrogen liquefaction are provided. The integrated nitrogen liquefier and associated methods may be operated in at least three distinct modes including: (i) a nil liquid nitrogen mode; (ii) a low liquid nitrogen mode; and (iii) a high liquid nitrogen mode. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

Abstract: A system and method for co-producing ultra-high purity oxygen and ultra-high purity hydrogen from a water electrolysis unit is provided. The presently disclosed system and method includes upgrading the crude oxygen stream coming from the water electrolysis unit by means of a small, stand-alone cryogenic distillation system wherein the refrigeration for such cryogenic distillation system is supplied by a nitrogen recycle refrigeration loop.

Abstract: A nitrogen liquefier configured to be integrated with an argon and nitrogen producing cryogenic air separation unit and method of nitrogen liquefaction are provided. The integrated nitrogen liquefier and associated methods may be operated in at least three distinct modes including: (i) a nil liquid nitrogen mode; (ii) a low liquid nitrogen mode; and (iii) a high liquid nitrogen mode. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

Abstract: A nitrogen liquefier configured to be integrated with an argon and nitrogen producing cryogenic air separation unit and method of nitrogen liquefaction are provided. The integrated nitrogen liquefier and associated methods may be operated in at least three distinct modes including: (i) a nil liquid nitrogen mode; (ii) a low liquid nitrogen mode; and (iii) a high liquid nitrogen mode. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

Abstract: A nitrogen liquefier configured to be integrated with an argon and nitrogen producing cryogenic air separation unit and method of nitrogen liquefaction are provided. The integrated nitrogen liquefier and associated methods may be operated in at least three distinct modes including: (i) a nil liquid nitrogen mode; (ii) a low liquid nitrogen mode; and (iii) a high liquid nitrogen mode. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

Abstract: Enhancements to the distillation column system and cycles for an argon and nitrogen producing cryogenic air separation unit are provided. The enhancements include systems and methods for: (i) recovery of xenon and krypton; (ii) production of oxygen product substantially free of hydrocarbons; and (iii) improvement in the design and performance of the super-stage argon column. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

Abstract: A moderate pressure nitrogen and argon producing cryogenic air separation unit is provided that includes a three distillation column system and turbine air stream bypass arrangement or circuit. The turbine air stream bypass arrangement or circuit is configured to improve argon and nitrogen recoveries in select operating modes by optionally diverting a portion of the turbine air stream to a nitrogen waste stream circuit drawn from the lower pressure column of the cryogenic air separation unit such that the diverted portion of the turbine air stream bypasses the distillation column system.

Abstract: A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98 percent or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.

Abstract: A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon and an overall nitrogen recovery of 98% or greater. The air separation is configured to produce a high purity oxygen enriched stream which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption prepurifier unit. Argon recovery is facilitated with the use of an argon superstaged column.

Abstract: A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98 percent or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.

Abstract: A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98% or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.

Abstract: A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98 percent or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.