Abstract: A method for removing hydrocarbon impurities from acetic acid is disclosed. The method comprises extracting acetic acid with a hydrophilic imidazolium salt. The imidazolium salt preferably has the general structure of wherein X? is a counter ion and R1, R2, R3, R4, and R5 are independently selected from the group consisting of C1-C6 hydrocarbon substitutes. The method is useful for removing hydrocarbon impurities from the alkane distillation bottoms stream of a methanol carbonylation process.

Abstract: A method for removing hydrocarbon impurities from an acetic acid production process is disclosed. The method comprises distilling at least a portion of the heavy organic phase from the decanter of the acetic acid production process into a vapor stream comprising the majority of methyl iodide (i.e., over 50% of the methyl iodide from the heavy organic phase) and a bottoms stream comprising the majority of acetic acid, methyl acetate, methyl iodide and the hydrocarbon impurity (i.e., over 50% of each of the components from the heavy organic phase); extracting the bottoms stream with water, an acetic acid aqueous solution, or with a methanol aqueous solution to form an organic phase comprising the majority of the hydrocarbon impurity (over 50% of the hydrocarbon impurity from the bottom stream) and an aqueous phase comprising the majority of methyl iodide (over 50% of the methyl iodide from the bottoms stream); and recycling the aqueous phase to the carbonylation reaction.

Abstract: A method for removing aldehyde impurities from an acetic acid stream is disclosed. The method comprises reacting an acetic acid stream containing aldehyde impurities with a hydroxyl compound to form corresponding acetals. The acetals are subsequently removed from the acetic acid by, e.g., distillation.

Abstract: A method for removing aldehyde impurities from an acetic acid stream is disclosed. The method comprises reacting aldehyde impurities with a hydroxyl compound in a drying distillation column or a combined column to form corresponding acetals. The acetals are subsequently removed as heavy impurities from acetic acid by distillation.

Abstract: Described herein are inkjet inks that are substantially free of volatile organic compounds, or have a relatively small amount of volatile organic compounds, that are considered to significantly contribute to the formation of ground level ozone. The inkjet inks include at least one resin selected from the group consisting of a vinyl chloride-vinyl acetate copolymer resin and a copolyester resin; at least one colorant; and a solvent mixture that includes acetone and at least one additional solvent selected from the group consisting of tertiary butyl acetate and parachlorobenzotrifluoride. Also described are methods of printing indicia with inkjet inks.

Abstract: Inkjet inks that include a solvent, a thermoplastic resin, a urethane resin ,a first colorant, and a second colorant. When printed onto a surface of an article, the first and second colorant migrate into the article, thereby producing a resilient image. Also described methods of applying indicia with the inkjet inks and articles that include an image printed with the inkjet inks.

Abstract: Disclosed is a method for removing aldehyde impurities from a methyl acetate supply. The method comprises reacting the methyl acetate supply with a polyol and converting the aldehyde impurities to cyclic acetals. The acetals are subsequently removed from the methyl acetate supply by, e.g., distillation. The purified methyl acetate supply is used for carbonylation to produce acetic acid.

Abstract: A method for removing aldehyde impurities from acetic acid is disclosed. The method comprises extracting the aldehyde impurities from a methyl iodide solution such as the decanter heavy phase with a polyol. After the aldehyde impurities are removed, the methyl iodide heavy phase can be recycled to the carbonylation.

Abstract: A method for removing aldehyde impurities from an acetic acid stream is disclosed. The method comprises reacting aldehyde impurities with a hydroxyl compound in a drying distillation column or a combined column to form corresponding acetals. The acetals are subsequently removed as heavy impurities from acetic acid by distillation.

Abstract: A method for removing aldehyde impurities from an acetic acid stream is disclosed. The method comprises reacting an acetic acid stream containing aldehyde impurities with a hydroxyl compound to form corresponding acetals. The acetals are subsequently removed from the acetic acid by, e.g., distillation.

Abstract: Impulse ink jet compositions are provided which are suitable for printing clear, well-defined alphanumeric text or low spread, narrow bar width bar codes on porous substrates such as Kraft paper or corrugated cardboard. The inks may also contain an antioxidant that lowers the dissolved oxygen level in the ink, thereby enhancing the jetting performance of the printhead.

Abstract: Inkjet inks that include a solvent, a thermoplastic resin, a urethane resin, a first colorant, and a second colorant. When printed onto a surface of an article, the first and second colorant migrate into the article, thereby producing a resilient image. Also described methods of applying indicia with the inkjet inks and articles that include an image printed with the inkjet inks.

Abstract: Methods for reducing cavitation in impulse or drop on demand ink jetting devices are provided. Impulse ink jet compositions including antioxidant are also provided which are suitable for printing clear, well-defined alphanumeric text or low spread, narrow bar width bar codes on porous substrates such as Kraft paper or corrugated cardboard. The antioxidant additive lowers the dissolved oxygen level in the ink, thereby enhancing the jetting performance of the printhead.

Abstract: Methods for reducing cavitation in impulse or drop on demand ink jetting devices are provided. Impulse ink jet compositions comprising antioxidant are also provided which are suitable for printing clear, well-defined alphanumeric text or low spread, narrow bar width bar codes on porous substrates such as Kraft paper or corrugated cardboard. The antioxidant additive lowers the dissolved oxygen level in the ink, thereby enhancing the jetting performance of the printhead.

Abstract: Impulse ink jet compositions are provided which are suitable for printing clear, well-defined alphanumeric text or low spread, narrow bar width bar codes on porous substrates such as Kraft paper or corrugated cardboard. The inks may also contain an antioxidant that lowers the dissolved oxygen level in the ink, thereby enhancing the jetting performance of the printhead.

Abstract: Methods for reducing cavitation in impulse or drop on demand ink jetting devices are provided. Impulse ink jet compositions comprising antioxidant are also provided which are suitable for printing clear, well-defined alphanumeric text or low spread, narrow bar width bar codes on porous substrates such as Kraft paper or corrugated cardboard. The ink compositions preferably comprise from about 20 to 50 percent by weight of a carbon black dispersion, from about 10 to 20 percent by weight of a dispersion medium, from about 40 to 60 percent by weight of a plasticizer and less than 2% of an antioxidant additive. The antioxidant additive lowers the dissolve oxygen level in the ink, thereby enhancing the jetting perfomance of the printhead.

Abstract: Impulse ink jet compositions are provided which are suitable for printing clear, well-defined alphanumeric text or low spread, narrow bar width bar codes on porous substrates such as Kraft paper or corrugated cardboard. In one embodiment, the ink compositions preferably comprise from about 20 to 50 percent by weight of a carbon black dispersion, from about 10 to 20 percent by weight of a dispersion medium, from about 40 to 60 percent by weight of a plasticizer and optionally an antioxidant additive. The antioxidant additive lowers the dissolved oxygen level in the ink, thereby enhancing the jetting performance of the printhead.

Abstract: Impulse ink jet compositions are provided which are suitable for printing clear, well-defined alphanumeric text or low spread, narrow bar width bar codes on porous substrates such as Kraft paper or corrugated cardboard. In one embodiment, the ink compositions preferably comprise from about 20 to 50 percent by weight of a carbon black dispersion, from about 10 to 20 percent by weight of a dispersion medium, from about 40 to 60 percent by weight of a plasticizer and optionally an antioxidant additive. The antioxidant additive lowers the dissolved oxygen level in the ink, thereby enhancing the jetting performance of the printhead.