Abstract: An improved method for the preparation of a supported polymerisation catalyst system comprises the combination of (i) a porous support (ii) a polymerisable monomer, (iii) a polymerisation catalyst, and (iv) a cocatalyst, characterised in that the polymerisable monomer is added to the porous support before addition of one or both of the polymerisation catalyst and the cocatalyst. The preferred polymerisation catalyst is a metallocene complex and the preferred porous support is silica. The resultant supported catalysts are stable over long periods of time. The supported catalyst are particularly suitable for use in the gas phase.

Abstract: An organic coating composition is described, which can be used to enrich the surface region of a metal-based substrate with aluminum. The composition comprises an aluminum-based powder and at least one organic resin, e.g., alkyds, epoxies, or silicone materials. At least some of the aluminum-based powder is in the form of substantially spherical powder particles. The coating composition is substantially free of hexavalent chromium. It can be applied to the substrate by a variety of techniques, such as spraying. It is then heat-treated, to cause diffusion of aluminum into the surface region of the substrate, e.g., a turbine engine component. The composition exhibits good thermal and chemical stability for extended periods of time. Related articles are also described.

Abstract: Supported catalyst systems are provided comprising (a) a transition metal compound, (b) an activator comprising (iii) an aluminoxane or (iv) a Group lilA metal or metalloid compound, and (c) a support material comprising an inorganic metal oxide, inorganic metal halide or polymeric material or mixtures thereof characterised in that the support material has been pretreated with a source of a transition metal atom. The preferred transition metal compounds are metallocenes and the source of the transition metal atom is typically a ferrous or cupric metal salt. The supported catalyst systems show improved activity and also may reduce fouling in gas phase fluidised bed processes.

Abstract: This invention pertains to methods for oligonucleotide synthesis, specifically the synthesis of oligonucleotides that contain a high content of guanine monomers. In more detail, the invention relates to a method for coupling a nucleoside phosphoramidite during the synthesis of an oligonucleotide to a universal support, to a first nucleoside, or to an extending oligonucleotide. The invention further relates to oligonucleotides obtainable by the methods of the invention.

Abstract: Differential, current-steering DACs with reduced small signal differential non-linearity. A set of binary-weighted steerable constant current generators is used in which each constant current generator comprises a ternary constant current generator configured to generate a three-state differential current in response to a ternary signal on a control input. Each ternary current generator is associated with a bit of the binary code. The DAC further comprises a code converter coupled between a digital input, to receive a signed digital value for conversion, and control inputs of the steerable current generators, to convert the binary input code to a ternary code to control the steerable current generators to provide a differential analogue output. In embodiments the smallest current source is ½I0 where I0 is a change in differential output current caused by an lsb change in the binary input code.

Abstract: A catalyst for the polymerisation of 1-olefins is disclosed, which comprises (1) a compound of Formula B wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6 and R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R1-R7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and (2) a further catalyst. Copolymers made using the catalyst having specific physical properties are also disclosed.

Abstract: A process for the polymerisation of olefins is described involving the use of a catalyst system comprising a supported transition metal compound and an activator based on an organoborane and an aluminoxane. Preferably the transition metal compound is a metallocene complex. The support is pretreated with an organoaluminium compound and the process is particularly suitable for the gas phase preparation of copolymers of ethylene and alpha-olefins having a molecular weight distribution in the range 2.5-7.0 and a melt strength in the range 3-12 cN.

Abstract: A full-size keyboard with an integrated laptop stand. In one embodiment, the laptop stand is part of a cover for a portable keyboard, with the cover unfolding and including a pop-up stand for supporting a portable computer. The stand is thus connected to the keyboard rather than being a separate article. The cover includes electronics, such as a USB hub and ports, an MP3 player docking station, speakers, etc. A flexible hinge connects the keyboard and cover, with imbedded electrical flex connectors. A presence sensor, such as a PIR sensor, shuts off battery use by these electronics when the user is not around.

Abstract: This application relates to a compound of Formula (I) or a pharmaceutically acceptable salt thereof, pharmaceutical compositions thereof, and its use as an inhibitor of the NK-1 subtype of tachykinin receptors, as well as a process for its preparation and intermediates therefor.

Abstract: A method for the preparation of a supported transition metal catalyst system which includes the steps of: (i) mixing together in a suitable solvent (a) an aluminoxane and (b) an ionic activator containing a cation and an anion, wherein the anion has at least one substituent containing a moiety having an active hydrogen, (ii) addition of the mixture from step (i) to a support material, and (iii) addition of a transition metal compound in a suitable solvent. The use of tetraisobutylaluminoxane as the aluminoxane results in a more stable activity profile and improved polymer properties in particular melt strength.

Abstract: The present invention is concerned with an apparatus for preparing food (10), in particular baby food made from fresh vegetables or the like, the apparatus comprising a body (12) and heating means (32) adapted to heat and/or cook food placed within the body, preferably by steaming, the apparatus (20) also comprising a blending assembly (18) which is operable to blend food located within the body (12), preferably after said food has been cooked using the apparatus (10).

Abstract: Differential, current-steering DACs with reduced small signal differential non-linearity. A set of binary-weighted steerable constant current generators is used in which each constant current generator comprises a ternary constant current generator configured to generate a three-state differential current in response to a ternary signal on a control input. Each ternary current generator is associated with a bit of the binary code. The DAC further comprises a code converter coupled between a digital input, to receive a signed digital value for conversion, and control inputs of the steerable current generators, to convert the binary input code to a ternary code to control the steerable current generators to provide a differential analogue output. In embodiments the smallest current source is ½I0 where I0 is a change in differential output current caused by an 1sb change in the binary input code.

Abstract: Supported catalyst systems are provided comprising (a) a transition metal compound, (b) a non aluminoxane activator comprising, and (c) a support material comprising an inorganic metal oxide, inorganic metal halide or polymeric material or mixtures thereof characterised in that the support material has been pretreated with an SO4 containing compound. The preferred transition metal compounds are metallocenes and the SO4 containing compound is typically sulphuric acid. The supported catalyst systems show improved activity and also may reduce fouling in gas phase fluidised bed processes.