Patents by Inventor Brita Engels
Brita Engels has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11318451Abstract: Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.Type: GrantFiled: August 20, 2019Date of Patent: May 3, 2022Assignee: ExxonMobil Research & Engineering CompanyInventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi, Brandon J. O'Neill
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Patent number: 11318450Abstract: Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.Type: GrantFiled: August 20, 2019Date of Patent: May 3, 2022Assignee: ExxonMobil Research & Engineering CompanyInventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
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Patent number: 11111153Abstract: Processes are provided for preparing molecular sieves for use as catalysts. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier which may be selected from cationic surfactants having a single quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars, and combinations thereof.Type: GrantFiled: August 20, 2019Date of Patent: September 7, 2021Assignee: ExxonMobil Research and Engineering CompanyInventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
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Publication number: 20200062604Abstract: Processes are provided for preparing molecular sieves for use as catalysts. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier which may be selected from cationic surfactants having a single quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars, and combinations thereof.Type: ApplicationFiled: August 20, 2019Publication date: February 27, 2020Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
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Publication number: 20200061592Abstract: Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.Type: ApplicationFiled: August 20, 2019Publication date: February 27, 2020Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
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Publication number: 20200061593Abstract: Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.Type: ApplicationFiled: August 20, 2019Publication date: February 27, 2020Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi, Brandon J. O'Neill
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Patent number: 9725327Abstract: A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing; (R) and water, said synthesis mixture having the following molar composition: YO2, (p)X2O3: (q) MOH: (r) R: (s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.Type: GrantFiled: November 14, 2013Date of Patent: August 8, 2017Assignee: ExxonMobil Chemical Patents Inc.Inventors: Machteld Maria Wilfried Mertens, Marc H. Anthonis, Antonie Jan Bons, Brita Engels, Wilfried Jozef Mortier, Jane Chi-ya Cheng
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Patent number: 9365431Abstract: Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Additionally, by controlling the ratio of water content to silica content in the synthesis mixture, it has unexpectedly been found that ZSM-58 crystals can be formed with an improved morphology. The improved morphology can result in ZSM-58 crystals with a more uniform size across the various dimensions of the crystal, which allows for more uniform diffusion within the crystal. This is in contrast to conventionally synthesized crystals, where the size of the crystal can vary along different axes of the crystals.Type: GrantFiled: November 8, 2013Date of Patent: June 14, 2016Assignee: ExxonMobil Research and Engineering CompanyInventors: Ivy D. Johnson, Nadya A. Hrycenko, Barbara Carstensen, Machteld Mertens, Brita Engels
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Publication number: 20150298982Abstract: A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing agent (R) and water, said synthesis mixture having the following molar composition: YO2:(p) X2O3:(q) MOH:(r) R:(s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.Type: ApplicationFiled: November 14, 2013Publication date: October 22, 2015Inventors: Machteld Maria Wilfried Mertens, Marc H. Anthonis, Antonie Jan Bons, Brita Engels, Wilfried Jozef Mortier, Jane Chi-ya Cheng
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Publication number: 20140161717Abstract: Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Additionally, by controlling the ratio of water content to silica content in the synthesis mixture, it has unexpectedly been found that ZSM-58 crystals can be formed with an improved morphology. The improved morphology can result in ZSM-58 crystals with a more uniform size across the various dimensions of the crystal, which allows for more uniform diffusion within the crystal. This is in contrast to conventionally synthesized crystals, where the size of the crystal can vary along different axes of the crystals.Type: ApplicationFiled: November 8, 2013Publication date: June 12, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Ivy D. Johnson, Nadya A. Hrycenko, Barbara Carstensen, Machteld Mertens, Brita Engels
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Patent number: 8049053Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.Type: GrantFiled: January 28, 2011Date of Patent: November 1, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Machteld M. Mertens, Brita Engels, Els Cecilia De Clerck
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Publication number: 20110124937Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.Type: ApplicationFiled: January 28, 2011Publication date: May 26, 2011Inventors: Machteld M. Mertens, Brita Engels, Els Cecilia De Clerck
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Patent number: 7901649Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.Type: GrantFiled: November 7, 2005Date of Patent: March 8, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Machteld M. Mertens, Brita Engels, Els Cecilia De Clerck
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Publication number: 20110009685Abstract: The disclosure relates to a substantially uniform molecular sieve having MFI topology and quasi parallelepiped morphology. This disclosure also relates to a method of making the crystalline molecular sieve of this disclosure.Type: ApplicationFiled: February 13, 2009Publication date: January 13, 2011Inventors: Sebastien Kremer, Brita Engels, Els Cecilia De Clerck, Katleen Hermans
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Patent number: 7090814Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then cooling the combination of the phosphorus source and organic directing agent to a temperature of less than or equal to 50° C., prior to introducing a source of aluminum into the combination. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.Type: GrantFiled: November 10, 2004Date of Patent: August 15, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: Machteld M. Mertens, Brita Engels, Els Cecilia De Clerck
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Publication number: 20060100095Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then cooling the combination of the phosphorus source and organic directing agent to a temperature of less than or equal to 50° C., prior to introducing a source of aluminum into the combination. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.Type: ApplicationFiled: November 10, 2004Publication date: May 11, 2006Inventors: Machteld Mertens, Brita Engels, Els De Clerck
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Publication number: 20060100472Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.Type: ApplicationFiled: November 7, 2005Publication date: May 11, 2006Inventors: Machteld Mertens, Brita Engels, Els Clerck
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Patent number: 7014827Abstract: Disclosed is a method for the manufacture of silicoaluminophosphate (SAPO) and/or aluminophosphate (ALPO) molecular sieves. The method includes maintaining the slurry of the as crystallized molecular sieve under substantially static conditions when stored after substantially complete crystallization and prior to recovery of the product.Type: GrantFiled: October 23, 2001Date of Patent: March 21, 2006Inventors: Machteld Maria Mertens, Brita Engels
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Patent number: 6838586Abstract: The invention is directed to a method for making a silicoaluminophosphate (SAPO) molecular sieve from a reaction mixture comprising components present in amounts sufficient to form the SAPO, the reaction mixture having a first pH. The method comprises the steps of: adding an acid to the reaction mixture after the reaction mixture undergoes a change in pH from the first pH; and crystallizing the SAPO from the reaction mixture. The present invention is also directed to a silicoaluminophosphate molecular sieve made by this process.Type: GrantFiled: December 31, 2002Date of Patent: January 4, 2005Assignee: Exxon Mobil Chemical Patents Inc.Inventors: Machteld M. Mertens, Brita Engels, Ronald G. Searle, Grigore Pop, Irina Rodica Tamas, Rodica Ganea, Ruxandra Birjega
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Patent number: 6685905Abstract: In SAPO manufacture, handling of the synthesis mixture is facilitated by providing an initial aluminium-containing aqueous slurry with an H2O:Al2O3 weight ratio of 3:1 to 8:1.Type: GrantFiled: February 13, 2002Date of Patent: February 3, 2004Assignee: ExxonMobil Chemical Patents Inc.Inventors: Machteld M. Mertens, Brita Engels