Patents by Inventor Brita Engels

Brita Engels has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11318451
    Abstract: Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.
    Type: Grant
    Filed: August 20, 2019
    Date of Patent: May 3, 2022
    Assignee: ExxonMobil Research & Engineering Company
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi, Brandon J. O'Neill
  • Patent number: 11318450
    Abstract: Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.
    Type: Grant
    Filed: August 20, 2019
    Date of Patent: May 3, 2022
    Assignee: ExxonMobil Research & Engineering Company
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
  • Patent number: 11111153
    Abstract: Processes are provided for preparing molecular sieves for use as catalysts. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier which may be selected from cationic surfactants having a single quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars, and combinations thereof.
    Type: Grant
    Filed: August 20, 2019
    Date of Patent: September 7, 2021
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
  • Publication number: 20200062604
    Abstract: Processes are provided for preparing molecular sieves for use as catalysts. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier which may be selected from cationic surfactants having a single quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars, and combinations thereof.
    Type: Application
    Filed: August 20, 2019
    Publication date: February 27, 2020
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
  • Publication number: 20200061592
    Abstract: Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.
    Type: Application
    Filed: August 20, 2019
    Publication date: February 27, 2020
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
  • Publication number: 20200061593
    Abstract: Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.
    Type: Application
    Filed: August 20, 2019
    Publication date: February 27, 2020
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi, Brandon J. O'Neill
  • Patent number: 9725327
    Abstract: A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing; (R) and water, said synthesis mixture having the following molar composition: YO2, (p)X2O3: (q) MOH: (r) R: (s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.
    Type: Grant
    Filed: November 14, 2013
    Date of Patent: August 8, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Machteld Maria Wilfried Mertens, Marc H. Anthonis, Antonie Jan Bons, Brita Engels, Wilfried Jozef Mortier, Jane Chi-ya Cheng
  • Patent number: 9365431
    Abstract: Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Additionally, by controlling the ratio of water content to silica content in the synthesis mixture, it has unexpectedly been found that ZSM-58 crystals can be formed with an improved morphology. The improved morphology can result in ZSM-58 crystals with a more uniform size across the various dimensions of the crystal, which allows for more uniform diffusion within the crystal. This is in contrast to conventionally synthesized crystals, where the size of the crystal can vary along different axes of the crystals.
    Type: Grant
    Filed: November 8, 2013
    Date of Patent: June 14, 2016
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ivy D. Johnson, Nadya A. Hrycenko, Barbara Carstensen, Machteld Mertens, Brita Engels
  • Publication number: 20150298982
    Abstract: A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing agent (R) and water, said synthesis mixture having the following molar composition: YO2:(p) X2O3:(q) MOH:(r) R:(s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.
    Type: Application
    Filed: November 14, 2013
    Publication date: October 22, 2015
    Inventors: Machteld Maria Wilfried Mertens, Marc H. Anthonis, Antonie Jan Bons, Brita Engels, Wilfried Jozef Mortier, Jane Chi-ya Cheng
  • Publication number: 20140161717
    Abstract: Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Additionally, by controlling the ratio of water content to silica content in the synthesis mixture, it has unexpectedly been found that ZSM-58 crystals can be formed with an improved morphology. The improved morphology can result in ZSM-58 crystals with a more uniform size across the various dimensions of the crystal, which allows for more uniform diffusion within the crystal. This is in contrast to conventionally synthesized crystals, where the size of the crystal can vary along different axes of the crystals.
    Type: Application
    Filed: November 8, 2013
    Publication date: June 12, 2014
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Ivy D. Johnson, Nadya A. Hrycenko, Barbara Carstensen, Machteld Mertens, Brita Engels
  • Patent number: 8049053
    Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.
    Type: Grant
    Filed: January 28, 2011
    Date of Patent: November 1, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Machteld M. Mertens, Brita Engels, Els Cecilia De Clerck
  • Publication number: 20110124937
    Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.
    Type: Application
    Filed: January 28, 2011
    Publication date: May 26, 2011
    Inventors: Machteld M. Mertens, Brita Engels, Els Cecilia De Clerck
  • Patent number: 7901649
    Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.
    Type: Grant
    Filed: November 7, 2005
    Date of Patent: March 8, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Machteld M. Mertens, Brita Engels, Els Cecilia De Clerck
  • Publication number: 20110009685
    Abstract: The disclosure relates to a substantially uniform molecular sieve having MFI topology and quasi parallelepiped morphology. This disclosure also relates to a method of making the crystalline molecular sieve of this disclosure.
    Type: Application
    Filed: February 13, 2009
    Publication date: January 13, 2011
    Inventors: Sebastien Kremer, Brita Engels, Els Cecilia De Clerck, Katleen Hermans
  • Patent number: 7090814
    Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then cooling the combination of the phosphorus source and organic directing agent to a temperature of less than or equal to 50° C., prior to introducing a source of aluminum into the combination. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.
    Type: Grant
    Filed: November 10, 2004
    Date of Patent: August 15, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Machteld M. Mertens, Brita Engels, Els Cecilia De Clerck
  • Publication number: 20060100095
    Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then cooling the combination of the phosphorus source and organic directing agent to a temperature of less than or equal to 50° C., prior to introducing a source of aluminum into the combination. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.
    Type: Application
    Filed: November 10, 2004
    Publication date: May 11, 2006
    Inventors: Machteld Mertens, Brita Engels, Els De Clerck
  • Publication number: 20060100472
    Abstract: In a method of synthesizing a silicoaluminophosphate molecular sieve, a synthesis mixture is prepared by combining a source of phosphorus and at least one organic directing agent; and then introducing a source of aluminum into the combination of the phosphorus source and organic directing agent, wherein the temperature of the combination is less than or equal to 50° C. when addition of the source of aluminum begins. After addition of a source of silicon, the synthesis mixture is heated to a crystallization temperature of between about 100° C. and about 300° C. and the molecular sieve is recovered.
    Type: Application
    Filed: November 7, 2005
    Publication date: May 11, 2006
    Inventors: Machteld Mertens, Brita Engels, Els Clerck
  • Patent number: 7014827
    Abstract: Disclosed is a method for the manufacture of silicoaluminophosphate (SAPO) and/or aluminophosphate (ALPO) molecular sieves. The method includes maintaining the slurry of the as crystallized molecular sieve under substantially static conditions when stored after substantially complete crystallization and prior to recovery of the product.
    Type: Grant
    Filed: October 23, 2001
    Date of Patent: March 21, 2006
    Inventors: Machteld Maria Mertens, Brita Engels
  • Patent number: 6838586
    Abstract: The invention is directed to a method for making a silicoaluminophosphate (SAPO) molecular sieve from a reaction mixture comprising components present in amounts sufficient to form the SAPO, the reaction mixture having a first pH. The method comprises the steps of: adding an acid to the reaction mixture after the reaction mixture undergoes a change in pH from the first pH; and crystallizing the SAPO from the reaction mixture. The present invention is also directed to a silicoaluminophosphate molecular sieve made by this process.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: January 4, 2005
    Assignee: Exxon Mobil Chemical Patents Inc.
    Inventors: Machteld M. Mertens, Brita Engels, Ronald G. Searle, Grigore Pop, Irina Rodica Tamas, Rodica Ganea, Ruxandra Birjega
  • Patent number: 6685905
    Abstract: In SAPO manufacture, handling of the synthesis mixture is facilitated by providing an initial aluminium-containing aqueous slurry with an H2O:Al2O3 weight ratio of 3:1 to 8:1.
    Type: Grant
    Filed: February 13, 2002
    Date of Patent: February 3, 2004
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Machteld M. Mertens, Brita Engels