Abstract: A spectroscopic sample analysis apparatus includes an actively controlled heat exchanger in serial fluid communication with a spectroscopic analyzer, and a controller communicably coupled to the heat exchanger. The heat exchanger is disposed downstream of a fluid handler in the form of a stream selection unit/stream switching unit (SSU), a solvent/standard recirculation unit (SRU), and/or an auto-sampling unit (ASU). The SSU selectively couples individual stream inputs to an output port. The SRU includes a solvent/standard reservoir, and selectively couples output ports to the heat exchanger, and returns the solvent/standard sample to the reservoirs. The ASU includes a sample reservoir having a sample transfer pathway with a plurality of orifices disposed at spaced locations along a length thereof. The controller selectively actuates the fluid handler, enabling sample to flow there through to the heat exchanger, and actuates the heat exchanger to maintain the sample at a predetermined temperature.

Abstract: A method and apparatus is provided for determining concentration of components in a liquid hydrocarbon mixture including hydrocarbons and water flowing through an alkylation process. A fluid flow path conveys the liquid continuously from the alkylation process through a first instrument configured for measuring a property of the liquid mixture, and having responsivities to concentration of the components, which are independent of the concentration of the water. A temperature detector generates temperature data for the liquid, and a second instrument measures another property of the liquid mixture. The instruments have mutually distinct responsivities to concentrations of the components.

Abstract: A spectroscopic sample analysis apparatus includes an actively controlled heat exchanger in serial fluid communication with a spectroscopic analyzer, and a controller communicably coupled to the heat exchanger. The heat exchanger is disposed downstream of a fluid handler in the form of a stream selection unit (SSU), a solvent/standard recirculation unit (SRU), and/or an auto-sampling unit (ASU). The SSU selectively couples individual stream inputs to an output port. The SRU includes a solvent/standard reservoir, and selectively couples output ports to the heat exchanger, and returns the solvent/standard sample to the reservoirs. The ASU includes a sample reservoir having a sample transfer pathway with a plurality of orifices disposed at spaced locations along a length thereof. The controller selectively actuates the fluid handler, enabling sample to flow therethrough to the heat exchanger, and actuates the heat exchanger to maintain the sample at a predetermined temperature.

Abstract: A spectroscopic sample analysis apparatus includes an actively controlled heat exchanger in serial fluid communication with a spectroscopic analyzer, and a controller communicably coupled to the heat exchanger. The heat exchanger is disposed downstream of a fluid handler in the form of a stream selection unit (SSU), a solvent/standard recirculation unit (SRU), and/or an auto-sampling unit (ASU). The SSU selectively couples individual stream inputs to an output port. The SRU includes a solvent/standard reservoir, and selectively couples output ports to the heat exchanger, and returns the solvent/standard sample to the reservoirs. The ASU includes a sample reservoir having a sample transfer pathway with a plurality of orifices disposed at spaced locations along a length thereof. The controller selectively actuates the fluid handler, enabling sample to flow therethrough to the heat exchanger, and actuates the heat exchanger to maintain the sample at a predetermined temperature.

Abstract: Closed-loop control of a hydrocarbon process is provided by an analyzer including an instrument configured for measuring a property of the liquid mixture, and having responsivities to concentrations of one of the components, independent of concentrations of others of the components. A temperature detector generates temperature data for the liquid mixture, and a processor captures data generated by the temperature detector and the instrument, and uses the data in combination with a model of responsivities to various concentrations of the components at various temperatures, to determine a temperature compensated concentration of the components while the liquid mixture flows continuously through the analyzer. A process control module including a process model of the hydrocarbon process, is coupled to the analyzer and is couplable to the hydrocarbon process, to receive the temperature compensated concentration and to generate at least one output configured to affect operation of the hydrocarbon process.

Abstract: A method and apparatus is provided for determining concentration of components in a liquid hydrocarbon mixture including hydrocarbons and water flowing through an alkylation process. A fluid flow path conveys the liquid continuously from the alkylation process through a first instrument configured for measuring a property of the liquid mixture, and having responsivities to concentration of the components, which are independent of the concentration of the water. A temperature detector generates temperature data for the liquid, and a second instrument measures another property of the liquid mixture. The instruments have mutually distinct responsivities to concentrations of the components.

Abstract: A method and apparatus is provided for determining concentration of components in a liquid hydrocarbon mixture including hydrocarbons and water flowing through an alkylation process. A fluid flow path conveys the liquid continuously from the alkylation process through a first instrument configured for measuring a property of the liquid mixture, and having responsivities to concentration of the components, which are independent of the concentration of the water. A temperature detector generates temperature data for the liquid, and a second instrument measures another property of the liquid mixture. The instruments have mutually distinct responsivities to concentrations of the components.

Abstract: A method and apparatus is provided for determining concentration of components in a liquid hydrocarbon mixture including hydrocarbons and water flowing through an alkylation process. A fluid flow path conveys the liquid continuously from the alkylation process through a first instrument configured for measuring a property of the liquid mixture, and having responsivities to concentration of the components, which are independent of the concentration of the water. A temperature detector generates temperature data for the liquid, and a second instrument measures another property of the liquid mixture. The instruments have mutually distinct responsivities to concentrations of the components.

Abstract: Closed-loop control of a hydrocarbon process is provided by an analyzer including an instrument configured for measuring a property of the liquid mixture, and having responsivities to concentrations of one of the components, independent of concentrations of others of the components. A temperature detector generates temperature data for the liquid mixture, and a processor captures data generated by the temperature detector and the instrument, and uses the data in combination with a model of responsivities to various concentrations of the components at various temperatures, to determine a temperature compensated concentration of the components while the liquid mixture flows continuously through the analyzer. A process control module including a process model of the hydrocarbon process, is coupled to the analyzer and is couplable to the hydrocarbon process, to receive the temperature compensated concentration and to generate at least one output configured to affect operation of the hydrocarbon process.

Abstract: A method and apparatus is provided for determining concentration of components in a liquid hydrocarbon mixture including hydrocarbons and water flowing through an alkylation process. A fluid flow path conveys the liquid continuously from the alkylation process through a first instrument configured for measuring a property of the liquid mixture, and having responsivities to concentration of the components, which are independent of the concentration of the water. A temperature detector generates temperature data for the liquid, and a second instrument measures another property of the liquid mixture. The instruments have mutually distinct responsivities to concentrations of the components.

Abstract: A spectroscopic sample analysis apparatus includes an actively controlled heat exchanger in serial fluid communication with a spectroscopic analyzer, and a controller communicably coupled to the heat exchanger. The heat exchanger is disposed downstream of a fluid handler in the form of a stream selection unit (SSU), a solvent/standard recirculation unit (SRU), and/or an auto-sampling unit (ASU). The SSU selectively couples individual stream inputs to an output port. The SRU includes a solvent/standard reservoir, and selectively couples output ports to the heat exchanger, and returns the solvent/standard sample to the reservoirs. The ASU includes a sample reservoir having a sample transfer pathway with a plurality of orifices disposed at spaced locations along a length thereof. The controller selectively actuates the fluid handler, enabling sample to flow therethrough to the heat exchanger, and actuates the heat exchanger to maintain the sample at a predetermined temperature.

Abstract: A spectroscopic sample analysis apparatus includes an actively controlled, direct contact heat exchanger in serial fluid communication with a spectroscopic analyzer, and a controller communicably coupled to the heat exchanger. The heat exchanger is disposed downstream of a fluid handler in the form of a stream selection unit (SSU), a solvent/standard recirculation unit (SRU), and/or an auto-sampling unit (ASU). The SSU selectively couples individual stream inputs to an output port. The SRU includes a solvent/standard reservoir, and selectively couples output ports to the heat exchanger, and returns the solvent/standard sample to the reservoirs. The ASU includes a sample reservoir having a sample transfer pathway with a plurality of orifices disposed at spaced locations along a length thereof. The controller selectively actuates the fluid handler, enabling sample to flow therethrough to the heat exchanger, and actuates the heat exchanger to maintain the sample at a predetermined temperature.

Abstract: A spectroscopic sample analysis apparatus includes an actively controlled, direct contact heat exchanger in serial fluid communication with a spectroscopic analyzer, and a controller communicably coupled to the heat exchanger. The heat exchanger is disposed downstream of a fluid handler in the form of a stream selection unit (SSU), a solvent/standard recirculation unit (SRU), and/or an auto-sampling unit (ASU). The SSU selectively couples individual stream inputs to an output port. The SRU includes a solvent/standard reservoir, and selectively couples output ports to the heat exchanger, and returns the solvent/standard sample to the reservoirs. The ASU includes a sample reservoir having a sample transfer pathway with a plurality of orifices disposed at spaced locations along a length thereof. The controller selectively actuates the fluid handler, enabling sample to flow therethrough to the heat exchanger, and actuates the heat exchanger to maintain the sample at a predetermined temperature.