Patents by Inventor Bruce Allan Harrington

Bruce Allan Harrington has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9234150
    Abstract: This invention is directed to ultra-low viscosity passenger car engine oil compositions with a kinematic viscosity at 100° C. of from 4 to 6 cSt, and comprising in admixture 60 wt % to 90 wt % of a first base oil component, based on the total weight of the composition, the first base oil component consisting of a polyalphaolefin base stock or combination of polyalphaolefin base stocks, each having a kinematic viscosity at 100° C. of from 3.2 cSt to 3.8 cSt; and 0.1 wt % to 20 wt % of a second base oil component, based on the total weight of the composition, the second base oil component consisting of a Group II, Group III or Group V base stock, or any combination thereof; wherein the composition comprises from 0 wt % to less than 0.25 wt % viscosity index improver, on a solid polymer basis.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: January 12, 2016
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Richard Wayne Martin, Douglas Edward Deckman, Kevin John Kelly, Craig Janzen Emett, Mark Paul Hagemeister, Bruce Allan Harrington, Chon-Yie Lin, Phillip Thomas Matsunaga, Charles James Ruff, Kevin Bruce Stavens
  • Patent number: 9234151
    Abstract: This invention is directed to lubricating compositions comprising a first base oil component consisting of a polyalphaolefin base stock or combination of polyalphaolefin base stocks, each having a kinematic viscosity at 100° C. of from 3.2 cSt to 3.8 cSt and obtained by a process comprising: (a) contacting a catalyst, an activator, and a monomer in a first reactor to obtain a first reactor effluent, the effluent comprising a dimer product, a trimer product, and optionally a higher oligomer product, (b) feeding at least a portion of the dimer product to a second reactor, (c) contacting said dimer product with a second catalyst, a second activator, and optionally a second monomer in the second reactor, (d) obtaining a second reactor effluent, the effluent comprising at least a trimer product, and (e) hydrogenating at least the trimer product of the second reactor effluent.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: January 12, 2016
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Richard Wayne Martin, Douglas Edward Deckman, Kevin John Kelly, Craig Janzen Emett, Mark Paul Hagemeister, Bruce Allan Harrington, Chon-Yie Lin, Phillip Thomas Matsunaga, Charles James Ruff, Kevin Bruce Stavens
  • Patent number: 9234152
    Abstract: This invention is directed to passenger car engine oil compositions comprising in admixture 60 wt % to 90 wt % of a first base oil component, based on the total weight of the composition, the first base oil component consisting of a polyalphaolefin base stock or combination of polyalphaolefin base stocks, each having a kinematic viscosity at 100° C. of from 3.2 cSt to 3.8 cSt; 0.1 wt % to 20 wt % of a second base oil component, based on the total weight of the composition, the second base oil component consisting of a Group II, Group III or Group V base stock, or any combination thereof; and at least 0.75 wt % viscosity index improver, on a solid polymer basis.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: January 12, 2016
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Richard Wayne Martin, Douglas Edward Deckman, Kevin John Kelly, Craig Janzen Emett, Mark Paul Hagemeister, Bruce Allan Harrington, Chon-Yie Lin, Phillip Thomas Matsunaga, Charles James Ruff, Kevin Bruce Stavens
  • Patent number: 8829127
    Abstract: The invention relates to a continuous polymerization process for preparing a random ethylene interpolymer which comprises: (A) polymerizing ethylene, and an ?-olefin comonomer selected from propylene and/or 1-butene, and mixtures thereof, under continuous random polymerization conditions in the presence of single site catalyst system employing an ionic activator having cyclic ligands shielding a central charge bearing atom, at a temperature of 140° C. to 250° C. at a conversion of ethylene of 80 to 99% and a comonomer conversion of from at least 20%; and (B) devolatilizing the polymer to provide an ethylene copolymer having a density of from 0.85 to 0.92 g/cm3, an MI of from 0.01 to 100 g/10 min and an I21/I2 of from 30 to 400.
    Type: Grant
    Filed: August 7, 2012
    Date of Patent: September 9, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Rui Zhao, Bruce Allan Harrington, George James Pehlert, Periagaram S. Ravishankar, Kent L. Chasey
  • Publication number: 20130090273
    Abstract: This invention is directed to ultra-low viscosity passenger car engine oil compositions with a kinematic viscosity at 100° C. of from 4 to 6 cSt, and comprising in admixture 60 wt % to 90 wt % of a first base oil component, based on the total weight of the composition, the first base oil component consisting of a polyalphaolefin base stock or combination of polyalphaolefin base stocks, each having a kinematic viscosity at 100° C. of from 3.2 cSt to 3.8 cSt; and 0.1 wt % to 20 wt % of a second base oil component, based on the total weight of the composition, the second base oil component consisting of a Group II, Group III or Group V base stock, or any combination thereof; wherein the composition comprises from 0 wt % to less than 0.25 wt % viscosity index improver, on a solid polymer basis.
    Type: Application
    Filed: September 12, 2012
    Publication date: April 11, 2013
    Applicants: ExxonMobil Chemical Patents Inc., ExxonMobil Research and Engineering Company
    Inventors: Richard Wayne Martin, Douglas Edward Deckman, Kevin John Kelly, Craig Janzen Emett, Mark Paul Hagemeister, Bruce Allan Harrington, Chon-Yie Lin, Phillip Thomas Matsunaga, Charles James Ruff, Kevin Bruce Stavens
  • Publication number: 20130090278
    Abstract: This invention is directed to passenger car engine oil compositions comprising in admixture 60 wt % to 90 wt % of a first base oil component, based on the total weight of the composition, the first base oil component consisting of a polyalphaolefin base stock or combination of polyalphaolefin base stocks, each having a kinematic viscosity at 100° C. of from 3.2 cSt to 3.8 cSt; 0.1 wt % to 20 wt % of a second base oil component, based on the total weight of the composition, the second base oil component consisting of a Group II, Group III or Group V base stock, or any combination thereof; and at least 0.75 wt % viscosity index improver, on a solid polymer basis.
    Type: Application
    Filed: September 12, 2012
    Publication date: April 11, 2013
    Applicants: EXXONMOBIL CHEMICAL PATENTS INC., EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Richard Wayne Martin, Douglas Edward Deckman, Kevin John Kelly, Craig Janzen Emett, Mark Paul Hagemeister, Bruce Allan Harrington, Chon-Yie Lin, Phillip Thomas Matsunaga, Charles James Ruff, Kevin Bruce Stavens
  • Publication number: 20130090277
    Abstract: This invention is directed to lubricating compositions comprising a first base oil component consisting of a polyalphaolefin base stock or combination of polyalphaolefin base stocks, each having a kinematic viscosity at 100° C. of from 3.2 cSt to 3.8 cSt and obtained by a process comprising: (a) contacting a catalyst, an activator, and a monomer in a first reactor to obtain a first reactor effluent, the effluent comprising a dimer product, a trimer product, and optionally a higher oligomer product, (b) feeding at least a portion of the dimer product to a second reactor, (c) contacting said dimer product with a second catalyst, a second activator, and optionally a second monomer in the second reactor, (d) obtaining a second reactor effluent, the effluent comprising at least a trimer product, and (e) hydrogenating at least the trimer product of the second reactor effluent.
    Type: Application
    Filed: September 12, 2012
    Publication date: April 11, 2013
    Applicants: ExxonMobil Chemical Patents Inc., ExxonMobil Research and Engineering Company
    Inventors: Richard Wayne Martin, Douglas Edward Deckman, Kevin John Kelly, Craig Janzen Emett, Mark Paul Hagemeister, Bruce Allan Harrington, Chon-Yie Lin, Phillip Thomas Matsunaga, Charles James Ruff, Kevin Bruce Stavens
  • Publication number: 20130035460
    Abstract: The invention relates to a continuous polymerization process for preparing a random ethylene interpolymer which comprises: (A) polymerizing ethylene, and an ?-olefin comonomer selected from propylene and/or 1-butene, and mixtures thereof, under continuous random polymerization conditions in the presence of single site catalyst system employing an ionic activator having cyclic ligands shielding a central charge bearing atom, at a temperature of 140° C. to 250° C. at a conversion of ethylene of 80 to 99% and a comonomer conversion of from at least 20%; and (B) devolatilizing the polymer to provide an ethylene copolymer having a density of from 0.85 to 0.92 g/cm3, an MI of from 0.01 to 100 g/10 min and an I21/I2 of from 30 to 400.
    Type: Application
    Filed: August 7, 2012
    Publication date: February 7, 2013
    Inventors: Narayanaswami R. DHARMARAJAN, Rui Zhao, Bruce Allan Harrington, George James Pehlert, Periagaram S. Ravishankar, Kent L. Chasey
  • Patent number: 8263722
    Abstract: The invention relates to a continuous polymerization process for preparing a random ethylene interpolymer with propylene and/or 1-butene which comprises: (A) polymerizing ethylene, and as an ?-olefin comonomer propylene and/or 1-butene under continuous random polymerization conditions in the presence of single site catalyst system employing an ionic activator having cyclic ligands shielding a central charge bearing atom, at a temperature of 140° C. to 250° C. at a conversion of ethylene of 80 to 99% and a comonomer conversion of from at least 30% and (B) devolatilizing the polymer to provide an ethylene copolymer having a density of from 0.85 to 0.92 g/cm3, an MI of from 0.01 to 100 g/10 min, preferably from 0.1 to 20, and an I21/I2 of from 30 to 400. The invention also relates to polymers made by such processes containing as ?-olefin comonomer propylene and/or 1-butene, having a density of from 0.85 to 0.92 g/cm3, an MI of from 0.
    Type: Grant
    Filed: March 21, 2005
    Date of Patent: September 11, 2012
    Assignee: Exxonmobil Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Rui Zhao, Bruce Allan Harrington, George James Pehlert, Periagaram S. Ravishankar, Kent L. Chasey
  • Patent number: 8222358
    Abstract: In a process for producing a propylene copolymer, propylene and at least one olefin monomer selected from ethylene and alpha olefins having 4 to 20 carbon atoms are contacted with a catalyst system comprising (a) a catalyst precursor comprising an organometallic compound and (b) an activator comprising a fluoroarylborate anion represented by the formula: Ct+[B(Ar)x(R)n]? where Ct+ is a cation capable of extracting an alkyl group from, or breaking a carbon-metal bond of, the organometallic compound; Ar is a fluorophenyl group; R is a fluoronaphthyl group and each of x and n is 1, 2, or 3, with the proviso that the sum of x+n=4.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: July 17, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: George Rodriguez, Bruce Allan Harrington
  • Patent number: 8013069
    Abstract: Blends of at least two polymers incorporating propylene-derived units and processes for producing such blends are provided. The first polymer of the blend is a low crystallinity polymer including propylene-derived units. The second polymer is a high crystallinity polymer including propylene-derived units. The polymer blends exhibit the beneficial performance characteristics of low crystallinity propylene polymers while minimizing certain processing and handling problems associated with low crystallinity propylene polymers. Low crystallinity propylene polymer pellets often exhibit a tendency to agglomerate because of the softness of such particles. Agglomeration of the pellets creates problems in handling and processing the particles. The polymer blends disclosed reduce the tendency of polymer pellets to agglomerate while maintaining the desirable physical properties, such as elastomeric properties, exhibited by low crystallinity propylene polymers.
    Type: Grant
    Filed: January 13, 2006
    Date of Patent: September 6, 2011
    Assignee: Exxonmobil Chemical Patents Inc.
    Inventors: Bruce Allan Harrington, Michael Glenn Williams, Sudhin Datta, Srivatsan Srinivas Iyer
  • Publication number: 20070208148
    Abstract: In a process for producing a propylene copolymer, propylene and at least one olefin monomer selected from ethylene and alpha olefins having 4 to 20 carbon atoms are contacted with a catalyst system comprising (a) a catalyst precursor comprising an organometallic compound and (b) an activator comprising a fluoroarylborate anion represented by the formula: Ct+[B—(ArxRn)]? where Ct+ is a cation capable of extracting an alkyl group from, or breaking a carbon-metal bond of, the organometallic compound; Ar is a fluorophenyl group; R is a fluoronaphthyl group and each of x and n is 1, 2, or 3, with the proviso that the sum of x+n=4.
    Type: Application
    Filed: January 26, 2007
    Publication date: September 6, 2007
    Inventors: George Rodriguez, Bruce Allan Harrington
  • Patent number: 7067603
    Abstract: The invention relates to novel adhesive alpha-olefin inter-polymers which are largely amorphous and have a rheological behavior that makes them suitable for adhesive use, both without and with minimzed amounts of tackifying resins. Specifically, the invention poly-alpha olefin inter-polymer may be composed of A) from 60 to 94% of units derived from one alpha mono-olefin having from 3 to 6 carbon atoms and B) from 6 to 40 mol % of units derived from one or more other mono-olefins having from 4 to 10 carbon atoms and at least one carbon atom more than A); and C) optionally from 0 to 10 mol % of units derived from another copolymerizable unsaturated hydrocarbon, different from A) and B); the diad distribution of component A in the polymer as determined by 13C NMR as described herein showing a ratio of experimentally determined diad distribution over the calculated Bernoullian diad distribution of less than 1.
    Type: Grant
    Filed: May 7, 2003
    Date of Patent: June 27, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Anthony G. Karandinos, David J. Lohse, Olivier J. F. Georjon, Kenneth Lewtas, Keith A. Nelson, Jean M. Tancrede, Bruce Allan Harrington
  • Patent number: 6627723
    Abstract: The invention relates to novel adhesive alpha-olefin inter-polymers which are largely amorphous and have a rheological behavior that makes them suitable for adhesive use, both without and with minimized amounts of tackifying resins. Specifically, the invention poly-alpha olefin inter-polymer may be composed of A) from 60 to 94 mol % of units derived from one alpha mono-olefin having from 3 to 6 carbon atoms and B) from 6 to 40 mol % of units derived from one or more other mono-olefins having from 4 to 10 carbon atoms and at least one carbon atom more than A); and C) optionally from 0 to 10 mol % of units derived from another copolymerizable unsaturated hydrocarbon, different from A) and B); the diad distribution of component A in the polymer as determined by 13C NMR as described herein showing a ratio of experimentally determined diad distribution over the calculated Bernoullian diad distribution of less than 1.
    Type: Grant
    Filed: December 21, 2000
    Date of Patent: September 30, 2003
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Anthony G. Karandinos, David J. Lohse, Keith A. Nelson, Jean M. Tancrede, Bruce Allan Harrington, Olivier J. F. Georjon, Kenneth Lewtas
  • Patent number: 6111019
    Abstract: This invention is for LLDPE blends with an ethylene-norbornene copolymer for resins and improved toughness and processibility for film production. This invention provides LLDPE based resins which are significantly improved with respect to their capability to be fabricated into a film layer, particularly by a blown bubble extrusion technique. Films prepared of the LLDPE/E-NB melt blended resins of this invention are significantly improved with respect to certain of their film properties, such as tear strength, without detracting from the beneficial properties that a LLDPE otherwise provides to a film.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: August 29, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Palanisamy Arjunan, Wai Yan Chow, Bruce Allan Harrington, Yu Feng Wang, Henry Yang
  • Patent number: 5837787
    Abstract: Rubbery, amorphous cyclic olefin/.alpha.-olefin copolymers in a molar ratio from 5/95 to 30/70. The copolymers are rubbery and have the general properties of thermoplastic elastomers, e.g. good elastic recovery, toughness, and high elasticity, and have a relatively low glass transition temperature (Tg) to avoid brittleness and hardness under normal use temperature. The copolymers also have a high molecular weight, a narrow molecular weight distribution and a uniform, random comonomer distribution to impart a rubbery loss modulus plateau over the temperature range from Tg to above 100.degree. C., and are optionally lightly crosslinked or plasticized to further extend their useful temperature range.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: November 17, 1998
    Assignee: Exxon Chemical Patents, Inc.
    Inventor: Bruce Allan Harrington
  • Patent number: 5763532
    Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.
    Type: Grant
    Filed: October 6, 1995
    Date of Patent: June 9, 1998
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias
  • Patent number: 5723545
    Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: March 3, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias