Patents by Inventor Bruce L. Knight

Bruce L. Knight has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4236545
    Abstract: Drag reduction of fluids containing a water phase, e.g. hydrocarbon-in-water mixture, flowing through a conduit, is reduced by incorporating within the water phase a polymer obtained by radiation-induced polymerization of acrylamide, methacrylamide, acrylic acid, methacrylic acid, alkali metal salts thereof, or mixtures thereof. The polymerization is preferably carried out in 10-60% aqueous monomer solution with gamma radiation. The mixture of monomers, before radiation, preferably contains 25-99% acrylamide and 75-1% sodium acrylate. The polymer preferably shows viscoelastic effects at high concentrations in a solvent. Concentrations of about 1-10,000 ppm of the polymer in the water phase is desired. Examples of fluids useful with this invention include hydrocarbon-in-water and water-in-hydrocarbon slurries, the hydrocarbon is preferably comminuted oil shale or coal, congealed particles of crude oil and/or wax, viscous crude oil, etc.
    Type: Grant
    Filed: December 30, 1977
    Date of Patent: December 2, 1980
    Assignee: Hercules Incorporated
    Inventors: Bruce L. Knight, John S. Rhudy, William B. Gogarty
  • Patent number: 4014801
    Abstract: Oil and water emulsions containing a high molecular weight polymer (e.g. a partially hydrolyzed polyacrylamide) and a surfactant (e.g. monovalent cation-containing petroleum sulfonate) are broken with a de-emulsifying agent made up of a divalent cation-containing salt, e.g. CaCl.sub.2, and a strong oxidizing or reducing agent, e.g. sodium hypochlorite or hydrazine.
    Type: Grant
    Filed: September 30, 1974
    Date of Patent: March 29, 1977
    Assignee: Marathon Oil Company
    Inventors: James H. Fullinwider, Bruce L. Knight
  • Patent number: 3973629
    Abstract: The injectivity profile of a heterogeneous formation and/or vertical conformance is improved by injecting an aqueous solution into the formation, the solution containing a polymer obtained as a product of radiation-induced polymerizatin of acrylamide and/or methacrylamide and acrylic acid, methacrylic acid, and/or alkali metal salts thereof. The polymerization is preferably carried out in a 10-60% aqueous solution with gamma radiation; the aqueous monomer solution preferably contains 25-99% acrylamide and 1-75% sodium acrylate. Immiscible, miscible, or miscible-like displacing processes can be used in conjunction with this invention.
    Type: Grant
    Filed: November 6, 1972
    Date of Patent: August 10, 1976
    Inventors: Bruce L. Knight, John S. Rhudy, William B. Gogarty
  • Patent number: 3938594
    Abstract: Improved fracturing of subterranean formations with water-based fracturing fluids is obtained by incorporating into an aqueous fracturing fluid (1) a water-soluble, high molecular weight polymer that will crosslink in the presence of chromic ion and (2) controlled amounts of chromic ion to crosslink the polymer to form a gel of desired viscosity. Useful polymers include partially hydrolyzed polyacrylamide and copolymers of acrylamide and sodium acrylate.
    Type: Grant
    Filed: April 8, 1974
    Date of Patent: February 17, 1976
    Assignee: Marathon Oil Company
    Inventors: John S. Rhudy, Bruce L. Knight
  • Patent number: 3937633
    Abstract: Water loss from cement slurries is reduced by incorporating within a cement slurry a polymer obtained as a product of radiation-induced polymerization of acrylamide and/or methacrylamide and acrylic acid, methacrylic acid, and/or alkali metal salts thereof. The polymerization is preferably carried out in 10-60% aqueous monomer solution with gamma radiation. The aqueous monomer solution preferably contains 25-99% acrylamide and 75-1% sodium acrylate. The polymer can be present in concentration of about 0.001 to about 3.0 weight percent, based on the aqueous phase of the slurry.
    Type: Grant
    Filed: November 21, 1973
    Date of Patent: February 10, 1976
    Assignee: Hercules, Incorporated
    Inventors: Bruce L. Knight, John S. Rhudy, William B. Gogarty