Abstract: Provided are compositions including a population of particulates that comprise an at least partially crystalline polycarbonate having an average cross-sectional dimension of from about 1 to about 200 ?m, and have a weight-average molecular weight, per polystyrene standards, of from about 17,000 to about 40,000 Daltons. The composition exhibits a zero-shear viscosity of less than about 104 Pa·s at the melting temperature of the partially crystalline polycarbonate. Related systems and methods for utilizing these compositions in additive manufacturing applications, including selective laser sintering (SLS) applications, are also disclosed. Also provided are additively-manufactured articles made with the disclosed compositions and according to the disclosed methods.

Abstract: A semicrystalline polyphenylsulfone, has the structure Formula (I) wherein n and R are defined herein. The semicrystalline polyphenylsulfone, which exhibits a crystalline melting point in a range of 215 to 270° C., can be prepared from amorphous polyphenylsulfone using a solvent-induced crystallization method. An additive manufacturing method utilizing particles of the semicrystalline polyphenylsulfone is described.

Abstract: Provided are particulate compositions that include a matrix polymer and fibrillated reinforcement materials (e.g., PTFE or ultra-high molecular weight polyethylene fibrils) dispersed therein. The compositions are suitable for use in additive manufacturing processes.

Abstract: Provided are systems and methods for additive manufacturing, which systems and methods yield parts having improved interlayer adhesion. In the disclosed technology, additional heating steps are applied on the upper surface of the already printed workpiece so as to offset the dropping temperature of that surface during part fabrication. These heating steps elevate the temperature of the surface to a value that results in a molten interface with subsequently-applied build material, leading to improved interlayer adhesion. This technology is applicable to a variety of additive manufacturing processes, including but not limited to selective laser sintering, fused filament fabrication, and large format additive manufacturing approaches.

Abstract: Provided are compositions comprising partially crystalline polycarbonate particulate having an average cross-sectional dimension of from about 1 ??? to about 200 ????, having from about 10% crystallinity to about 50% crystallinity, and having a weight-average molecular weight, per polystyrene standards, of from about 17,000 to about 40,000 Daltons. The composition exhibits a zero-shear viscosity of less than about 104 Pa s at the melting temperature of the partially crystalline polycarbonate. Related systems and methods for utilizing these compositions in additive manufacturing applications, including selective laser sintering (SLS) applications, are also disclosed. Also provided are additively-manufactured articles made with the disclosed compositions and according to the disclosed methods.

Abstract: Provided are thermoplastic-nanoparticle compositions that exhibit enhanced powder and melt flow. The disclosed compositions, comprising nanoparticles being silylated, have particular application in additive manufacturing processes, such as selective laser sintering and other processes.