Patents by Inventor Bruno Dufour
Bruno Dufour has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11817579Abstract: The invention relates to a cathode composition usable in a lithium-ion battery, to a process for the preparation of this composition, to such a cathode and to a lithium-ion battery incorporating this cathode. The composition comprises an active material which comprises an alloy of lithium nickel cobalt aluminum oxides, an electrically conductive filler and a polymeric binder, and it is such that said polymeric binder comprises at least one modified polymer (Id2) which is the product of a thermal oxidation reaction of a starting polymer and which incorporates oxygenated groups comprising CO groups, the composition being capable of being obtained by the molten route and without evaporation of solvent by being the product of said thermal oxidation reaction applied to a precursor mixture comprising said active material, said electrically conductive filler, said starting polymer and a sacrificial polymer phase.Type: GrantFiled: September 27, 2018Date of Patent: November 14, 2023Assignee: HUTCHINSONInventors: Bruno Dufour, Marc Zimmermann, Ksenia Astafyeva, Melanie Leclerc
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Publication number: 20230361371Abstract: The invention relates in particular to a method for recycling a first electrode for a lithium-ion battery, a precursor mixture of an electrode composition obtained through this recycling, and the composition resulting therefrom. The first electrode includes a first collector and a first coating which comprises first ingredients, and the method comprises: a) separating the first coating from the first collector, b) melt mixing, without solvent, the recovered first coating with new second ingredients comprising a second active material, a second binder comprising a permanent binder and a sacrificial binder, and an electrically-conductive second additive to obtain the precursor mixture, then c) eliminating the sacrificial binder to obtain the composition forming a second electrode coating.Type: ApplicationFiled: September 29, 2021Publication date: November 9, 2023Inventors: Bruno DUFOUR, Ksenia ASTAFYEVA, Capucine DOUSSET
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Patent number: 11699444Abstract: Techniques for using multiple voice-enabled devices in a user environment to reduce the latency for obtaining responses to user utterances from a remote system. The voice-enabled devices may each establish connections with the remote system to have the remote system perform supplemental speech processing for utterances the devices are unable to process locally. One voice-enabled device may have a higher-latency connection to the remote system, and another voice-enabled device may have a lower-latency connection to the remote system. The lower-latency device may send an utterance to the remote system before the higher-latency device is able, and the remote system may begin processing the utterance faster than if the lower-latency device sent the utterance. The remote system may then provide a response for the utterance to the higher-latency device in less time than if the remote system had to wait for the utterance from the higher-latency device.Type: GrantFiled: October 23, 2020Date of Patent: July 11, 2023Assignee: Amazon Technologies, Inc.Inventors: Sahil Puri, Zhengran Li, Zhan Xu, Oliver Sinsik Chiu, Sembhayya Gollakota, Bruno Dufour
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Patent number: 11326083Abstract: The invention relates to a material including a support consisting of a porous composite material including at least one polymer phase forming a binder based on at least one polymer selected from thermoplastic polymers, elastomers, and elastomer thermoplastics, and at least one filler selected from thermally conductive fillers, the pores of the support consisting of the porous composite material being partially or entirely filled with at least one phase-change material. The invention also relates to a method for producing said material.Type: GrantFiled: April 7, 2016Date of Patent: May 10, 2022Assignee: HUTCHINSONInventors: Arnaud Prebe, Bruno Dufour, Fabrice Chopard, Nicolas Garois, Philippe Sonntag
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Publication number: 20220115634Abstract: Provided is a process for the degradation of at least one polymer of an alkene carbonate, a polymeric composition for a lithium-ion battery electrode having a degradation residue obtained by this process, a process for the preparation thereof, an electrode and a battery incorporating it and a degradation process for the sintering of ceramics. The degradation process includes a reaction at 120° C. and 270° C., and under air of a primary amine with a poly(alkene carbonate) polyol, which depolymerizes it in order to obtain a non-polymeric degradation residue. This composition includes an active material, an electrically conductive filler, a polymeric binder and a residue from the degradation under air between 120° C. and 270° C. of a sacrificial phase which includes the polymer and which has been melt blended beforehand with the active material, with the filler and with the binder in order to obtain a precursor mixture of the composition.Type: ApplicationFiled: December 10, 2021Publication date: April 14, 2022Applicant: HUTCHINSONInventors: Philippe SONNTAG, Bruno Dufour, Arnaud Prebe
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Patent number: 11233228Abstract: Provided is a process for the degradation of at least one polymer of an alkene carbonate, a polymeric composition for a lithium-ion battery electrode having a degradation residue obtained by this process, a process for the preparation thereof, an electrode and a battery incorporating it and a degradation process for the sintering of ceramics. The degradation process includes a reaction at 120° C. and 270° C., and under air of a primary amine with a poly(alkene carbonate) polyol, which depolymerizes it in order to obtain a non-polymeric degradation residue. This composition includes an active material, an electrically conductive filler, a polymeric binder and a residue from the degradation under air between 120° C. and 270° C. of a sacrificial phase which includes the polymer and which has been melt blended beforehand with the active material, with the filler and with the binder in order to obtain a precursor mixture of the composition.Type: GrantFiled: October 26, 2017Date of Patent: January 25, 2022Assignee: HutchinsonInventors: Philippe Sonntag, Bruno Dufour, Arnaud Prebe
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Patent number: 11180625Abstract: Porous polymeric materials having a very high content of thermally conductive and/or electrically conductive fillers. Process for the preparation of the porous composite material including at least one binder-forming polymeric phase and one or more fillers, this process including the stages of hot mixing, by the molten route, the polymeric phase, the fillers and a sacrificial polymeric phase, so as to obtain a mixture, of shaping the mixture and of removing the sacrificial polymeric phase.Type: GrantFiled: April 7, 2016Date of Patent: November 23, 2021Assignee: HUTCHINSONInventors: Arnaud Prebe, Bruno Dufour, David Ayme-Perrot, Yannick Bureau, Philippe Sonntag
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Patent number: 11176934Abstract: A speech interface device is configured to switch between languages, at the request of a user, in order to locally process utterances spoken in different languages, even in instances when a remote system is unavailable to, slower than, or otherwise less preferred than the speech interface device. For example, a user can request to set the language setting of the speech interface device to a second language, different from a first language to which the language setting of the device is currently set. Based on this user request, a local speech processing component of the device may load a language model(s) associated with the second language. The speech interface can also output voice prompts in the second language to manage the user's experience while a language update is in progress on the speech interface device.Type: GrantFiled: March 22, 2019Date of Patent: November 16, 2021Assignee: AMAZON TECHNOLOGIES, INC.Inventors: Ashwin Venkatesh Raman, Bruno Dufour, Sasi Kiran Vepanjeri Lokanadha Reddy, Michal Kowalczuk, Maciej Grabon, Maciej Makowski, Fabian Andreas Bumberger
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Patent number: 11155690Abstract: The invention relates to a process for preparing a gelled, dried composition forming a monolithic aerogel with a heat conductivity of less than or equal to 40 mW·m?1·K?1 and derived from a resin of polyhydroxybenzene(s) and formaldehyde(s), to this aerogel composition and to the use thereof. This process comprises: a) polymerization in an aqueous solvent of said polyhydroxybenzene(s) and formaldehyde(s) in the presence of an acidic or basic catalyst, to obtain a solution based on the resin, b) gelation of the solution obtained in a) to obtain a gel of the resin, and c) drying of the gel to obtain a dried gel. According to the invention, step a) is performed in the presence of a cationic polyelectrolyte dissolved in this solvent, and the process also comprises a step d) of heat treatment under inert gas of the dried gel obtained in step c) at temperatures of between 150° C. and 500° C.Type: GrantFiled: December 17, 2019Date of Patent: October 26, 2021Assignee: HUTCHINSONInventors: Bruno Dufour, Benjamin Swoboda, Cedric Huillet, Florian Fannechere, Nadine Poupa
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Patent number: 11133493Abstract: Polymer composition for an electrode, method, and a lithium-ion battery including same are provided. This composition includes an active material having a graphite usable in the anode, an electrically conductive filler and a cross-linked elastomer binder that includes a hydrogenated acrylonitrile butadiene copolymer (HNBR). The binder includes a non-hydrogenated acrylonitrile butadiene copolymer (NBR) and/or a HNBR with an acrylonitrile content that is at least 40% by weight and cross-linked by thermal oxidation. This method includes: a) mixing the active material, the binder in a non-cross-linked state and the electrically conductive filler, to obtain a precursor mixture of the composition, b) depositing the mixture on a metal current collector so that the mixture forms a non-cross-linked film, then c) thermal oxidation of the non-cross-linked film under an atmosphere containing oxygen at a temperature of between 200 and 300° C., to obtain the electrode in which the binder is cross-linked.Type: GrantFiled: July 21, 2017Date of Patent: September 28, 2021Assignee: HutchinsonInventors: Philippe Sonntag, Julie Courtat, Marc Zimmermann, Ksenia Astafyeva, Bruno Dufour, David Ayme-Perrot
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Patent number: 11032876Abstract: A method for preparing an article, the structure of which comprises a substrate of a glass or a glass-ceramic and a coating fixed to at least one portion of the surface of the substrate. In a characteristic way, the coating is generated from at least one loaded polysilsesquioxane resin; the at least one polysilsesquioxane resin not containing any aryl radical in its structure.Type: GrantFiled: November 6, 2018Date of Patent: June 8, 2021Assignee: EurokeraInventors: Bruno Dufour, Gaelle Ferriz, David Henry, Philippe Lehuede
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Publication number: 20200358095Abstract: The invention relates to a cathode composition usable in a lithium-ion battery, to a process for the preparation of this composition, to such a cathode and to a lithium-ion battery incorporating this cathode. The composition comprises an active material which comprises an alloy of lithium nickel cobalt aluminum oxides, an electrically conductive filler and a polymeric binder, and it is such that said polymeric binder comprises at least one modified polymer (Id2) which is the product of a thermal oxidation reaction of a starting polymer and which incorporates oxygenated groups comprising CO groups, the composition being capable of being obtained by the molten route and without evaporation of solvent by being the product of said thermal oxidation reaction applied to a precursor mixture comprising said active material, said electrically conductive filler, said starting polymer and a sacrificial polymer phase.Type: ApplicationFiled: September 27, 2018Publication date: November 12, 2020Applicant: HUTCHINSONInventors: Bruno DUFOUR, Marc ZIMMERMANN, Ksenia ASTAFYEVA, Melanie LECLERC
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Publication number: 20200343548Abstract: The invention relates to an electrode composition for lithium-ion battery, a process for preparing the composition, such an electrode and a lithium-ion battery incorporating same. The composition comprises an active substance able to perform reversible insertion/deinsertion of lithium in the electrode, an electrically conductive filler and a polymeric binder comprising at least one modified polyolefin, and it is such that the modified polyolefin (If1) is derived from a nonpolar aliphatic polyolefin and incorporates oxygenated CO and OH groups, having a content by weight of oxygen atoms of between 2% and 10% inclusive. The modified polyolefin may be the product of a controlled thermal oxidation reaction, under an atmosphere comprising oxygen and at a temperature of between 200° C. and 300° C., of the nonpolar aliphatic polyolefin with oxygen.Type: ApplicationFiled: October 8, 2018Publication date: October 29, 2020Applicant: HUTCHINSONInventors: Bruno DUFOUR, Marc ZIMMERMANN, Ksenia ASTAFYEVA, Julie COURTAT, Capucine DOUSSET
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Patent number: 10723846Abstract: A process for preparing a polymeric composition for forming a lithium-ion or sodium-ion battery electrode or a supercapacitor electrode or for exhibiting magnetic properties, to such a polymeric composition obtained by means of this process, to a mixture which is a precursor of the composition, obtained by means of a first mixing step of the process, and to this electrode. The process for preparing this composition comprises: a) hot-mixing, via the melt process and without solvent, at least one active material, a binder-forming polymeric phase and a sacrificial polymeric phase so as to obtain a mixture, and b) at least partially eliminating said sacrificial polymeric phase so as to obtain said composition which comprises the active material(s) according to a weight fraction greater than 80%. The sacrificial phase is used in step a) according to a weight fraction in the mixture being greater than or equal to 15%.Type: GrantFiled: February 19, 2014Date of Patent: July 28, 2020Assignee: HUTCHINSONInventors: Philippe Sonntag, David Ayme-Perrot, Bruno Dufour, Arnaud Prebe, Nicolas Garois
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Publication number: 20200123340Abstract: The invention relates to a process for preparing a gelled, dried composition forming a monolithic aerogel with a heat conductivity of less than or equal to 40 mW·m?1·K?1 and derived from a resin of polyhydroxybenzene(s) and formaldehyde(s), to this aerogel composition and to the use thereof. This process comprises: a) polymerization in an aqueous solvent of said polyhydroxybenzene(s) and formaldehyde(s) in the presence of an acidic or basic catalyst, to obtain a solution based on the resin, b) gelation of the solution obtained in a) to obtain a gel of the resin, and c) drying of the gel to obtain a dried gel. According to the invention, step a) is performed in the presence of a cationic polyelectrolyte dissolved in this solvent, and the process also comprises a step d) of heat treatment under inert gas of the dried gel obtained in step c) at temperatures of between 150° C. and 500° C.Type: ApplicationFiled: December 17, 2019Publication date: April 23, 2020Applicant: HUTCHINSONInventors: Bruno DUFOUR, Benjamin SWOBODA, Cedric HUILLET, Florian FANNECHERE, Nadine POUPA
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Patent number: 10629388Abstract: The invention relates to a gelled aqueous polymer composition for forming, by means of drying then pyrolysis, a monolithic porous carbon, to a pyrolysed carbonated composition produced by the drying, followed by the pyrolysis, of said gelled composition, to a porous carbon electrode for a supercapacitor comprising said pyrolysed composition, and to methods for producing said respectively gelled and pyrolysed compositions. A gelled composition according to the invention, produced from the polycondensation of polyhydroxybenzene(s) and hexymethylenetetramine, is such that the hexymethylenetetramine comprised therein represents a mass fraction of between 7% and 15% inclusive. Said gelled composition is produced by a) polycondensation in an aqueous solvent of the polyhydroxybenzene(s) and hexymethylenetetramine, followed by b) gelling by heating of said polycondensate.Type: GrantFiled: June 10, 2015Date of Patent: April 21, 2020Assignee: HUTCHINSONInventors: Hugo Dorie, David Ayme-Perrot, Philippe Sonntag, Bruno Dufour
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Publication number: 20200075929Abstract: Provided is a process for the degradation of at least one polymer of an alkene carbonate, a polymeric composition for a lithium-ion battery electrode having a degradation residue obtained by this process, a process for the preparation thereof, an electrode and a battery incorporating it and a degradation process for the sintering of ceramics. The degradation process includes a reaction at 120° C. and 270° C., and under air of a primary amine with a poly(alkene carbonate) polyol, which depolymerizes it in order to obtain a non-polymeric degradation residue. This composition includes an active material, an electrically conductive filler, a polymeric binder and a residue from the degradation under air between 120° C. and 270° C. of a sacrificial phase which includes the polymer and which has been melt blended beforehand with the active material, with the filler and with the binder in order to obtain a precursor mixture of the composition.Type: ApplicationFiled: October 26, 2017Publication date: March 5, 2020Applicant: HUTCHINSONInventors: Philippe SONNTAG, Bruno Dufour, Arnaud Prebe
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Patent number: 10550238Abstract: The invention relates to a process for preparing a gelled, dried composition forming a monolithic aerogel with a heat conductivity of less than or equal to 40 mW·m?1·K?1 and derived from a resin of polyhydroxybenzene(s) and formaldehyde(s), to this aerogel composition and to the use thereof. This process comprises: a) polymerization in an aqueous solvent of said polyhydroxybenzene(s) and formaldehyde(s) in the presence of an acidic or basic catalyst, to obtain a solution based on the resin, b) gelation of the solution obtained in a) to obtain a gel of the resin, and c) drying of the gel to obtain a dried gel. According to the invention, step a) is performed in the presence of a cationic polyelectrolyte dissolved in this solvent, and the process also comprises a step d) of heat treatment under inert gas of the dried gel obtained in step c) at temperatures of between 150° C. and 500° C.Type: GrantFiled: April 11, 2014Date of Patent: February 4, 2020Assignee: HUTCHINSONInventors: Bruno Dufour, Benjamin Swoboda, Cedric Huillet, Florian Fannechere, Nadine Poupa
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Patent number: 10526505Abstract: A non-crosslinked, gelled carbonaceous composition and a pyrolyzed composition respectively forming an aqueous polymer gel and the pyrolysate thereof in the form of porous carbon is provided. Also provided is a production method thereof, to a porous carbon electrode formed by the pyrolyzed composition, and to a supercapacitor containing the electrodes. The gelled, non-crosslinked composition (G2) is based on a resin created at least partly from polyhydroxybenzene(s) R and formaldehyde(s) F and comprises at least one hydrosoluble cationic polyelectrolyte P. The composition forms a rheofluidifying physical gel. A pyrolyzed carbonaceous composition having a carbon monolith, is the product of coating, crosslinking, drying then pyrolysis of the non-crosslinked gelled composition, the carbon monolith being predominantly microporous and able to form a supercapacitor electrode having a thickness of less than 1 mm.Type: GrantFiled: October 8, 2013Date of Patent: January 7, 2020Assignee: HutchinsonInventors: Bruno Dufour, Yannick Bureau, Hugo Dorie, Pierre-Axel Parodat, Philippe Sonntag
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Publication number: 20190382614Abstract: The invention relates to a noncrosslinked gelled carbonaceous composition and a pyrolyzed composition respectively forming an aqueous polymer gel and the pyrolysate thereof in the form of porous carbon. The invention also relates to the production method thereof, to a porous carbon electrode formed by the pyrolyzed composition, and to a supercapacitor containing said electrodes. The gelled, noncrosslinked composition (G2) is based on a resin created at least partly from polyhydroxybenzene(s) R and formaldehyde(s) F and comprises at least one hydrosoluble cationic polyelectrolyte P. According to the invention, the composition forms a rheofluidifying physical gel. A pyrolyzed carbonaceous composition according to the invention, consisting of a carbon monolith, is the product of coating, crosslinking, drying and pyrolysis of the non-crosslinked gelled composition, the carbon monolith being predominantly microporous and able to form a supercapacitor electrode having a thickness of less than 1 mm.Type: ApplicationFiled: August 30, 2019Publication date: December 19, 2019Applicant: HutchinsonInventors: Bruno Dufour, Yannick Bureau, Hugo Dorie, Pierre-Axel Parodat, Philippe Sonntag